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Ionics

, Volume 24, Issue 10, pp 2957–2963 | Cite as

Effect of high-temperature crystallization on the electrochemical properties of LiNi0.5Co0.2Mn0.3O2 synthesized from a lithiated transition metal oxide precursor

  • Longlong Xue
  • Yunjiao Li
  • Qiang Han
  • Qianye Su
  • Yongxiang Chen
  • Jianguo Li
  • Tongxing Lei
  • Yujie Chen
  • Jian Chen
Original Paper
  • 94 Downloads

Abstract

The lithiated transition metal oxide precursor (LNCMO) with typical α-NaFeO2 structure and imperfect crystallinity, obtained from a hydrothermal process, was pretreated at 500 °C and then subjected to sintering at 800–920 °C to synthesize the ternary layered LiNi0.5Co0.2Mn0.3O2 (NCM523). X-ray diffraction (XRD), scanning electron microscope (SEM), cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and charge/discharge testing were used for investigating the effect of the high-temperature crystallization on the properties of the NCM523 cathode materials. The results show that the materials heated at 880–900 °C possess superior cation ordering, perfect crystallinity, and excellent electrochemical performances, among which the material heated at 900 °C delivers better performances, with the initial discharge capacity of 152.6 mAh g−1 at 0.5 C over 3.0 to 4.3 V and the capacity retention of 95.5% after 50 cycles. Furthermore, the effect of the high-temperature crystallization on the Li+ diffusion coefficient, potential polarization, and electrochemical resistance are discussed.

Keywords

Lithium-ion battery LiNi0.5Co0.2Mn0.3O2 Lithiated precursor High-temperature crystallization Electrochemical properties 

Notes

Acknowledgments

The authors are very grateful for the financial support from the Glorious Laurel Scholar Program of the Government of Guangxi Zhuang Autonomous Region, No.2011A025.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Longlong Xue
    • 1
  • Yunjiao Li
    • 1
  • Qiang Han
    • 1
  • Qianye Su
    • 1
  • Yongxiang Chen
    • 1
  • Jianguo Li
    • 1
  • Tongxing Lei
    • 1
  • Yujie Chen
    • 1
  • Jian Chen
    • 1
  1. 1.School of Metallurgy and EnvironmentCentral South UniversityChangshaPeople’s Republic of China

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