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Pollutant gas and particulate material emissions in ethanol production in Brazil: social and environmental impacts

  • Marcelo S. SthelEmail author
  • Georgia A. Mothé
  • Marcenilda A. Lima
  • Maria P. P. de Castro
  • Israel Esquef
  • Marcelo G. da Silva
Research Article
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Abstract

The replacement of fossil-based fuels by renewable fuels (biofuels) was proposed in the IPCC report, as an alternative to reduce greenhouse gas emission and reach out to a low-carbon economy. On this perspective, the Brazilian government had implemented a renewable energy program based on the use of ethanol in the transport sector. This work evaluates the scenario of pollutant gas emissions and particulate material that comes from the biomass burning process involved in ethanol production cycle, in the city of Campos dos Goytacazes, Brazil. The gases and particulate material emitted by sugarcane and bagasse burning processes—the last one in energy co-generation mills—were analyzed. A laboratory-controlled burning of both samples was realized in an oven with temperature ramp from 250 to 400 °C, at a regular rate of 50 °C. The gas samples were collected directly from the oven’s exhaust pipe. The particulates obtained were the residual material taken out of the burned samples: a powder with the aspect of soot. A photoacoustic spectroscopy system coupled with quantum cascade laser and electrochemical analyzers was used to measure the emission of polluting gases such as N2O, CO2, CO, NOx (NO, NO2), and SO2 in ppmv range. Fluorescent X-ray spectrometry was applied to evaluate the chemical composition of particulate material, enabling the identification of elements such as Si, Al, Ca, K, Fe, S, P, Ti, Mn, Cu, Zn, Sc, V, Cu, and Sr.

Keywords

Ethanol Social impact Environmental policies Particulates Pollutant gas 

Notes

Acknowledgments

The authors are grateful to the Brazilian agencies of the Foundation for Research Support of the State of Rio de Janeiro (FAPERJ), National Council for Scientific and Technological Development (CNPq), Coordination of Improvement of Higher Education Personnel (CAPES) for the financial support.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Marcelo S. Sthel
    • 1
    Email author
  • Georgia A. Mothé
    • 2
  • Marcenilda A. Lima
    • 1
  • Maria P. P. de Castro
    • 1
  • Israel Esquef
    • 1
  • Marcelo G. da Silva
    • 1
  1. 1.Laboratory of Physical Sciences, Center for Science and TechnologyNorth Fluminense State UniversityCampos dos GoytacazesBrazil
  2. 2.Chemistry and Technology LaboratoryHigher Institutes of Education CENSA—ISECENSACampos dos GoytacazesBrazil

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