Environmental Science and Pollution Research

, Volume 26, Issue 7, pp 6811–6817 | Cite as

Preparation and characterization of activated carbon produced from tannery solid waste applied for tannery wastewater treatment

  • Bianca MellaEmail author
  • Jaqueline Benvenuti
  • Renata F. Oliveira
  • Mariliz Gutterres
Philippe Garrigues


The removal of toxic compounds (azo dyes) from dyeing wastewater was investigated by an environmentally friendly activated carbon produced from solid waste generated in the tannery process, the cattle hair (CHW), activated with H3PO4 (AC-CHW), suggesting a life cycle extension for this material from leather processing. Preliminary tests with aqueous solutions containing Acid Brown 414 (AB-414) and Acid Orange 142 (AO-142) removed 71.06% and 73.05%, respectively. The activated carbon was characterized by zeta potential (ZP), functional groups (FTIR), elemental composition, sorbent specific surface area, and pore size distribution (BET/BJH). The specific surface area showed low values when compared to commercial activated carbon, but average pore diameter was higher, which facilitates the adsorption of larger and complex molecules, such as those present in real wastewaters. Through SEM and FTIR, the presence of the toxic compounds studied in the AC-CHW after sorption process was observed, where the results indicated that the functional groups of -CH=CH- participated in the removal process for these compounds. The removal efficiency obtained with AC-CHW was 51.94% and 49.73% for the dyeing wastewater containing AB-414 and AO-142, respectively. The obtained results open a promising via to use AC-CHW as efficient eco-friendly sorbent for the treatment of leather wastewater.


Activated carbon Adsorption Dye Leather solid waste Tannery wastewater 



We would like to thank the scholarships provided by Brazilian Federal Agency for the Scholarship (CAPES) and to Financier of Studies and Projects (FINEP)—public call MCTI/FINEP CT-HIDRO 01/2013. We are also grateful to Tannery Fridolino Ritter Ltda for the samples of cattle hair waste.


  1. Alvarez J, Lopez G, Amutio M, Bilbao J, Olazar M (2014) Upgrading the rice husk char obtained by flash pyrolysis for the production of amorphous silica and high quality activated carbon. Bioresour Technol 170:132–137CrossRefGoogle Scholar
  2. Andrioli E, Petry L, Gutterres M (2015) Environmentally friendly hide unhairing: enzymatic-oxidative unhairing as an alternative to use of lime and sodium sulfide. Proc Saf Env Protec 93:9–17CrossRefGoogle Scholar
  3. da Silva LG, Ruggiero R, Gontijo PM, Pinto RB, Royer B, Lima EC, Fernandes THM, Calvete T (2011) Adsorption of Brilliant Red 2BE dye from water solutions by a chemically modified sugarcane bagasse lignin. Chem Eng J 168:620–628CrossRefGoogle Scholar
  4. Dai H, Huang H (2016) Modified pineapple peel cellulose hydrogels embedded with sepia ink for effective removal of methylene blue. Carbohydr Polym 148:1–10CrossRefGoogle Scholar
  5. Das SK, Khan MMR, Parandhaman T, Laffir F, Guha AK, Sekarana G, Mandal AB (2013) Nano-silica fabricated with silver nanoparticles: antifouling adsorbent for efficient dye removal, effective water disinfection and biofouling control. Nanoscale 5:5549–5560CrossRefGoogle Scholar
  6. De Gisi S, Lofrano G, Grassi M, Notarnicola M (2016) Characteristics and adsorption capacities of low-cost sorbents for wastewater treatment: a review. Sustain Mater Technol 9:10–40Google Scholar
  7. Doke KM, Khan EM (2017) Equilibrium, kinetic and diffusion mechanism of Cr(VI) adsorption onto activated carbon derived from wood apple shell. Arab J Chem 10:S252CrossRefGoogle Scholar
  8. dos Santos DC, Adebayo MA, Pereira SFP, Prola LDT, Cataluña R, Lima EC, Saucier C, Gally C, Machado F (2014) New carbon composite adsorbents for the removal of textiles dyes form aqueous solutions: kinetic, equilibrium and thermodynamic studies. Korean J Chem Eng 31:1470–1479CrossRefGoogle Scholar
  9. Jiang Z, Lin Y, Sun X, Tain F, Sun F, Liang C, You W, Han C, Li C (2013) Chromium (VI) removal from aqueous system using Helianthus annuus (sunflower) stem waste. Langmuir 19:731CrossRefGoogle Scholar
  10. Kacan E (2016) Optimum BET surface areas for activated carbon produced from textile sewage sludges and its application as dye removal. J Environ Manag 166:116–123CrossRefGoogle Scholar
  11. Kilic M, Apaydin-Varol E, Pütün AE (2011) Adsorptive removal of phenol from aqueous solutions on activated carbon prepared from tobacco residues: equilibrium, kinetics and thermodynamics. J Hazard Mater 189:397–403CrossRefGoogle Scholar
  12. Mattson JS, Mark HBJ (1971) Activated carbon surface chemistry and adsorption from solution. Marcel Dekker, Inc., New YorkGoogle Scholar
  13. Mella B, Gutterres M (2017) Preparation and characterisation of tannery solid waste as an alternative biosorbent for leather dyes. J Soc Leather Technol Chem 101:143Google Scholar
  14. Mella B, Puchana-Rosero MJ, Costa DES, Gutterres M (2017) Utilization of tannery solid waste as an alternative biosorbent for acid dyes in wastewater treatment. J Mol Liq 242:137–145CrossRefGoogle Scholar
  15. Piccin JS, Gomes CS, Mella B, Gutterres M (2016) Color removal from real leather dyeing effluent using tannery waste as an adsorbent. J Environ Chem Eng 4:1061–1067CrossRefGoogle Scholar
  16. Piccin JS, Guterres M, Salau NPG, Dotto GL (2017) Mass transfer models for the adsorption of Acid Red 357 and Acid Black 210 by tannery solid wastes. Adsorpit Sci Technol 35:300–3016CrossRefGoogle Scholar
  17. Prola LDT, Acayanka E, Lima EC, Umpierres CS, Vaghetti JCP, Santos WO, Laminsi S, Njifon PT (2013) Comparison of Jatropha curcas shells in natural form and treated by non-thermal plasma as biosorbents for removal of Reactive Red 120 textile dye from aqueous solution. Ind Crop Prod 46:328–340CrossRefGoogle Scholar
  18. Puchana-Rosero MJ, Adebayo MA, Lima EC, Machado FM, Thue PS, Vaghetti JCP, Umpierres CS, Gutterres M (2016) Microwave-assisted activated carbon obtained from the sludge of tannery-treatment effluent plant for removal of leather dyes. Colloids Surf A Physicochem Eng Asp 504:105–115CrossRefGoogle Scholar
  19. Rengarag S, Moon SH, Sivabalan S, Arabindoo B, Murugesan V (2002) Agricultural solid waste for the removal of organics: adsorption of phenol from water and wastewater by palm seed coat activated carbon. Waste Manag 22:543–548CrossRefGoogle Scholar
  20. Rovani S, Censi MT, Pedrotti SL, Lima ÉC, Cataluña R, Fernandes AN (2014) Development of a new adsorbent from agro-industrial waste and its potential use in endocrine disruptor compound removal. J Hazard Mater 271:311–320CrossRefGoogle Scholar
  21. dos Santos DC, Adebayo MA, Lima EC, Pereira SFP, Cataluña R, Saucier C, Thue PS, Machado FM (2015) Application of carbon composite adsorbents prepared from coffee waste and clay for the removal of reactive dyes from aqueous solutions. J Braz Chem Soc 26:924Google Scholar
  22. Sekaran G, Shanmugasundaram KA, Mariappan M (1998) Characterization and utilisation of buffing dust generated by the leather industry. J Hazard Mater B 63:53–68CrossRefGoogle Scholar
  23. Sing KSW (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (recommendations 1984). Pure Appl Chem 57:603–619CrossRefGoogle Scholar
  24. Smisek M, Cerney S (1970) Active carbon: manufacture, properties and applications. Elsevier, AmsterdamGoogle Scholar
  25. Tomic NM, Dohcevic-Mitrovic ZD, Paunovic NM, Mijin DZ, Radic ND, Grbic BV, Askrabic SM, Babic BM, Bajuk-Bogdanovic DV (2014) NanocrystallineCeO2 as effective adsorbent of azo dyes. Langmuir 30:11582–11590CrossRefGoogle Scholar
  26. Wen G, Pan Z, Ma J, Liu Z, Zhao L, Li J (2012) Reuse of sewage sludge as a catalyst in ozonation—efficiency for the removal of oxalic acid and the control of bromate formation. J Hazard Mater 239:381CrossRefGoogle Scholar
  27. Yagub MT, Sen TK, Afroze S, Ang HM (2014) Dye and its removal from aqueous solution by adsorption: a review. Adv Colloid Interf Sci 209:172–184CrossRefGoogle Scholar
  28. Yılmaz O, Cem Kantarli I, Yuksel M, Saglam M, Yanik J (2007) Conversion of leather wastes to useful products. Resour Conserv Recycl 49:436–448CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Laboratory for Leather and Environmental Studies (LACOURO), Chemical Engineering Post-Graduated Program (PPGEQ)Federal University of Rio Grande do Sul (UFRGS)Porto AlegreBrazil
  2. 2.Chemical Engineering Post-Graduated Program (PPGEQ)Federal University of Rio Grande do Sul (UFRGS)Porto AlegreBrazil
  3. 3.Lutheran University of Brazil (ULBRA)CanoasBrazil

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