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Environmental Science and Pollution Research

, Volume 26, Issue 31, pp 31623–31631 | Cite as

Removal of silica from brackish water by integrated adsorption/ultrafiltration process

  • Hilla ShemerEmail author
  • Nitzan Melki-Dabush
  • Raphael Semiat
Research Article
  • 68 Downloads

Abstract

A lab-scale unit of the hybrid continuous stirred tank reactor (CSTR) adsorption/ultrafiltration (UF) system was used to evaluate the removal efficiency of silica from brackish water. The semi-batch adsorption process was carried out using iron oxy/hydroxide agglomerates (IOAs) as adsorbent and hollow fiber ultrafiltration membrane as a barrier to the adsorbent passage to the product water. The effect of residence time, concentration of silica, and adsorbent dosage on the silica removal and UF membrane blockage was examined. It was found that a short residence time of 15 min was sufficient to achieve the maximum adsorption capacity similar to that obtained in batch isotherm experiments. The adsorption capacity increased with the augmentation of the silica concentration and decreased with the increase in the adsorbent dosage. The UF was effectively employed to separate the loaded adsorbent without fouling the membrane until breakthrough. A simple model was applied to accurately predict the adsorption breakthrough curves.

Keywords

Hybrid process Semi-batch adsorption Iron oxy/hydroxide CSTR Membrane fouling 

Notes

Funding information

The authors gratefully acknowledge the financial support from the Joint German-Israeli Water Technology Research Program BMBF Germany/MOST Israel.

Supplementary material

11356_2019_6363_MOESM1_ESM.docx (30 kb)
ESM 1 (DOCX 29 kb)

References

  1. Al-Rehaili AM (2003) Comparative chemical clarification for silica removal from RO groundwater feed. Desalination 159:21–31CrossRefGoogle Scholar
  2. Amjad Z (2013) Mineral scales in biological and industrial systems. 1st Edition, Chapter 10, CRC PressGoogle Scholar
  3. Ang WL, Mohammad AW, Hilal N, Leo CP (2015) A review on the applicability of integrated/hybrid membrane processes in water treatment and desalination plants. Desalination 363:2–18CrossRefGoogle Scholar
  4. Aydın YA, Aksoy ND (2009) Adsorption of chromium on chitosan: optimization, kinetics and thermodynamics. Chem Eng J 151:188–194CrossRefGoogle Scholar
  5. Beolchini F, Pagnanelli F, Veglio F (2001) Modeling of copper biosorption by Arthrobacter sp. in a UF/MF membrane reactor. Environ Sci Technol 35:3048–3054CrossRefGoogle Scholar
  6. Bouguerra W, Ben Sik Ali M, Hamrouni B, Dhahbi M (2007) Equilibrium and kinetic studies of adsorption of silica onto activated alumina. Desalination 206:141–146CrossRefGoogle Scholar
  7. Chan SH (1989) A review on solubility and polymerization of silica. Geothermics 18:49–56CrossRefGoogle Scholar
  8. Chen S, Lin C, Chang T (2008) Silica pretreatment for RO membrane by softening-adsorption. J Environ Eng Manage 18:99–103Google Scholar
  9. Cheng HH, Chen SS, Yang SR (2009) In-line coagulation/ultrafiltration for silica removal from brackish water as RO membrane pretreatment. Sep Purif Technol 70:112–117CrossRefGoogle Scholar
  10. Crini G, Peindy NH, Gimbert F, Robert C (2007) Removal of C.I. basic green 4 (malachite green) from aqueous solutions by adsorption using cyclodextrin-based adsorbent: kinetic and equilibrium studies. Sep Purif Technol 53:97–110CrossRefGoogle Scholar
  11. Davis C, Wenchen H, Wards M (2002) Modeling silica sorption to iron hydroxide. Environ Sci Technol 36:582–587CrossRefGoogle Scholar
  12. Drioli E, Stankiewicz AI, Macedonio F (2011) Membrane engineering in process intensification- an overview. J Membr Sci 380:1–8CrossRefGoogle Scholar
  13. Gonzalez CM, Hernandez J, Peralta-Videa JR, Botez CE, Parsons JG, Gardea-Torresdey JL (2012) Sorption kinetic study of selenite and selenate onto a high and low pressure aged iron oxide nanomaterial. J Hazard Mater 211–212:138–145CrossRefGoogle Scholar
  14. Gorni-Pinkesfeld O, Hasson D, Shemer H, Semiat R (2016) Silica removal by a novel electrochemical system. Corrosion 2016, 6-10 March, Vancouver, British Columbia, Canada; NACE-2016-7039Google Scholar
  15. Gupta VK, Srivastava SK, Mohan D (1997) Equilibrium uptake, sorption dynamics, process optimization, and column operations for the removal and recovery of malachite green from wastewater using activated carbon and activated slag. Ind Eng Chem Res 36:2007–2018CrossRefGoogle Scholar
  16. Hermosilla D, Ordóñez R, Blanco L, de la Fuente E, Blanco A (2012) pH and particle structure effects on silica removal by coagulation. Chem Eng Technol 35:1632–1640CrossRefGoogle Scholar
  17. Hilbrandt I, Shemer H, Ruhl AR, Semiat R, Jekel M (2019) Comparing fine particulate iron hydroxide adsorbents for the removal of phosphate in a hybrid adsorption/ultrafiltration system. Sep Purif Technol 221:23–28CrossRefGoogle Scholar
  18. Kalaruban M, Loganathan P, Kandasamy J, Vigneswaran S (2018) Submerged membrane adsorption hybrid system using four adsorbents to remove nitrate from water. Environ Sci Pollut Res 25:20328–20335CrossRefGoogle Scholar
  19. Latour I, Miranda R, Carceller R, Blanco A (2015) Efficiency of polyaluminum nitrate sulphate-polyamine hybrid coagulants for silica removal. Desalin Water Treat 38:17973–17984Google Scholar
  20. Latour I, Miranda R, Blanco A (2016) Optimization of silica removal with magnesium chloride in papermaking effluents: mechanistic and kinetic studies. Environ Sci Pollut Res 23:3707–3717CrossRefGoogle Scholar
  21. Lu D, Cao Q, Cao X, Luo F (2009) Removal of Pb(II) using the modified lawny grass: mechanism, kinetics, equilibrium and thermodynamic studies. J Hazard Mater 166:239–247CrossRefGoogle Scholar
  22. Milne NA, O'Reilly T, Sanciolo P, Ostarcevic E, Beighton M, Taylor K, Mullett M, Tarquin AJ, Gray SR (2014) Chemistry of silica scale mitigation for RO desalination with particular reference to remote operations. Water Res 65:107–133CrossRefGoogle Scholar
  23. Miranda R, Latour I, Hörsken A, Jarabo R, Blanco A (2015) Enhanced silica removal by polyamine- and polyacrylamide- polyaluminum hybrid coagulants. Chem Eng Technol 38:2045–2053CrossRefGoogle Scholar
  24. Ning RY (2010) Reactive silica in natural waters - a review. Deslin Water Treat 21:79–86CrossRefGoogle Scholar
  25. Reddad Z, Gerente C, Andres Y, Thibault JF, Le Cloirec P (2003) Cadmium and lead adsorption by a natural polysaccharide in MF membrane reactor: experimental analysis and modelling. Water Res 37:3983–3991CrossRefGoogle Scholar
  26. Sablani SS, Goosen MFA, Al-Belushi R, Wilf M (2001) Concentration polarization in ultrafiltration and reverse osmosis: a critical review. Desalination 141:269–289CrossRefGoogle Scholar
  27. Sanciolo P, Milne N, Taylor J, Mullet M, Gray S (2014) Silica scale mitigation for high recovery reverse osmosis of groundwater for a mining process. Desalination 340:49–58CrossRefGoogle Scholar
  28. Sasan K, Brady PV, Krumhansl JL, Nenoff TM (2017) Exceptional selectivity for dissolved silicas in industrial waters using mixed oxides. J Water Pro Eng 20:187–192CrossRefGoogle Scholar
  29. Shemer H, Armush A, Semiat R (2019) Reusability of iron oxyhydroxide agglomerates adsorbent for repetitive phosphate removal. Colloid Surfaces A 579:123680–123688CrossRefGoogle Scholar
  30. Stoquart C, Servais P, Berube PR, Barbeau B (2012) Hybrid membrane processes using activated carbon treatment for drinking water: a review. J Membr Sci 411-412:1–12CrossRefGoogle Scholar
  31. Swedlund PJ, Webster JG (1999) Adsorption and polymerization of silicic acid on ferrihydrite, and its effect on arsenic adsorption. Water Res 33:3413–3422CrossRefGoogle Scholar
  32. Swedlund PJ, Miskelly GM, McQuillan AJ (2010) Silicic acid adsorption and oligimerization at the ferrihydriteewater interface: interpretation of the ATR-IR spectra based on a model surface structure. Langmuir 26:3394–3401CrossRefGoogle Scholar
  33. Taylor P (1995) Interactions of silica with iron oxides: effects on oxide transformations and sorption properties. AECL-11257 CanadaGoogle Scholar
  34. Thompson J, Rahardianto A, Kim S, Bilal M, Breckenridge R, Cohen Y (2017) Real-time direct detection of silica scaling on RO membranes. J Membr Sci 528:346–358CrossRefGoogle Scholar
  35. Veglio F, Beolchini F, Barba D (2000) Experimental study and simulation on the biosorption of copper(II) in membrane reactors: a preliminary study. Ind Eng Chem Res 39:2480–2484CrossRefGoogle Scholar
  36. Wei Z, Semiat R (2017) Applying a modified Donnan model to describe the surface complexation of chromate to iron oxyhydroxide agglomerates with heteromorphous pores. J Colloid Interface Sci 506:66–75CrossRefGoogle Scholar
  37. Wei Z, Luo S, Xiao R, Khalfin R, Semiat R (2017) Characterization and quantification of chromate adsorption by layered porous iron oxyhydroxide: an experimental and theoretical study. J Hazard Mater 338:472–481CrossRefGoogle Scholar
  38. Winter J, Barbeau B, Bérubé P (2017) Nanofiltration and tight ultrafiltration membranes for natural organic matter removal- contribution of fouling and concentration polarization to filtration resistance. Membranes 7(3):34–48CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Hilla Shemer
    • 1
    Email author
  • Nitzan Melki-Dabush
    • 1
  • Raphael Semiat
    • 1
  1. 1.GWRI Rabin Desalination Laboratory, Department of Chemical EngineeringTechnion-Israel Institute of TechnologyHaifaIsrael

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