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Science China Technological Sciences

, Volume 61, Issue 9, pp 1301–1308 | Cite as

Revisit of energy transfer upconversion luminescence dynamics—the role of energy migration

  • LangPing Tu
  • Jing Zuo
  • Hong Zhang
Review
  • 16 Downloads

Abstract

Upconversion is a process in which one photon is emitted upon absorption of several photons of lower energy. Potential applications include super resolution spectroscopy, high density data storage, anti-counterfeiting and biological imaging and photo-induced therapy. Upconversion luminescence dynamics has long been believed to be determined solely by the emitting ions and their interactions with neighboring sensitizing ions. Recent research shows that this does not hold for nanostructures. The luminescence time behavior in the nanomaterials is confirmed seriously affected by the migration process of the excitation energy. This new fundamental insight is significant for the design of functional upconversion nanostructures. In this paper we review relevant theoretical and spectroscopic results and demonstrate how to tune the rise and decay profile of upconversion luminescence based on energy migration path modulation.

Keywords

rare earth upconversion energy migration luminescence dynamics 

References

  1. 1.
    Chen G, Qiu H, Prasad P N, et al. Upconversion nanoparticles: Design, nanochemistry, and applications in theranostics. Chem Rev, 2014, 114: 5161–5214CrossRefGoogle Scholar
  2. 2.
    Zheng W, Huang P, Tu D, et al. Lanthanide-doped upconversion nanobioprobes: Electronic structures, optical properties, and biodetection. Chem Soc Rev, 2015, 44: 1379–1415CrossRefGoogle Scholar
  3. 3.
    Boyer J C, van Veggel F C J M. Absolute quantum yield measurements of colloidal NaYF4: Er3+, Yb3+ upconverting nanoparticles. Nanoscale, 2010, 2: 1417–1419CrossRefGoogle Scholar
  4. 4.
    Zuo J, Sun D, Tu L, et al. Precisely tailoring upconversion dynamics via energy migration in core-shell nanostructures. Angew Chem Int Ed, 2018, 57: 3054–3058CrossRefGoogle Scholar
  5. 5.
    Inokuti M, Hirayama F. Influence of energy transfer by the exchange mechanism on donor luminescence. J Chem Phys, 1965, 43: 1978–1989CrossRefGoogle Scholar
  6. 6.
    Chan E M, Han G, Goldberg J D, et al. Combinatorial discovery of lanthanide-doped nanocrystals with spectrally pure upconverted emission. Nano Lett, 2012, 12: 3839–3845CrossRefGoogle Scholar
  7. 7.
    Burshtei. A. Jump mechanism of energy-transfer. Zhurnal Eksperimentalnoi Teor Fiz, 1972, 62: 1695Google Scholar
  8. 8.
    Yokota M, Tanimoto O. Effects of diffusion on energy transfer by resonance. J Phys Soc Jpn, 1967, 22: 779–784CrossRefGoogle Scholar
  9. 9.
    Grant W J C. Role of rate equations in the theory of luminescent energy transfer. Phys Rev B, 1971, 4: 648–663CrossRefGoogle Scholar
  10. 10.
    Liu H, Huang K, Valiev R R, et al. Photon upconversion kinetic nanosystems and their optical response. Laser Photonics Rev, 2018, 12: 1700144CrossRefGoogle Scholar
  11. 11.
    Tu L, Liu X, Wu F, et al. Excitation energy migration dynamics in upconversion nanomaterials. Chem Soc Rev, 2015, 44: 1331–1345CrossRefGoogle Scholar
  12. 12.
    Wang F, Deng R, Wang J, et al. Tuning upconversion through energy migration in core-shell nanoparticles. Nat Mater, 2011, 10: 968–973CrossRefGoogle Scholar
  13. 13.
    Su Q, Han S, Xie X, et al. The effect of surface coating on energy migration-mediated upconversion. J Am Chem Soc, 2012, 134: 20849–20857CrossRefGoogle Scholar
  14. 14.
    Zhong Y, Tian G, Gu Z, et al. Elimination of photon quenching by a transition layer to fabricate a quenching-shield sandwich structure for 800 nm excited upconversion luminescence of Nd3+-sensitized nanoparticles. Adv Mater, 2014, 26: 2831–2837CrossRefGoogle Scholar
  15. 15.
    Vetrone F, Naccache R, Mahalingam V, et al. The active-core/activeshell approach: A strategy to enhance the upconversion luminescence in lanthanide-doped nanoparticles. Adv Funct Mater, 2009, 19: 2924–2929CrossRefGoogle Scholar
  16. 16.
    Zhong Y, Rostami I, Wang Z, et al. Energy migration engineering of bright rare-earth upconversion nanoparticles for excitation by lightemitting diodes. Adv Mater, 2015, 27: 6418–6422CrossRefGoogle Scholar
  17. 17.
    Wang J, Deng R, MacDonald M A, et al. Enhancing multiphoton upconversion through energy clustering at sublattice level. Nat Mater, 2014, 13: 157–162CrossRefGoogle Scholar
  18. 18.
    Deng R, Wang J, Chen R, et al. Enabling Förster resonance energy transfer from large nanocrystals through energy migration. J Am Chem Soc, 2016, 138: 15972–15979CrossRefGoogle Scholar
  19. 19.
    Fischer S, Bronstein N D, Swabeck J K, et al. Precise tuning of surface quenching for luminescence enhancement in core-shell lanthanidedoped nanocrystals. Nano Lett, 2016, 16: 7241–7247CrossRefGoogle Scholar
  20. 20.
    Hossan M Y, Hor A, Luu Q A, et al. Explaining the nanoscale effect in the upconversion dynamics of β-NaYF4:Yb3+, Er3+ core and coreshell nanocrystals. J Phys Chem C, 2017, 121: 16592–16606CrossRefGoogle Scholar
  21. 21.
    Anderson R B, Smith S J, May P S, et al. Revisiting the NIR-to-Visible upconversion mechanism in β-NaYF4:Yb3+, Er3+. J Phys Chem Lett, 2014, 5: 36–42CrossRefGoogle Scholar
  22. 22.
    Chen X, Jin L, Kong W, et al. Confining energy migration in upconversion nanoparticles towards deep ultraviolet lasing. Nat Commun, 2016, 7: 10304CrossRefGoogle Scholar
  23. 23.
    Wang Y F, Liu G Y, Sun L D, et al. Nd3+-sensitized upconversion nanophosphors: Efficientin vivo bioimaging probes with minimized heating effect. ACS Nano, 2013, 7: 7200–7206CrossRefGoogle Scholar
  24. 24.
    Pollnau M, Gamelin D R, Lüthi S R, et al. Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems. Phys Rev B, 2000, 61: 3337–3346CrossRefGoogle Scholar
  25. 25.
    Wang D, Xue B, Kong X, et al. 808 nm driven Nd3+-sensitized upconversion nanostructures for photodynamic therapy and simultaneous fluorescence imaging. Nanoscale, 2015, 7: 190–197CrossRefGoogle Scholar
  26. 26.
    Lu Y, Zhao J, Zhang R, et al. Tunable lifetime multiplexing using luminescent nanocrystals. Nat Photonics, 2014, 8: 33–37Google Scholar
  27. 27.
    Auzel F. Upconversion and anti-stokes processes with f and d ions in solids. Chem Rev, 2004, 104: 139–174CrossRefGoogle Scholar

Copyright information

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Van’t Hoff Institute for Molecular SciencesUniversity of AmsterdamAmsterdamThe Netherlands
  2. 2.Changchun Institute of Optics, Fine Mechanics and PhysicsChinese Academy of SciencesChangchunChina

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