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Dual-band simultaneous lasing in MOFs single crystals with Fabry-Perot microcavities

  • Hongjun Li
  • Huajun He
  • Jiancan Yu
  • Yuanjing Cui
  • Yu Yang
  • Guodong QianEmail author
Articles
  • 23 Downloads

Abstract

Multi-band microlasers based on single microcrystalline materials with Fabry-Perot (F-P) cavities are critically and technologically essential. Here, we demonstrate simultaneous dual-band lasing output (615 and 685 nm) in metal-organic frameworks (MOFs) and organic dyes hybrid single crystals, which support F-P resonances. Through a two-step assembly strategy, two different types of cationic pyridinium hemicyanine dye molecules can be encapsulated into the channel pores of anionic bio-MOF-1-2Me successfully. In addition, the employment of the host-guest system significantly increases the dye loading, enhances luminescent efficiency, and diminishes the aggregation-caused quenching (ACQ) effect in the resultant MOFs/dye composites. This finding not only combines the characteristic of MOFs materials with excellent luminescent properties of organic dyes, but also points out a simple and promising strategy to design multi-band microlasers based on F-P mechanism, opening a low-cost avenue for the rational design of miniaturized lasers in the future.

Keywords

dual-band lasing metal-organic frameworks organic dye Fabry-Perot cavity 

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Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (U1609219, 51432001, 51632008, 61721005) and Zhejiang Provincial Natural Science Foundation (LD18E020001).

Supplementary material

11426_2019_9485_MOESM1_ESM.pdf (919 kb)
Dual-band simultaneous lasing in MOFs single crystals with Fabry-Perot microcavities

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Copyright information

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Hongjun Li
    • 1
  • Huajun He
    • 1
  • Jiancan Yu
    • 1
  • Yuanjing Cui
    • 1
  • Yu Yang
    • 1
  • Guodong Qian
    • 1
    Email author
  1. 1.State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, School of Materials Science and EngineeringZhejiang UniversityHangzhouChina

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