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Copper(II) oxide nanoparticles coated cellulose sponge—an effective heterogeneous catalyst for the reduction of toxic organic dyes

  • Durgadevi Nagarajan
  • Swarnalatha VenkatanarasimhanEmail author
Research Article

Abstract

Discharge of unprocessed coloured waste water from industries gives rise to water contamination. In the current work, we propose the application of CuO nanoparticles supported on cellulose kitchen wipe sponge as a heterogeneous catalyst for the reductive decolourization of various toxic cationic and anionic dye molecules. The catalytic activity of the CuO nanoparticles under normal light for reduction has been examined in which sunlight irradiation is not necessitated. The CuO nanoparticles were synthesized by a simple wet chemical method and characterized using High Resolution Transmission Electron Microscope (HRTEM), SEM, EDX, XRD, XPS and TGA analyses. In the presence of CuO@CS catalyst and sodium borohydride, decolourization reaction of dyes such as acid red, acid green, methylene blue, rhodamine B and solochrome black-T was carried out. The catalytic reduction behaves as a pseudo-first-order reaction and is found to be superior in comparison with other reported catalysts in terms of reaction velocity. The reduction reaction can be further accelerated by increasing the reaction temperature. The developed catalyst drives the reduction faster on exposing the reaction mixture to sunlight confirming the usage of the catalyst at normal light and sunlight conditions. The catalyst retains 100% efficiency even after 5 cycles and remains suitable even for further use. Thus, a low-cost heterogeneous catalyst has been successfully developed and employed to decolourize various dye molecules in short duration with good recyclability and therefore can be used as the potential candidate in environmental remediation.

Keywords

Heterogeneous catalyst CuO nanoparticles Cellulose sponge Dye decolourization Catalytic reduction 

Notes

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

11356_2019_5419_MOESM1_ESM.docx (134 kb)
ESM 1 (DOCX 134 kb)

References

  1. Abderrahim B, Abderrahman E, Mohamed A et al (2015) Kinetic thermal degradation of cellulose , polybutylene succinate and a green composite: comparative study. World J Environ Eng 3:95–110.  https://doi.org/10.12691/wjee-3-4-1 Google Scholar
  2. Ai L, Zeng C, Wang Q (2011) One-step solvothermal synthesis of ag-Fe3O4 composite as a magnetically recyclable catalyst for reduction of Rhodamine B. Catal Commun 14:68–73.  https://doi.org/10.1016/j.catcom.2011.07.014 CrossRefGoogle Scholar
  3. Aksu Z, Tezer S (2005) Biosorption of reactive dyes on the green alga Chlorella vulgaris. Process Biochem 40:1347–1361.  https://doi.org/10.1016/j.procbio.2004.06.007 CrossRefGoogle Scholar
  4. Ali F, Bahadar S, Kamal T et al (2017a) Chemosphere bactericidal and catalytic performance of green nanocomposite based on chitosan/carbon black fiber supported monometallic and bimetallic nanoparticles. Chemosphere 188:588–598.  https://doi.org/10.1016/j.chemosphere.2017.08.118 CrossRefGoogle Scholar
  5. Ali F, Khan SB, Kamal T, Alamry KA, Asiri AM, Sobahi TRA (2017b) Chitosan coated cotton cloth supported zero-valent nanoparticles: simple but economically viable, efficient and easily retrievable catalysts. Sci Rep 7:1–16.  https://doi.org/10.1038/s41598-017-16815-2 CrossRefGoogle Scholar
  6. Ali F, Khan SB, Kamal T, Alamry KA, Bakhsh EM, Asiri AM, Sobahi TRA (2018) Synthesis and characterization of metal nanoparticles templated chitosan-SiO2 catalyst for the reduction of nitrophenols and dyes. Carbohydr Polym 192:217–230.  https://doi.org/10.1016/j.carbpol.2018.03.029 CrossRefGoogle Scholar
  7. Anandkumar J, Mandal B (2011) Adsorption of chromium(VI) and Rhodamine B by surface modified tannery waste: kinetic, mechanistic and thermodynamic studies. J Hazard Mater 186:1088–1096.  https://doi.org/10.1016/j.jhazmat.2010.11.104 CrossRefGoogle Scholar
  8. Basak S (2014) Synthesis of chiral, crystalline Au-nanoflower catalyst assisting conversion of Rhodamine-B to Rhodamine-110 and a single step, one pot, eco-friendly reduction of nitroarenes. J Phys Chem C 119:1800–1808.  https://doi.org/10.1021/jp5086125 Google Scholar
  9. Chang M, Shu H, Yu H, Sung Y (2006) Reductive decolourization and total organic carbon reduction of the diazo dye CI Acid Black 24 by zero-valent iron. J Chem Technol Biotechnol 1266:1259–1266.  https://doi.org/10.1002/jctb CrossRefGoogle Scholar
  10. Chawla S, Uppal H, Yadav M, Bahadur N, Singh N (2017) Zinc peroxide nanomaterial as an adsorbent for removal of Congo red dye from waste water. Ecotoxicol Environ Saf 135:68–74.  https://doi.org/10.1016/j.ecoenv.2016.09.017 CrossRefGoogle Scholar
  11. Dahiya JB, Rana S (2004) Thermal degradation and morphological studies on cotton cellulose modified with various arylphosphorodichloridites. Polym Int 53:995–1002.  https://doi.org/10.1002/pi.1500 CrossRefGoogle Scholar
  12. Deng J-P, Shih W-C, Mou C-Y (2007) Electron transfer-induced hydrogenation of anthracene catalyzed by gold and silver nanoparticles. J Phys Chem C 111:9723–9728.  https://doi.org/10.1021/jp0690042 CrossRefGoogle Scholar
  13. El-Sheikh SM, Ismail AA, Al-Sharab JF (2013) Catalytic reduction of p-nitrophenol over precious metals/highly ordered mesoporous silica. New J Chem 37:2399–2407.  https://doi.org/10.1039/C3NJ00138E CrossRefGoogle Scholar
  14. Ethiraj AS, Kang DJ (2012) Synthesis and characterization of CuO nanowires by a simple wet chemical method. Nanoscale Res Lett 7:70.  https://doi.org/10.1186/1556-276X-7-70 CrossRefGoogle Scholar
  15. Gao D, Zhang J, Zhu J, Qi J, Zhang Z, Sui W, Shi H, Xue D (2010) Vacancy-mediated magnetism in pure copper oxide nanoparticles. Nanoscale Res Lett 5:769–772.  https://doi.org/10.1007/s11671-010-9555-8 CrossRefGoogle Scholar
  16. Ghosh SK, Mandal M, Kundu S et al (2004) Bimetallic Pt–Ni nanoparticles can catalyze reduction of aromatic nitro compounds by sodium borohydride in aqueous solution. Appl Catal A Gen 268:61–66.  https://doi.org/10.1016/j.apcata.2004.03.017 CrossRefGoogle Scholar
  17. Gooch J, Abbate V, Daniel B, Frascione N (2016) Solid-phase synthesis of Rhodamine-110 fluorogenic substrates and their application in forensic analysis. Analyst 141:2392–2395.  https://doi.org/10.1039/C6AN00686H CrossRefGoogle Scholar
  18. Gupta VK, Jain R, Nayak A, Agarwal S, Shrivastava M (2011) Removal of the hazardous dye—tartrazine by photodegradation on titanium dioxide surface. Mater Sci Eng C 31:1062–1067.  https://doi.org/10.1016/j.msec.2011.03.006 CrossRefGoogle Scholar
  19. He Z, Sun C, Yang S, Ding Y, He H, Wang Z (2009) Photocatalytic degradation of rhodamine B by Bi2WO6 with electron accepting agent under microwave irradiation: mechanism and pathway. J Hazard Mater 162:1477–1486.  https://doi.org/10.1016/j.jhazmat.2008.06.047 CrossRefGoogle Scholar
  20. Ibupoto Z, Khun K, Beni V, Liu X, Willander M (2013) Synthesis of novel CuO nanosheets and their non-enzymatic glucose sensing applications. Sensors 13:7926–7938.  https://doi.org/10.3390/s130607926 CrossRefGoogle Scholar
  21. Kamal T, Bahadar S, Asiri AM (2016) Synthesis of zero-valent Cu nanoparticles in the chitosan coating layer on cellulose microfibers: evaluation of azo dyes catalytic reduction. Cellulose 23:1911–1923.  https://doi.org/10.1007/s10570-016-0919-9 CrossRefGoogle Scholar
  22. Kumar A, Saxena A, De A et al (2013) Facile synthesis of size-tunable copper and copper oxide nanoparticles using reverse microemulsions. RSC Adv 3:5015.  https://doi.org/10.1039/c3ra23455j CrossRefGoogle Scholar
  23. Kumar B, Hazra S, Naik B, Nath N (2015) Preparation of cu nanoparticle loaded SBA-15 and their excellent catalytic activity in reduction of variety of dyes. Powder Technol 269:371–378.  https://doi.org/10.1016/j.powtec.2014.09.027 CrossRefGoogle Scholar
  24. Kuroda K, Ishida T, Haruta M (2009) Reduction of 4-nitrophenol to 4-aminophenol over Au nanoparticles deposited on PMMA. J Mol Catal A Chem 298:7–11.  https://doi.org/10.1016/j.molcata.2008.09.009 CrossRefGoogle Scholar
  25. Li S, Li H, Liu J, Zhang H, Yang Y, Yang Z, Wang L, Wang B (2015) Highly efficient degradation of organic dyes by palladium nanoparticles decorated on 2D magnetic reduced graphene oxide nanosheets. Dalton Trans 44:9193–9199.  https://doi.org/10.1039/C5DT01036E CrossRefGoogle Scholar
  26. Mogha NK, Gosain S, Masram DT (2017) Gold nanoworms immobilized graphene oxide polymer brush nanohybrid for catalytic degradation studies of organic dyes. Appl Surf Sci 396:1427–1434.  https://doi.org/10.1016/j.apsusc.2016.11.182 CrossRefGoogle Scholar
  27. Nacèra Y, Aicha B (2006) Equilibrium and kinetic modelling of methylene blue biosorption by pretreated dead Streptomyces rimosus: effect of temperature. Chem Eng J 119:121–125.  https://doi.org/10.1016/j.cej.2006.01.018 CrossRefGoogle Scholar
  28. Naduparambath S, Jinitha TV, Shaniba V et al (2018) Isolation and characterisation of cellulose nanocrystals from sago seed shells. Carbohydr Polym 180:13–20.  https://doi.org/10.1016/j.carbpol.2017.09.088 CrossRefGoogle Scholar
  29. Narasaiah P, Mandal BKSN (2017) Green synthesis of Pd NPs from Pimpinella tirupatiensis plant extract and their application in photocatalytic activity dye degradation. IOP Conf Series Mater Sci Eng 263:1–12.  https://doi.org/10.1088/1757-899X/263/2/022013 Google Scholar
  30. Peng Y, Fu D, Liu R, Zhang F, Liang X (2008) NaNO2/FeCl3 catalyzed wet oxidation of the azo dye Acid Orange 7. Chemosphere 71:990–997.  https://doi.org/10.1016/j.chemosphere.2007.10.065 CrossRefGoogle Scholar
  31. Perotti GF, Barud HS, Ribeiro SJL, Constantino VRL (2014) Bacterial cellulose as a template for preparation of hydrotalcite-like compounds. J Braz Chem Soc 25:1647–1655.  https://doi.org/10.5935/0103-5053.20140153 Google Scholar
  32. Riera-Torres M, Gutiérrez-Bouzán C, Crespi M (2010) Combination of coagulation–flocculation and nanofiltration techniques for dye removal and water reuse in textile effluents. Desalination 252:53–59.  https://doi.org/10.1016/j.desal.2009.11.002 CrossRefGoogle Scholar
  33. Saha J, Begum A, Mukherjee A, Kumar S (2017) A novel green synthesis of silver nanoparticles and their catalytic action in reduction of Methylene Blue dye. Sustain Environ Res 27:245–250.  https://doi.org/10.1016/j.serj.2017.04.003 CrossRefGoogle Scholar
  34. Sahoo PK, Thakur D, Bahadur D, Panigrahy B (2016) Highly efficient and simultaneous catalytic reduction of multiple dyes using recyclable RGO/Co dendritic nanocomposites as catalyst for wastewater treatment. RSC Adv 6:106723–106731.  https://doi.org/10.1039/C6RA23621A CrossRefGoogle Scholar
  35. Saikia P, Miah AT, Das PP (2017) Highly efficient catalytic reductive degradation of various organic dyes by Au/CeO2-TiO2 nano-hybrid. J Chem Sci 129:81–93.  https://doi.org/10.1007/s12039-016-1203-0 CrossRefGoogle Scholar
  36. Sangpour P, Hashemi F, Moshfegh AZ (2010) Photoenhanced degradation of methylene blue on cosputtered M:TiO2 (M = Au, Ag, Cu) nanocomposite systems: a comparative study. J Phys Chem C 114:13955–13961.  https://doi.org/10.1021/jp910454r CrossRefGoogle Scholar
  37. Saravanan C, Rajesh R, Kaviarasan T, Muthukumar K, Kavitake D, Shetty PH (2017) Synthesis of silver nanoparticles using bacterial exopolysaccharide and its application for degradation of azo-dyes synthesis of silver nanoparticles using bacterial exopolysaccharide and its application for degradation of azo-dyes. Biotechnology. 15:11–19.  https://doi.org/10.1016/j.btre.2017.02.006 Google Scholar
  38. Shaffiey SF, Shapoori M, Bozorgnia A, Ahmadi M (2014) Synthesis and evaluation of bactericidal properties of CuO nanoparticles against Aeromonas hydrophila. Nanomed J 1:198–204Google Scholar
  39. Stoyanova M, Slavova I, Christoskova S, Ivanova V (2014) Catalytic performance of supported nanosized cobalt and iron-cobalt mixed oxides on MgO in oxidative degradation of Acid Orange 7 azo dye with peroxymonosulfate. Appl Catal A Gen 476:121–132.  https://doi.org/10.1016/j.apcata.2014.02.024 CrossRefGoogle Scholar
  40. Thekkae Padil V, Cernik M (2013) Green synthesis of copper oxide nanoparticles using gum karaya as a biotemplate and their antibacterial application. Int J Nanomedicine 8:889–898.  https://doi.org/10.2147/IJN.S40599 Google Scholar
  41. Trivedi MK, Nayak G, Shrikant P et al (2015) Impact of biofield treatment on chemical and thermal properties of cellulose and cellulose acetate. Bioeng Biomed Sci 5:162.  https://doi.org/10.4172/2155-9538.1000162 Google Scholar
  42. Vainio U, Pirkkalainen K, Kisko K, Goerigk G, Kotelnikova NE, Serimaa R (2007) Copper and copper oxide nanoparticles in a cellulose support studied using anomalous small-angle X-ray scattering. Eur Phys J D 42:93–101CrossRefGoogle Scholar
  43. Vasquez RP (1998) CuO by XPS. Surf Sci Spectra 5:262–266.  https://doi.org/10.1116/1.1247882 CrossRefGoogle Scholar
  44. Vinodgopal K, Bedja I (1994) Of textile azo dyes in colloidal semiconductor suspensions. Langmuir 10:1767–1771CrossRefGoogle Scholar
  45. Vinothkannan M, Karthikeyan C, Gnana Kumar G et al (2015) One-pot green synthesis of reduced graphene oxide (RGO)/Fe3O4nanocomposites and its catalytic activity toward methylene blue dye degradation. Spectrochim Acta A Mol Biomol Spectrosc 136:256–264.  https://doi.org/10.1016/j.saa.2014.09.031 CrossRefGoogle Scholar
  46. Wang C, Tang K, Wang D, Liu Z, Wang L (2012) Simple self-assembly of HLaNb2O7 nanosheets and ag nanoparticles/clusters and their catalytic properties. J Mater Chem 22:22929–22934.  https://doi.org/10.1039/c2jm34321e CrossRefGoogle Scholar
  47. Wang N, Hu Y, Zhang Z (2017) Sustainable catalytic properties of silver nanoparticles supported montmorillonite for highly efficient recyclable reduction of methylene blue. Appl Clay Sci 150:47–55.  https://doi.org/10.1016/j.clay.2017.08.024 CrossRefGoogle Scholar
  48. Yu K, Yang S, He H, Sun C, Gu C, Ju Y (2009) Visible light-driven photocatalytic degradation of Rhodamine B over NaBiO3: pathways and mechanism. J Phys Chem A 113:10024–10032CrossRefGoogle Scholar
  49. Yun H, He Z, Xinfu P, Shaofei W, (1989) Reduction with Metal Borohydride-Transition Metal Salt System. I. Reduction of Aromatic Nitro Compunds with Potassium Borohydride-Copper(I) Chloride. Synth Commun 3047–3050.  https://doi.org/10.1080/00397918908052699
  50. Zhang XF, Zhang Y, Liu L (2014) Fluorescence lifetimes and quantum yields of ten rhodamine derivatives: structural effect on emission mechanism in different solvents. J Lumin 145:448–453.  https://doi.org/10.1016/j.jlumin.2013.07.066 CrossRefGoogle Scholar
  51. Zhong HE, Shaogui Y, Yongming JU, Cheng SUN (2009) Microwave photocatalytic degradation of Rhodamine B using TiO2 supported on activated carbon: mechanism implication. J Environ Sci 21:268–272.  https://doi.org/10.1016/S1001-0742(08)62262-7 CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Department of Sciences, Amrita School of EngineeringAmrita Vishwa VidyapeethamCoimbatoreIndia

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