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Removal of Cu(II) from wastewater by using mechanochemically activated carbonate-based tailings through chemical precipitation

  • Bowen Xiong
  • Tingting Zhang
  • Yunliang ZhaoEmail author
  • Tong Wen
  • Qiwu Zhang
  • Shenxu BaoEmail author
  • Shaoxian Song
Research Article
  • 38 Downloads

Abstract

This work explored the feasibility of utilizing the copper tailings (CT) for removing copper from the waste mine water based on the mechanochemical activation. Batch experiments were performed to evaluate the influences of various experimental parameters like the dosage of CT, reaction time, initial concentration of Cu, and anion species. By cogriding copper solution with CT in the stirred mill (mechanochemical activation), over 99.5% of copper was removed and the residual copper concentration in the solution was less than 0.5 mg/L, reaching the discharge limit. This reaction was a chemical precipitation process. The calcite of CT played a major role in precipitating copper and had a better removal effect on copper in the copper sulfate solution than copper nitrate solution. For copper sulfate solution, the copper deposit was mainly posnjakite (Cu4(SO4)(OH)6·H2O). In the copper nitrate solution, the copper sediment might consist mainly of basic copper nitrate. The stability of the two reaction products was measured by leaching test. The result showed that the sediment obtained by this method was relatively stable and was not hazardous wastes.

Keywords

Mine tailings Copper removal Wet stirred mill Calcite Chemical precipitation 

Notes

Funding information

The financial supports for this work from the Natural Science Foundation of Hubei Province of China (2018CFB468, 2016CFA013) and the National Natural Science Foundation of China (51874220, 51674183) are gratefully acknowledged. Dr. Yunliang Zhao gratefully acknowledges financial support from China Scholarship Council (File No. 201806955006).

References

  1. Agnello AC, Potysz A, Fourdrin C, Huguenot D, Chauhan PS (2018) Impact of pyrometallurgical slags on sunflower growth, metal accumulation and rhizosphere microbial communities. Chemosphere 208:626–639.  https://doi.org/10.1016/j.chemosphere.2018.06.038 CrossRefGoogle Scholar
  2. Aguirre JM, Giraldo O (2011) Simple route for the synthesis of copper hydroxy salts. J Braz Chem Soc 22:546–551CrossRefGoogle Scholar
  3. Ahmari S, Zhang L (2012) Production of eco-friendly bricks from copper mine tailings through geopolymerization. Constr Build Mater 29:323–331.  https://doi.org/10.1016/j.conbuildmat.2011.10.048 CrossRefGoogle Scholar
  4. Akhgar BN, Pourghahramani P (2015) Impact of mechanical activation and mechanochemical activation on natural pyrite dissolution. Hydrometallurgy 153:83–87.  https://doi.org/10.1016/j.hydromet.2015.02.010 CrossRefGoogle Scholar
  5. Barakat MA (2011) New trends in removing heavy metals from industrial wastewater. Arab J Chem 4:361–377.  https://doi.org/10.1016/j.arabjc.2010.07.019 CrossRefGoogle Scholar
  6. Behrens M, Girgsdies F, Trunschke A, Schlögl R (2009) Minerals as model compounds for Cu/ZnO catalyst precursors: structural and thermal properties and IR spectra of mineral and synthetic (zincian) malachite, rosasite and aurichalcite and a catalyst precursor mixture. Eur J Inorg Chem:1347–1357.  https://doi.org/10.1002/ejic.200801216 CrossRefGoogle Scholar
  7. Ben-Ali S, Jaouali I, Souissi-Najar S, Ouederni A (2017) Characterization and adsorption capacity of raw pomegranate peel biosorbent for copper removal. J Clean Prod 142:3809–3821.  https://doi.org/10.1016/j.jclepro.2016.10.081 CrossRefGoogle Scholar
  8. Chen M, Shafer-Peltier K, Randtke SJ, Peltier E (2018) Competitive association of cations with poly(sodium 4-styrenesulfonate) (PSS) and heavy metal removal from water by PSS-assisted ultrafiltration. Chem Eng J 344:155–164.  https://doi.org/10.1016/j.cej.2018.03.054 CrossRefGoogle Scholar
  9. Chinese Ministry of Environmental Protection (1996) Integrated wastewater discharge standard. China Environment Science PressGoogle Scholar
  10. Chinese Ministry of Environmental Protection (2007a) Solid waste-extraction procedure for leaching toxicity—sulphuric acid & nitric Method. China Environment Science PressGoogle Scholar
  11. Chinese Ministry of Environmental Protection (2007b) Identification standards for hazardous wastes-Identification for extraction toxicity. China Environment Science PressGoogle Scholar
  12. De Beer M, Doucet FJ, Maree JP, Liebenberg L (2015) Synthesis of high-purity precipitated calcium carbonate during the process of recovery of elemental sulphur from gypsum waste. Waste Manag 46:619–627.  https://doi.org/10.1016/j.wasman.2015.08.023 CrossRefGoogle Scholar
  13. Di LP, Pizzigallo MD, Ancona V et al (2013) Mechanochemical degradation of pentachlorophenol onto birnessite. J Hazard Mater 244–245:303–310.  https://doi.org/10.1016/j.jhazmat.2012.11.037 CrossRefGoogle Scholar
  14. Djobo JNY, Elimbi A, Tchakouté HK, Kumar S (2016) Mechanical activation of volcanic ash for geopolymer synthesis: effect on reaction kinetics, gel characteristics, physical and mechanical properties. RSC Adv 6:39106–39117CrossRefGoogle Scholar
  15. Dohnálková B, Drochytka R, Hodul J (2018) New possibilities of neutralisation sludge solidification technology. J Clean Prod 204:1097–1107.  https://doi.org/10.1016/j.jclepro.2018.08.095 CrossRefGoogle Scholar
  16. Fall M, Célestin JC, Pokharel M, Touré M (2010) A contribution to understanding the effects of curing temperature on the mechanical properties of mine cemented tailings backfill. Eng Geol 114:397–413CrossRefGoogle Scholar
  17. Geng C, Wang HJ, Hu WT et al (2017) Recovery of iron and copper from copper tailings by coal-based direct reduction and magnetic separation. J Iron Steel Res 24:991–997CrossRefGoogle Scholar
  18. Hamberg R, Maurice C, Alakangas L (2017) Lowering the water saturation level in cemented paste backfill mixtures – effect on the release of arsenic. Miner Eng 112:84–91.  https://doi.org/10.1016/j.mineng.2017.05.005 CrossRefGoogle Scholar
  19. Han Q, Chen L, Li W, Zhou Z, Fang Z, Xu Z, Qian X (2018) Self-assembled three-dimensional double network graphene oxide/polyacrylic acid hybrid aerogel for removal of Cu2+ from aqueous solution. Environ Sci Pollut Res 25:34438–34447.  https://doi.org/10.1007/s11356-018-3409-9 CrossRefGoogle Scholar
  20. Hu H, Li X, Huang P, Zhang Q, Yuan W (2017) Efficient removal of copper from wastewater by using mechanically activated calcium carbonate. J Environ Manag 203:1–7.  https://doi.org/10.1016/j.jenvman.2017.07.066 CrossRefGoogle Scholar
  21. Kang S, Zhao Y, Wang W et al (2018) Removal of methylene blue from water with montmorillonite nanosheets/chitosan hydrogels as adsorbent. Appl Surf Sci 448:203–211.  https://doi.org/10.1016/j.apsusc.2018.04.037 CrossRefGoogle Scholar
  22. Kavaliauskas Z, Valincius V, Stravinskas G, Milieska M, Striugas N (2015) The investigation of solid slag obtained by neutralization of sewage sludge. J Air Waste Manage Assoc 65:1292–1296.  https://doi.org/10.1080/10962247.2015.1064045 CrossRefGoogle Scholar
  23. Ke Y, Chai LY, Liang YJ et al (2013) Sulfidation of heavy-metal-containing metallurgical residue in wet-milling processing. Miner Eng 53:136–143.  https://doi.org/10.1016/j.mineng.2013.07.013 CrossRefGoogle Scholar
  24. Li Z, Chen M, Li X et al (2017) Surface modification of basic copper carbonate by mechanochemical processing with sulfur and ammonium sulfate. Adv Powder Technol 28:1877–1881CrossRefGoogle Scholar
  25. Makó E, Senkár Z, Kristóf J, Vágvölgyi V (2006) Surface modification of mechanochemically activated kaolinites by selective leaching. J Colloid Interface Sci 294:362–370CrossRefGoogle Scholar
  26. Mitoma Y, Miyata H, Egashira N, Simion AM, Kakeda M, Simion C (2011) Mechanochemical degradation of chlorinated contaminants in fly ash with a calcium-based degradation reagent. Chemosphere 83:1326–1330CrossRefGoogle Scholar
  27. Mohamed S, Em VDM, Altermann W, Doucet FJ (2016) Addendum to “Process development for elemental recovery from PGM tailings by thermochemical treatment: Preliminary major element extraction studies using ammonium sulphate as extracting agent.” Waste Manag 50:334–345Google Scholar
  28. Motawei SM, Gouda HE (2016) Screening of blood levels of mercury, cadmium, and copper in pregnant women in Dakahlia, Egypt: new attention to an old problem. Biol Trace Elem Res 171:308–314.  https://doi.org/10.1007/s12011-015-0525-y CrossRefGoogle Scholar
  29. Pino L, Vargas C, Schwarz A, Borquez R (2018) Influence of operating conditions on the removal of metals and sulfate from copper acid mine drainage by nanofiltration. Chem Eng J 345:114–125.  https://doi.org/10.1016/j.cej.2018.03.070 CrossRefGoogle Scholar
  30. Pourghahramani P, Forssberg E (2007) Effects of mechanical activation on the reduction behavior of hematite concentrate. Int J Miner Process 82:96–105CrossRefGoogle Scholar
  31. Prasad H, Singh S, Panigrahi BB (2016) Mechanical activated synthesis of alumina dispersed FeNiCoCrAlMn high entropy alloy. J Alloys Compd 692:720–726CrossRefGoogle Scholar
  32. Schuiskii AV, Zorina ML (2013) Infrared spectra of natural and synthetic malachites. J Appl Spectrosc 80:576–580.  https://doi.org/10.1007/s10812-013-9808-2 CrossRefGoogle Scholar
  33. Soc C, James SL, Adams CJ et al (2012) Mechanochemistry : opportunities for new and cleaner synthesis. Chem Soc Rev:413–447.  https://doi.org/10.1039/c1cs15171a CrossRefGoogle Scholar
  34. Sun L, Hu Y, Sun W et al (2017) Selective recovery of mushistonite from gravity tailings of copper–tin minerals in Tajikistan. Minerals 7:242.  https://doi.org/10.3390/min7120242 CrossRefGoogle Scholar
  35. Tao HC, Liang M, Li W et al (2011) Removal of copper from aqueous solution by electrodeposition in cathode chamber of microbial fuel cell. J Hazard Mater 189:186–192.  https://doi.org/10.1016/j.jhazmat.2011.02.018 CrossRefGoogle Scholar
  36. Van Hille RP, Peterson KA, Lewis AE (2005) Copper sulphide precipitation in a fluidised bed reactor. Chem Eng Sci 60:2571–2578.  https://doi.org/10.1016/j.ces.2004.11.052 CrossRefGoogle Scholar
  37. Vieceli N, Nogueira CA, Pereira MFC et al (2017) Effects of mechanical activation on lithium extraction from a lepidolite ore concentrate. Miner Eng 102:1–14.  https://doi.org/10.1016/j.mineng.2016.12.001 CrossRefGoogle Scholar
  38. Wang LP, Chen YJ (2019) Sequential precipitation of iron , copper , and zinc from wastewater for metal recovery. J Environ Eng 145:1–11. doi:  https://doi.org/10.1061/(ASCE)EE.1943-7870.0001480.CrossRefGoogle Scholar
  39. Wang S, Zhang X, Pan L et al (2015) Controllable sonochemical synthesis of Cu2O/Cu2(OH)3NO3 composites toward synergy of adsorption and photocatalysis. Applied Catal B Environ 164:234–240.  https://doi.org/10.1016/j.apcatb.2014.09.033 CrossRefGoogle Scholar
  40. Wang W, Zhao Y, Liu H, Song S (2017) Fabrication and mechanism of cement-based waterproof material using silicate tailings from reverse flotation. Powder Technol 315:422–429.  https://doi.org/10.1016/j.powtec.2017.04.029 CrossRefGoogle Scholar
  41. Wen T, Zhao Y, Zhang T, Xiong B (2019) Chemosphere effect of anions species on copper removal from wastewater by using mechanically activated calcium carbonate. Chemosphere 230:127–135.  https://doi.org/10.1016/j.chemosphere.2019.04.213 CrossRefGoogle Scholar
  42. Xu J, Qu Z, Yan N et al (2016) Size-dependent nanocrystal sorbent for copper removal from water. Chem Eng J 284:565–570.  https://doi.org/10.1016/j.cej.2015.08.151 CrossRefGoogle Scholar
  43. Xu T, Lei X, Sun B, Yu G, Zeng Y (2017) Highly efficient and energy-conserved flocculation of copper in wastewater by pulse-alternating current. Environ Sci Pollut Res 24:20577–20586.  https://doi.org/10.1007/s11356-017-9280-2 CrossRefGoogle Scholar
  44. Xu W, Cao P, Tian M (2018) Strength development and microstructure evolution of cemented tailings backfill containing different binder types and contents. Minerals 8:1–15.  https://doi.org/10.3390/min8040167 CrossRefGoogle Scholar
  45. Ye C, He F, Shu H et al (2015) Preparation and properties of sintered glass-ceramics containing Au-Cu tailing waste. Mater Des 86:782–787.  https://doi.org/10.1016/j.matdes.2015.07.173 CrossRefGoogle Scholar
  46. Yoder CH, Gotlieb NR, Rowand AL (2010) The relative stability of stoichiometrically related natural and synthetic double salts. Am Mineral 95:47–51.  https://doi.org/10.2138/am.2010.3244 CrossRefGoogle Scholar
  47. Yuan L, Zhi W, Xie Q et al (2015) Lead removal from solution by a porous ceramisite made from bentonite, metallic iron, and activated carbon. Environ Sci Water Res Technol 1:814–822.  https://doi.org/10.1039/c5ew00091b CrossRefGoogle Scholar
  48. Yue ZX, Chen JN (2013) Study on preparation of ceramsite by kyanite tailings. Adv Mater Res 753–755:632–636CrossRefGoogle Scholar
  49. Zhang W, Wang H, Deng X, Hu H (2016) Mineralogy of the Au-Ag-Bi-Te-Se assemblages in the Jiguanzui Cu-Au skarn deposit, Daye District, southeastern Hubei Province. Acta Petrol Sin 32:456–470Google Scholar
  50. Zhang T, Wen T, Zhao Y et al (2018) Antibacterial activity of the sediment of copper removal from wastewater by using mechanically activated calcium carbonate. J Clean Prod 203:1019–1027.  https://doi.org/10.1016/j.jclepro.2018.08.278 CrossRefGoogle Scholar
  51. Zhang T, Zhao Y, Bai H et al (2019) Enhanced arsenic removal from water and easy handling of the precipitate sludge by using FeSO4 with CaCO3 to Ca(OH)2. Chemosphere 231:134–139.  https://doi.org/10.1016/j.chemosphere.2019.05.117 CrossRefGoogle Scholar
  52. Zhao Y, Zhang Y, Chen T et al (2012) Preparation of high strength autoclaved bricks from hematite tailings. Constr Build Mater 28:450–455CrossRefGoogle Scholar
  53. Zhao Y, Kang S, Qin L et al (2020) Self-assembled gels of Fe-chitosan/montmorillonite nanosheets: dye degradation by the synergistic effect of adsorption and photo-Fenton reaction. Chem Eng J 379:122322.  https://doi.org/10.1016/j.cej.2019.122322 CrossRefGoogle Scholar
  54. Zhou X, Liu W, Zhang J et al (2017) Biogenic calcium carbonate with hierarchical organic − inorganic composite structure enhancing the removal of Pb(II) from wastewater. 35785–35793.  https://doi.org/10.1021/acsami.7b09304 CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.School of Resources and Environmental EngineeringWuhan University of TechnologyWuhanChina
  2. 2.Hubei Key Laboratory of Mineral Resources Processing and EnvironmentWuhan University of TechnologyWuhanChina
  3. 3.Materials Research InstituteThe Pennsylvania State UniversityUniversity ParkUSA

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