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Aminosilane-grafted spherical cellulose nanocrystal aerogel with high CO2 adsorption capacity

  • Tianmeng Zhang
  • Yang ZhangEmail author
  • Hua Jiang
  • Xiaoyu Wang
Research Article
  • 51 Downloads

Abstract

In this study, the cellulose nanocrystals (CNC) obtained by acid hydrolysis of microcrystalline cellulose (MCC) are customized by suspension to obtain a spherical CNC hydrogel. The N-(2-aminoethyl) (3-amino-propyl) methyldimethoxyansile (AEAPMDS) preparation was grafted to spherical CNC hydrogel using a water phase heat treatment. Finally, aerogel samples were obtained by tert-butanol replacement and freeze-drying. The test results confirmed that the aminosilane was grafted on CNC. Electron micrographs and N2 sorption isotherms showed that the pores of the aerogel were partially blocked due to the introduction of AEAPMDS, and the specific surface area was decreased. Due to the presence of chemisorption, the amount of CO2 adsorbed at a pressure of 3 bar by the modified aerogel (2.63 mmol/g) was greatly improved compared with the unmodified aerogel (0.26 mmol/g), and the adsorption results were fit well by the Langmuir model. Thus, our experiments provided the opportunity to develop a new CO2 absorbent material.

Keywords

Cellulose nanocrystal Aerogel Graft CO2 adsorption 

Notes

Funding information

This work was financially supported by the Special Fund for Forest Scientific Research in the Public Welfare (201504603).

Supplementary material

11356_2019_5068_MOESM1_ESM.docx (813 kb)
ESM 1 (DOCX 812 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Tianmeng Zhang
    • 1
  • Yang Zhang
    • 1
    Email author
  • Hua Jiang
    • 2
  • Xiaoyu Wang
    • 1
  1. 1.College of Materials Science and EngineeringNanjing Forestry UniversityNanjingPeople’s Republic of China
  2. 2.College of Chemical EngineeringNanjing Forestry UniversityNanjingPeople’s Republic of China

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