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Ionics

, Volume 24, Issue 10, pp 2973–2982 | Cite as

Nano Li4Ti5O12 as sulfur host for high-performance Li-S battery

  • Tianbiao Zeng
  • Penghui Ji
  • Biao Shang
  • Qimeng Peng
  • Xuebu Hu
  • Gang Li
Original Paper
  • 234 Downloads

Abstract

S/Li4Ti5O12 cathode with high lithium ionic conductivity was prepared for Li-S battery. Herein, nano Li4Ti5O12 is used as sulfur host and fast Li+ conductor, which can adsorb effectively polysulfides and improve remarkably Li+ diffusion coefficient in sulfur cathode. At 0.5 C, S/Li4Ti5O12 cathode has a stable discharge capacity of 616 mAh g−1 at the 700th cycle and a capacity loss per cycle of 0.0196% from the second to the 700th cycle, but the corresponding values of S/C cathode are 437 mAh g−1 and 0.0598%. Even at 2 C, the capacity loss per cycle of S/Li4Ti5O12 cathode is only 0.0273% from the second to the 700th cycle. The results indicate that Li4Ti5O12 as the sulfur host plays a key role on the high performance of Li-S battery due to reducing the shuttle effect and enhancing lithium ionic conductivity.

Keywords

Li4Ti5O12 Sulfur host Li+ conductor Polysulfide Electrochemical performance 

Notes

Funding information

This work was supported by the Science and Technology Research Program of Chongqing Municipal Education Commission (Grant No. KJ1709217, KJ1600926), the National Natural Science Foundation of China (no. 21206203), Chongqing Research Program of Basic Research and Frontier Technology (no. cstc2016jcyjA0438), and the Scientific Research Innovation Team of Chongqing University of Technology (no. cqut2015srim).

Supplementary material

11581_2018_2468_MOESM1_ESM.doc (3.7 mb)
ESM 1 (DOC 3747kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Tianbiao Zeng
    • 1
  • Penghui Ji
    • 1
  • Biao Shang
    • 1
  • Qimeng Peng
    • 1
  • Xuebu Hu
    • 1
  • Gang Li
    • 1
  1. 1.College of Chemistry and Chemical EngineeringChongqing University of TechnologyChongqingChina

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