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Thermally induced characterization and modeling of physicochemical, acoustic, rheological, and thermodynamic properties of novel blends of (HEF + AEP) and (HEF + AMP) for CO2/H2S absorption

  • Sweta Balchandani
  • Bishnupada Mandal
  • Swapnil DharaskarEmail author
  • Arvind Kumar
  • Syamalendu Bandyopadhyay
Research Article
  • 42 Downloads

Abstract

CO2 and H2S removal from flue gases is indispensable to be done for protection of environment with respect to global warming as well as clean air. Chemical absorption is one of the most developed and capable techniques for the removal of these sour gases. Among the many solvents, ionic liquids (ILs) are more capable due to their desirable green solvent properties. However, ILs being usually costlier, the blends of ILs and amines are more suggestive for absorption. In the present work, various essential characterization properties such as density, viscosity, sound velocity, and refractive index of two ionic liquid–amine blend systems viz. (1) 2-Hydroxy ethyl ammonium formate (HEF) + 1-(2-aminoethyl) piperazine (AEP) and (2) 2-Hydroxy ethyl ammonium formate (HEF) + 2-Amino-2-methyl-1-propanol (AMP) are reported. The temperature range for which all the measurements were conducted is 298.15 to 333.15 K. For both systems of (HEF + AEP) and (HEF + AMP), HEF mass fractions were varied from 0.2 to 0.8.The density and viscosity results were correlated as a function of temperature and concentration of ionic liquid and amine with Redlich-Kister and Grunberg-Nissan models, respectively. Moreover, feed forward neural network model (ANN) is explored for correlating experimentally determined sound velocity and refractive index data. The measured properties are further analyzed to estimate various thermodynamic as well as transport properties such as diffusivity of CO2/H2S in the (HEF + AEP) and (HEF + AMP), thermal expansion coefficients, and isentropic compressibility, ΔG0, ΔS0, ΔH0, using the available models in the literature.

Keywords

Carbon dioxide Hydrogen sulfide HEF Redlich-Kister Grunberg-Nissan ANN 

Notes

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

11356_2019_6305_MOESM1_ESM.doc (164 kb)
ESM 1 (DOC 163 kb)

References

  1. Alvarez KEA, Gómez-Díaz D, Rubia MDL, Navaza JM (2006) Densities and viscosities of aqueous ternary mixtures of 2-(methylamino) ethanol and 2-(ethylamino)ethanol with diethanolamine, triethanolamine, N methyldiethanolamine, or 2-amino-1-methyl-1-propanol from 298.15 to 323.15. J Chem Eng Data 51:955–962CrossRefGoogle Scholar
  2. Alvarez E, Fernando C, Diego G, Jose MN (2010) Density, speed of sound, isentropic compressibility, and excess volume of binary mixtures of 1-amino-2-propanol or 3-amino-1-propanol with 2-amino-2-methyl-1-propanol, diethanolamine, or triethanolamine from (293.15to 323.15) K. J Chem Eng Data 55:2567–2575CrossRefGoogle Scholar
  3. Anastas PT, Warner JC (1988) Green chemistry: theory and practice, Oxford. University Press, New York, p 30Google Scholar
  4. Andre P, Keng LA, Kenneth NM, Shusheng P (2011) Density, viscosity and electrical conductivity of protic alkanolammonium ionic liquids. Phys Chem 13:5136–5143Google Scholar
  5. Aronu UE, Gondal S, Hessen ET, Haug-Warberg T, Hartono A, Hoff KA, Svendsen HF (2011) Solubility of CO2 in 15, 30, 45 and 60 mass% MEA from 40 to 120 °C and model representation using the extended UNIQUAC framework. Chem Eng Sci 66:6393–6406CrossRefGoogle Scholar
  6. Braun ON, Persson UA, Karlsson HT (2001) Densities and viscosities of mono (ethylene glycol) + 2-amino-2-methyl-1-propanol + Water. J Chem Eng Data 46:805–808CrossRefGoogle Scholar
  7. Choi J, Kim Y, Nam S, Yun S, Yoon Y, Lee J (2016) CO2 absorption characteristics of a piperazine derivative with primary, secondary, and tertiary amino groups. Kor J Chem Eng 33:3222–3230CrossRefGoogle Scholar
  8. Cota I, Gonzalez-Olmos R, Iglesias M, Medina F (2007) New short aliphatic chain ionic liquids: synthesis, physical properties, and catalytic activity in aldol condensations. J Phys Chem B 111:12468–12477CrossRefGoogle Scholar
  9. Das B, Deogam B, Mandal BP (2017) Experimental and theoretical studies on efficient carbon dioxide capture using novel bis (3-amino propyl) amine (APA)-activated aqueous 2-amino-2-methyl-1-propanol (AMP) solutions. RSC Adv 7:21518–21530CrossRefGoogle Scholar
  10. García-Abuín A, Gomez-Díaz D, Rubia MD, Navaza JM (2011) Density, speed of sound, viscosity, refractive index, and excess volume of N-methyl-2-pyrrolidone + ethanol (or water or ethanolamine) from T = (293.15 to 323.15) K. J Chem Eng Data 56:646–651CrossRefGoogle Scholar
  11. Ghani NA, Sairi NA, Aroua MK, Alias Y (2014) Density, surface tension, and viscosity of ionic liquids (1-ethyl-3-methylimidazolium diethylphosphate and 1,3-dimethylimidazolium dimethyl phosphate) aqueous ternary mixtures with MDEA. J Chem Eng Data 59:1737–1746CrossRefGoogle Scholar
  12. Gokul CK, Bradley DF, Bani HC, Alexander IN, Srinivasa RR (2005) Viscosity increase with temperature in cationic surfactant solutions due to the growth of wormlike micelles. Langmuir 21:10998–11004CrossRefGoogle Scholar
  13. Guo H, Zhou Z, Jing G (2013) Kinetics of carbon dioxide absorption into aqueous [Hmim] [Gly] solution. Int J Greenhouse Gas Control 16:197–205CrossRefGoogle Scholar
  14. Hamzehie ME, Najibi H (2015) Prediction of carbon dioxide loading capacity in amino acid salt solutions as new absorbents using artificial neural network and Deshmukhe Mather models. J Nat Gas Sci Eng 27:676–685CrossRefGoogle Scholar
  15. Hamzehie ME, Fattahi M, Najibi H, Bruggen BVD, Mazinani S (2015) Application of artificial neural networks for estimation of solubility of acid gases (H2S and CO2) in 32 commonly ionic liquid and amine solutions. J Nat Gas Sci Eng 24:106–114CrossRefGoogle Scholar
  16. Heintz YJ, Sehabiague L, Morsi BI, Jones KL, Luebke DR, Pennline HW (2009) Hydrogen sulfide and carbon dioxide removal from dry fuel gas streams using an ionic liquid as a physical solvent. Energy Fuel 23:4822–4830CrossRefGoogle Scholar
  17. Jalili AH, Mehdizadeh A, Shokouhi M, Ahmadi AN, Hosseini-Jenab M (2010a) Fatem-inassab F, 2010a. Solubility and diffusion of CO2 and H2S in the ionic liquid 1-ethyl-3-methylimidazolium ethylsulfate. J Chem Thermodyn 42:1298–1303CrossRefGoogle Scholar
  18. Jalili AH, Mehdizadeh A, Shokouhi M, Sakhaeinia H, Taghikhani V (2010b) Solubility of CO2 in 1-(2-hydroxyethyl)-3-methylimidazolium ionic liquids with different anions. J Chem Thermodyn 42:787–791CrossRefGoogle Scholar
  19. John G, Nandhibatla VS (2004) Densities, viscosities, speeds of sound, and relative permittivities for water + cyclic amides (2-pyrrolidinone, 1-methyl-2-pyrrolidinone, and 1-vinyl-2-pyrrolidinone) at different temperatures. J Chem Eng Data 49:235–242CrossRefGoogle Scholar
  20. Kristian OSH, Kurt VM, Thomas MN, Per-Olof AS (2005) Refractive index of liquid water in different solvent models. J Phys Chem A 109:905–914CrossRefGoogle Scholar
  21. Kuan H, Jian FL, You TW, Xing BH, Zhi BZ (2013) Absorption of SO2 in aqueous solutions of mixed hydroxyl ammonium dicarboxylate ionic liquids. Chem Eng J 215–216:36–44Google Scholar
  22. Kurnia KA, Harris F, Wilfred CD, Mutalib MIA, Murugesan T (2009) Thermodynamic properties of CO2 absorption in hydroxyl ammonium ionic liquids at pressures of (100–1600) kPa. J Chem Thermodyn 41:1069–1073CrossRefGoogle Scholar
  23. Li L, Zhang J, Li Q, Guo B, Zhao T, Sha F (2014) Density, viscosity, surface tension, and spectroscopic properties for binary system of 1, 2-ethanediamine + diethylene glycol. Thermochim Acta 590:91–99CrossRefGoogle Scholar
  24. Mahinder R, Theo WL, Thijs JHV (2012) State-of-the-Art of CO2 capture with ionic liquids. Ind Eng Chem Res 51(24):8149–8177CrossRefGoogle Scholar
  25. Mandal BP, Kundu M, Bandhyopadhyay SS (2003) Density and viscosity of aqueous solutions of (N-methyldiethanolamine + monoethanolamine), (N-methyldiethanolamine + diethanolamine), (2-amino-2-methyl-1-propanol + monoethanolamine) and (2-Amino-2-methyl-1-propanol + diethanolamine). J Chem Eng Data 48:703–707CrossRefGoogle Scholar
  26. Mandal BP, Kundu M, Padhiyar NU, Bandyopadhyay SS (2004a) Physical solubility and diffusivity of N2O and CO2 into aqueous solutions of (2-amino-2-methyl-1-propanol + diethanolamine) and (N-methyldiethanolamine + diethanolamine). J Chem Eng Data 49:264–270CrossRefGoogle Scholar
  27. Mandal BP, Biswas AK, Bandyopadhyay SS (2004b) Selective absorption of H2S from gas streams containing H2S and CO2 into aqueous solutions of N-methyldiethanolamine and 2-amino-2-methyl-1-propanol. Sep Purif Technol 35:191–202CrossRefGoogle Scholar
  28. McCoy CA, Gregor MC, Polsin DN, Fratanduono DE, Celliers PM, Boehly TR, Meyerhofer DD (2016) Measurements of the sound velocity of shock-compressed liquid silicato1100GPa. J Appl Phys 120:235901CrossRefGoogle Scholar
  29. Nithiyanantham S (2019) Ultrasonic velocity models in liquids (micro- and nanofluids): theoretical validations. Int Nano Lett 9(2):89–97CrossRefGoogle Scholar
  30. Noman H, Orville CS (1987) Absorption of H2S into aqueous methyldiethanolamine. Chem Eng Commun 59:85–93CrossRefGoogle Scholar
  31. Noman H, Orvlile CS (1984) Molecular diffusivity of hydrogen sulphide in water. J Chem Eng Data 29:20–22CrossRefGoogle Scholar
  32. Nwaoha C, Odoh K, Ikpatt E, Orji R, Idem R (2017) Process simulation, parametric sensitivity analysis and ANFIS modeling of CO2 capture from natural gas using aqueous MDEA–PZ blend solution. J Environ Chem Eng 5:5588–5598CrossRefGoogle Scholar
  33. Pani F, Gaunand A, Richon D, Cadours R, Bouallou C (1997) Absorption of H2S by an aqueous methyldiethanolamine solution at 296 and 343 K. J Chem Eng Data 42:865–870CrossRefGoogle Scholar
  34. Patil GN, Vaidya PD, Kenig EY (2012) Reaction kinetics of CO2 in aqueous methyl- and dimethyl monoethanolamine solutions. Ind Eng Chem Res 51:1592–1600CrossRefGoogle Scholar
  35. Paul S, Mandal BP (2006) Density and viscosity of aqueous solutions of 2-piperidineethanol, (2-piperidinethanol + monoethanolamine), and (2-piperidinethanol + diethanolamine) from (288 to 333) K. J Chem Eng Data 51:1406–1410CrossRefGoogle Scholar
  36. Paul S, Ghoshal AK, Mandal B (2009) Kinetics of absorption of carbon dioxide into aqueous blends of 2-(1-piperazinyl)-ethylamine and N-methyldiethanolamine. Chem Eng Sci 64:1618–1622CrossRefGoogle Scholar
  37. Pinto DD, Monteiro JGM, Johnsen B, Svendsen HF, Knuutila H (2014) Density measurements and modeling of loaded and unloaded aqueous solutions of MDEA (N-methyldiethanolamine), DMEA (N, N-dimethylethanolmine), DEEA (diethylethanolamine) and MAPA (N-methyl-1, 3-diaminopropane). Int J Greenhouse Gas Control 25:173–185CrossRefGoogle Scholar
  38. Rascol E, Meyer M, Huor MH, Prevost M (1997) Modelisation and simulation of the absorption of CO2 and H2S into mixed alkanolamine solutions. Hung J Ind Chem 25:11–16Google Scholar
  39. Remi B, Didier M (2018) Improved model for the refractive index: application to potential components of ambient aerosol. Phys Chem Chem Phys 20:22017–22026CrossRefGoogle Scholar
  40. Rinker EB, Ashour SS, Sandall OC (2000) Absorption of carbon dioxide into aqueous blends of diethanolamine and methyldiethanolamine. Ind Eng Chem Res 39:4346–4356CrossRefGoogle Scholar
  41. Saha AK, Bandyopadhyay SS, Saju P, Biswas AK (1993) Selective removal of H2S from gases containing H2S and CO2 by absorption into aqueous-solutions of 2-amino-2-methyl-1-propanol. Ind Eng Chem Res 32:3051–3055CrossRefGoogle Scholar
  42. Samuel S, Aruni MD, Han X, Joan FB (2015) Effect of cation on physical properties and CO2 solubility for phosphonium-based ionic liquids with 2-cyanopyrrolide anions. J Phys Chem B 119(35):11807–11814CrossRefGoogle Scholar
  43. Satish K, Jae HCM (2014) Ionic liquid-amine blends and CO2 BOLs: prospective solvents for natural gas sweetening and CO2 capture technology—a review. Int J Greenhouse Gas Control 20:87–116CrossRefGoogle Scholar
  44. Sedghamiz MA, Rasoolzadeh A, Rahimpour MR (2015) The ability of artificial neural network in prediction of the acid gases solubility in different ionic liquids. J CO2 Util 9:39–47CrossRefGoogle Scholar
  45. Sergey L, Anna P, Magdalena KO (2003) Sound velocity and acoustic nonlinearity parameter for fluids. Thermodynamic premises. arXiv:physics/0303117Google Scholar
  46. Shaikh MS, Shariff AM, Bustam MA, Murshid G (2013) Physical properties of aqueous blends of sodium glycinate (SG) and piperazine (PZ) as a solvent for CO2 capture. J Chem Eng Data 58:634–638CrossRefGoogle Scholar
  47. Shokouhi M, Adibi M, Jalili AH, Hosseini-Jenab M, Mehdizadeh A (2010) Solubility and diffusion of H2S and CO2 in the ionic liquid 1-(2-hydroxyethyl)-3-methylimidazolium tetrafluoroborate. J Chem Eng Data 55:1663–1668CrossRefGoogle Scholar
  48. Versteeg GF, Swaalj WV (1988) Solubility and diffusivity of acid gases (carbon dioxide, nitrous oxide) in aqueous alkaloamines solutions. J Chem Eng Data 33:29–34CrossRefGoogle Scholar
  49. Wu S-T (1991) A semi empirical model for liquid-crystal refractive index dispersions. J Appl Phys 69(4):2080–2087CrossRefGoogle Scholar
  50. Xiao LY, Suo JZ, Xing ML (2007) Hydroxyl ammonium ionic liquids: synthesis, properties, and solubility of SO2. J Chem Eng Data 52:596–599CrossRefGoogle Scholar
  51. Xiao LY, Xiao YC, Rong XQ, Bao YP, Yi W, Min H, Jin QL, Jing YZ, Geng GL (2019) Enhanced CO2 capture by reducing cation–anion interactions in hydroxyl-pyridine anion-based ionic liquids. Dalton Trans 48:2300–2307CrossRefGoogle Scholar
  52. Yang ZY, Soriano AN, Caparanga AR, Li MH (2010) Equilibrium solubility of carbon dioxide in (2-amino-2-methyl-1-propanol + piperazine + water). J Chem Thermodynamics 42:659–665CrossRefGoogle Scholar
  53. Yuan X, Zhang S, Liu J, Lua X (2007) Solubilities of CO2 in hydroxyl ammonium ionic liquids at elevated pressures. Fluid Phase Equilib 257:195–200CrossRefGoogle Scholar
  54. Zhao Y, Zhang X, Zeng S, Zhou Q, Dong H, Tian X, Zhang S (2010) Density, viscosity, and performances of carbon dioxide capture in 16 absorbents of amine + ionic liquid + H2O, ionic liquid + H2O, and amine + H2O systems. J Chem Eng Data 55:3513–3519CrossRefGoogle Scholar
  55. Zhou Q, Wu Y, Chan CW, Tontiwachwuthikul P (2011) From neural network to neuro-fuzzy modeling: applications to the carbon dioxide capture process. Energy Procedia 4:2066–2073CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Sweta Balchandani
    • 1
    • 2
  • Bishnupada Mandal
    • 1
  • Swapnil Dharaskar
    • 2
    Email author
  • Arvind Kumar
    • 3
  • Syamalendu Bandyopadhyay
    • 2
  1. 1.Department of Chemical EngineeringIndian Institute of TechnologyGuwahatiIndia
  2. 2.Department of Chemical Engineering, School of TechnologyPandit Deendayal Petroleum UniversityGandhinagarIndia
  3. 3.Salt and Marine Chemicals DisciplineCSIR-Central Salt and Marine Chemicals Research InstituteBhavnagarIndia

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