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Calcined CoAl-layered double hydroxide as a heterogeneous catalyst for the degradation of acetaminophen and rhodamine B: activity, stability, and mechanism

  • Jianyao Zhu
  • Zhiliang ZhuEmail author
  • Hua Zhang
  • Hongtao Lu
  • Yanling Qiu
Research Article
  • 14 Downloads

Abstract

Peroxymonosulfate (PMS) activated by nanomaterials presents one of the most promising strategies to generate reactive species for remediation of organic pollutant–contaminated water. In this study, CoAl-layered double hydroxide (CoAl-LDH) and calcined CoAl-LDH (CoAl-CLDH) were employed as catalysts for PMS activation towards aqueous organic pollutants degradation. Our experiments showed that the leaching of metal ions from catalyst can be significantly mediated by calcination treatment, which can avoid the secondary contamination. The stable CoAl-CLDH exhibited a high catalytic activity, which is comparable to that of the unstable CoAl-LDH. Importantly, reactive species quenching and electron paramagnetic resonance (EPR) results revealed that singlet oxygen (1O2) is the dominant reactive species and plays a crucial role in the catalytic oxidation process in CoAl-CLDH/PMS system. A possible mechanism was proposed for the activation of PMS on the CoAl-CLDH. We demonstrate that CoAl-CLDH is a highly active and stable heterogeneous catalyst for efficient catalytic oxidation of organic pollutants (such as acetaminophen and rhodamine B (RhB)) via activation of PMS.

Keywords

Calcined CoAl-layered double hydroxide Peroxymonosulfate Degradation Organic pollutants Singlet oxygen 

Notes

Funding information

This work was supported by the National Science and Technology Major Project of China (Grant No. 2017ZX07201005) and the Foundation of Key Laboratory of Yangtze River Water Environment, Ministry of Education (Tongji University), China, (YRWEF201904).

Supplementary material

11356_2019_6390_MOESM1_ESM.docx (1.8 mb)
ESM 1 (DOCX 1875 kb)

References

  1. Dou Y, Zhang S, Pan T, Xu S, Zhou A, Pu M, Yan H, Han J, Wei M, Evans DG, Duan X (2015) TiO2@ layered double hydroxide core-shell nanospheres with largely enhanced photocatalytic activity toward O2 generation. Adv Funct Mater 25:2243–2249CrossRefGoogle Scholar
  2. Duan X, Ao Z, Sun H, Indrawirawan S, Wang Y, Kang J, Liang F, Zhu ZH, Wang S (2015a) Nitrogen-doped graphene for generation and evolution of reactive radicals by metal-free catalysis. ACS Appl Mater Interfaces 7:4169–4178CrossRefGoogle Scholar
  3. Duan X, O'Donnell K, Sun H, Wang Y, Wang S (2015b) Sulfur and nitrogen Co-doped graphene for metal-free catalytic oxidation reactions. Small 11:3036–3044CrossRefGoogle Scholar
  4. Duan X, Sun H, Wang Y, Kang J, Wang S (2015c) N-doping-induced nonradical reaction on single-walled carbon nanotubes for catalytic phenol oxidation. ACS Catal 5:553–559CrossRefGoogle Scholar
  5. Duan X, Su C, Miao J, Zhong Y, Shao Z, Wang S, Sun H (2018) Insights into perovskite-catalyzed peroxymonosulfate activation: maneuverable cobalt sites for promoted evolution of sulfate radicals. Appl Catal B 220:626–634CrossRefGoogle Scholar
  6. Fan G, Li F, Evans DG, Duan X (2014) Catalytic applications of layered double hydroxides: recent advances and perspectives. Chem Soc Rev 43:7040–7066CrossRefGoogle Scholar
  7. Ghanbari F, Moradi M (2017) Application of peroxymonosulfate and its activation methods for degradation of environmental organic pollutants: Review. Chem Eng J 310:41–62CrossRefGoogle Scholar
  8. Guan Y-H, Ma J, Ren Y-M, Liu Y-L, Xiao J-Y, Lin L-q, Zhang C (2013) Efficient degradation of atrazine by magnetic porous copper ferrite catalyzed peroxymonosulfate oxidation via the formation of hydroxyl and sulfate radicals. Water Res 47:5431–5438CrossRefGoogle Scholar
  9. Hu L, Zhang G, Liu M, Wang Q, Dong S, Wang P (2019) Application of nickel foam-supported Co3O4-Bi2O3 as a heterogeneous catalyst for BPA removal by peroxymonosulfate activation. Sci Total Environ 647:352–361CrossRefGoogle Scholar
  10. Kumar S, Isaacs MA, Trofimovaite R, Durndell L, Parlett CMA, Douthwaite RE, Coulson B, Cockett MCR, Wilson K, Lee AF (2017) P25@CoAl layered double hydroxide heterojunction nanocomposites for CO2 photocatalytic reduction. Appl catal B 209:394–404CrossRefGoogle Scholar
  11. Li X, Huang X, Xi S, Miao S, Ding J, Cai W, Liu S, Yang X, Yang H, Gao J, Wang J, Huang Y, Zhang T, Liu B (2018) Single cobalt atoms anchored on porous N-doped graphene with dual reaction sites for efficient fenton-like catalysis. J Am Chem SocGoogle Scholar
  12. Liu ZP, Ma RZ, Osada M, Iyi N, Ebina Y, Takada K, Sasaki T (2006) Synthesis, anion exchange, and delamination of Co-Al layered double hydroxide: assembly of the exfoliated nanosheet/polyanion composite films and magneto-optical studies. J Am Chem Soc 128:4872–4880CrossRefGoogle Scholar
  13. Nagaraju G, Raju GSR, Ko YH, Yu JS (2016) Hierarchical Ni-Co layered double hydroxide nanosheets entrapped on conductive textile fibers: a cost-effective and flexible electrode for high-performance pseudocapacitors. Nanoscale 8:812–825CrossRefGoogle Scholar
  14. Rao Y, Han F, Chen Q, Wang D, Xue D, Wang H, Pu S (2018) Efficient degradation of diclofenac by LaFeO3-Catalyzed peroxymonosulfate oxidation---kinetics and toxicity assessment. Chemosphere 218:299–307CrossRefGoogle Scholar
  15. Rives V, del Arco M, Martin C (2014) Intercalation of drugs in layered double hydroxides and their controlled release: a review. Appl Clay Sci 88-89:239–269CrossRefGoogle Scholar
  16. Saarimaa V, Kaleva A, Paunikallio T, Nikkanen J-P, Heinonen S, Levanen E, Vaisanen P, Markkula A (2018) Convenient extraction method for quantification of thin zinc patina layers. Surf Interface Anal 50:564–570CrossRefGoogle Scholar
  17. Shao M, Ning F, Wei M, Evans DG, Duan X (2014) Hierarchical nanowire arrays based on ZnO core-layered double hydroxide shell for largely enhanced photoelectrochemical water splitting. Adv Funct Mater 24:580–586CrossRefGoogle Scholar
  18. Tao X, Wu Y, Wu Y, Zhang B, Sha H, Cha L, Liu N (2018) Activated carbon-supported cobalt molybdate as a heterogeneous catalyst to activate peroxymonosulfate for removal of organic dyes. Appl Organomet Chem 32Google Scholar
  19. Vialat P, Mousty C, Taviot-Gueho C, Renaudin G, Martinez H, Dupin J-C, Elkaim E, Leroux F (2014) High-performing monometallic cobalt layered double hydroxide supercapacitor with defined local structure. Adv Funct Mater 24:4831–4842CrossRefGoogle Scholar
  20. Wang H, Lang X, Hao R, Guo L, Li J, Wang L, Han X (2016) Facet-defined AgCl nanocrystals with surface-electronic-structure-dominated photoreactivities. Nano Energy 19:8–16CrossRefGoogle Scholar
  21. Wang C, Kang J, Liang P, Zhang H, Sun H, Tade MO, Wang S (2017) Ferric carbide nanocrystals encapsulated in nitrogen-doped carbon nanotubes as an outstanding environmental catalyst. Environ Sci Nano 4:170–179CrossRefGoogle Scholar
  22. Xiao R, Luo Z, Wei Z, Luo S, Spinney R, Yang W, Dionysiou DD (2018a) Activation of peroxymonosulfate/persulfate by nanomaterials for sulfate radical-based advanced oxidation technologies. Curr Opin Chem Eng 19:51–58CrossRefGoogle Scholar
  23. Xiao Y, Wang Y, Xie Y, Ni H, Li X, Zhang Y, Xie T (2018b) Shape-controllable synthesis of MnO2 nanostructures from manganese-contained wastewater for phenol degradation by activating peroxymonosulfate: Performance and mechanism. Environ Technol:1–61Google Scholar
  24. Yu L, Zhang G, Liu C, Lan H, Liu H, Qu J (2018) Interface stabilization of undercoordinated iron centers on manganese oxides for nature-inspired peroxide activation. ACS Catal 8:1090–1096CrossRefGoogle Scholar
  25. Zhang T, Zhu H, Croue J-P (2013) Production of sulfate radical from peroxymonosulfate induced by a magnetically separable CuFe2O4 Spinel in water: efficiency, stability, and mechanism. Environ Sci Technol 47:2784–2791CrossRefGoogle Scholar
  26. Zhang T, Chen Y, Wang Y, Le Roux J, Yang Y, Croue J-P (2014) Efficient peroxydisulfate activation process not relying on sulfate radical generation for water pollutant degradation. Environ Sci Technol 48:5868–5875CrossRefGoogle Scholar
  27. Zhang S, Fan Q, Gao H, Huang Y, Liu X, Li J, Xu X, Wang X (2016) Formation of Fe3O4@MnO2 ball-in-ball hollow spheres as a high performance catalyst with enhanced catalytic performances. J Mater Chem A 4:1414–1422CrossRefGoogle Scholar
  28. Zhao M, Zhao Q, Li B, Xue H, Pang H, Chen C (2017) Recent progress in layered double hydroxide based materials for electrochemical capacitors: design, synthesis and performance. Nanoscale 9:15206–15225CrossRefGoogle Scholar
  29. Zhu M, Miao J, Duan X, Guan D, Zhong Y, Wang S, Zhou W, Shao Z (2018) Postsynthesis growth of CoOOH nanostructure on SrCo0.6Ti0.4O3-δ perovskite surface for enhanced degradation of aqueous organic contaminants. ACS Sustain Chem Eng 6:15737–15748CrossRefGoogle Scholar
  30. Zou Y, Wang X, Wu F, Yu S, Hu Y, Song W, Liu Y, Wang H, Hayat T, Wang X (2017) Controllable synthesis of Ca-Mg-Al layered double hydroxides and calcined layered double oxides for the efficient removal of U(VI) from wastewater solutions. ACS Sustain Chem Eng 5:1173–1185CrossRefGoogle Scholar
  31. Zubair M, Daud M, McKay G, Shehzad F, Al-Harthi MA (2017) Recent progress in layered double hydroxides (LDH)-containing hybrids as adsorbents for water remediation. Appl Clay Sci 143:279–292CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.State Key Laboratory of Pollution Control and Resource ReuseTongji UniversityShanghaiChina
  2. 2.Shanghai Institute of Pollution Control and Ecological SecurityShanghaiChina
  3. 3.Shanghai Urban Construction Vocational CollegeShanghaiChina
  4. 4.Key Laboratory of Yangtze River Water Environment, Ministry of EducationTongji UniversityShanghaiChina

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