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Aggregation-amplified circularly polarized luminescence from axial chiral boron difluoride complexes

  • Zhiyong Jiang
  • Xiaoqing WangEmail author
  • Jianping Ma
  • Zhipeng LiuEmail author
Articles
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Abstract

The development of small organic molecules with intense and switchable circularly polarized luminescence (CPL) is currently attracting great interest due to their promising applications in chiroptical devices and sensors. In this paper, CPL-active BF2-bridged azaanthracene dimers (BA1 and BA2) were facilely synthesized by incorporating boron difluoride unit to the binaphthalene. BA1 and BA2 show moderate CPL in diluted solutions, however, BA2 exhibited aggregation-amplified red CPL with large dissymmetry factor up to 1.6×10−2. Moreover, acid-/base-triggered CPL switch off/on were also realized via disaggregation/aggregation of BA2 in tetrahydrofuran (THF)/water binary solvents.

Keywords

aggregation-induced emission bodipy circularly polarized luminescence dyes and pigments switch 

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Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (21501085) and Key University Science Research Project of Jiangsu Province (17KJA150004). We are grateful to the High Performance Computing Center of Nanjing Tech University supporting the computational resources.

Supplementary material

11426_2018_9385_MOESM1_ESM.pdf (3.2 mb)
Aggregation-amplified circularly polarized luminescence from axial chiral boron difluoride complexes

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Copyright information

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Key Laboratory of Flexible Electronics, Institute of Advanced MaterialsNanjing Tech UniversityNanjingChina
  2. 2.Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced MaterialsNanjing Tech UniversityNanjingChina
  3. 3.School of Chemistry & Cheimcal Engineering and Materials ScienceShandong Normal UniversityJi’nanChina

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