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Environmental Science and Pollution Research

, Volume 25, Issue 36, pp 36267–36277 | Cite as

Synthesis and characterization of citrate intercalated layered double hydroxide as a green adsorbent for Ni2+ and Pb2+ removal

  • Omid Rahmanian
  • Mohammad Dinari
  • Sima Neamati
Research Article
  • 69 Downloads

Abstract

Recently, a considerable attention has been paid on the preparation of layered double hydroxide (LDH) as a green adsorbent. This research presents a study on nickel and lead removal by Ca/Fe layered double hydroxides intercalate with citrate anions (Ca-Fe/LDH-Cit) which was successfully prepared through the co-precipitation and hydrothermal method. The as-synthesized Ca-Fe/LDH-Cit was characterized by various techniques including FT-IR, XRD, TGA, FE-SEM, and TEM techniques. The maximum uptake capacities of Ca-Fe/LDH-Cit were 2.26 mg/g for Ni(II) and 61.73 mg/g for Pb(II) inferred from the Langmuir model at the contact time of 30 min and pH of 7. Based on the results, the adsorption and kinetic isotherms were in good agreement with the Langmuir model and the pseudo-second-order equation, respectively. The results suggested that the composite adsorbent has the good ability to remove the Ni2+ and Pb2+ ions from aqueous solutions. The results reveal that the composite adsorbent can be considered as a high-capacity absorbent for Ni(II) and Pb(II) removal and also as a potential candidate for practical applications.

Keywords

Ca/Fe layered double hydroxides Citrate anions Green adsorbent Heavy metals removal Isotherms 

Notes

Acknowledgments

We wish to express our gratitude to the Research Affairs Division Isfahan University of Technology (IUT), Isfahan, and Hormozgan University of Medical Sciences, Bandar Abbas, Iran for partial financial support.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflicts of interest.

References

  1. Al Rub FA, Kandah M, Al Dabaybeh N (2002) Nickel removal from aqueous solutions using sheep manure wastes. Eng Life Sci 2:111–116CrossRefGoogle Scholar
  2. Bagheri AR, Ghaedi M, Asfaram A, Bazrafshan AA, Jannesar R (2017) Comparative study on ultrasonic assisted adsorption of dyes from single system onto Fe3O4 magnetite nanoparticles loaded on activated carbon: experimental design methodology. Ultrason Sonochem 34:294–304CrossRefGoogle Scholar
  3. Basu D, Das A, Stöckelhuber KW, Wagenknecht U, Heinrich G (2014) Advances in layered double hydroxide (LDH)-based elastomer composites. Prog Polym Sci 39:594–626CrossRefGoogle Scholar
  4. Choudary BM, Madhi S, Chowdari NS, Kantam ML, Sreedhar B (2002) Layered double hydroxide supported nanopalladium catalyst for Heck-, Suzuki-, Sonogashira-, and Stille-type coupling reactions of chloroarenes. J Am Chem Soc 124:14127–14136CrossRefGoogle Scholar
  5. Deng L, Shi Z, Peng XY (2015) Adsorption of Cr(VI) onto a magnetic CoFe2O4/MgAl-LDH composite and mechanism study. RSC Adv 5:49791–49801CrossRefGoogle Scholar
  6. Deng L, Shi Z, Wang L, Zhou S (2017) Fabrication of a novel NiFe2O4/Zn-Al layered double hydroxide intercalated with EDTA composite and its adsorption behavior for Cr(VI) from aqueous solution. J Phys Chem Solids 104:79–90CrossRefGoogle Scholar
  7. Dinari M, Haghighi A (2018) Ultrasound-assisted synthesis of nanocomposites based on aromatic polyamide and modified ZnO nanoparticle for removal of toxic Cr (VI) from water. Ultrason Sonochem 41:75–84CrossRefGoogle Scholar
  8. Dinari M, Nabiyan A (2017) Citric acid-modified layered double hydroxides as a green reinforcing agent for improving thermal and mechanical properties of poly(vinyl alcohol)-based nanocomposite films. Polym Compos 38:E128–E136CrossRefGoogle Scholar
  9. Dinari M, Asadi P, Khajeh S (2015) In situ thermal synthesis of novel polyimide nanocomposite films containing organo-modified layered double hydroxide: morphological, thermal and mechanical properties. New J Chem 39:8195–8203CrossRefGoogle Scholar
  10. Ding D, Zhang Z, Chen R, Cai T (2017) Selective removal of cesium by ammonium molybdophosphate – polyacrylonitrile bead and membrane. J Hazard Mater 324:753–761CrossRefGoogle Scholar
  11. Dong C, Zhang H, Pang Z, Liu Y, Zhang F (2013) Sulfonated modification of cotton linter and its application as adsorbent for high-efficiency removal of lead (II) in effluent. Bioresour Technol 146:512–518CrossRefGoogle Scholar
  12. Duan X, Evans DG (2006): Layered double hydroxides, 119. Springer Science & Business MediaGoogle Scholar
  13. Fahel J, Kim S, Durand P, André E, Carteret C (2016) Enhanced catalytic oxidation ability of ternary layered double hydroxides for organic pollutants degradation. Dalton Trans 45:8224–8235CrossRefGoogle Scholar
  14. González M, Pavlovic I, Barriga C (2015) Cu (II), Pb (II) and Cd (II) sorption on different layered double hydroxides. A kinetic and thermodynamic study and competing factors. Chem Eng J 269:221–228CrossRefGoogle Scholar
  15. Gündüz F, Bayrak B (2017) Biosorption of malachite green from an aqueous solution using pomegranate peel: equilibrium modelling, kinetic and thermodynamic studies. J Mol Liq 243:790–798CrossRefGoogle Scholar
  16. Guo F, Zhong Z (2018) Pollution emission and heavy metal speciation from co-combustion of sedum plumbizincicola and sludge in fluidized bed. J Clean Prod 179:317–324CrossRefGoogle Scholar
  17. He J, Wei M, Li B, Kang Y, Evans DG, Duan X (2006): Preparation of layered double hydroxides, layered double hydroxides. Springer, pp. 89–119Google Scholar
  18. Islam MS, Hossain MB, Matin A, Islam Sarker MS (2018) Assessment of heavy metal pollution, distribution and source apportionment in the sediment from Feni River estuary, Bangladesh. Chemosphere 202:25–32CrossRefGoogle Scholar
  19. Jafari K, Heidari M, Rahmanian O (2018) Wastewater treatment for Amoxicillin removal using magnetic adsorbent synthesized by ultrasound process. Ultrason Sonochem 45:248–256CrossRefGoogle Scholar
  20. Jiang J-Q, Ashekuzaman S (2015) Preparation and evaluation of layered double hydroxides (LDHs) for phosphate removal. Desalin Water Treat 55:836–843CrossRefGoogle Scholar
  21. Khan AI, O’Hare D (2002) Intercalation chemistry of layered double hydroxides: recent developments and applications. J Mater Chem 12:3191–3198CrossRefGoogle Scholar
  22. Konicki W, Pelka R, Arabczyk W (2016) Adsorption of Ni2+ from aqueous solution by magnetic Fe@ graphite nano-composite. Pol J Chem Technol 18:96–103CrossRefGoogle Scholar
  23. Krishnani KK, Meng X, Christodoulatos C, Boddu VM (2008) Biosorption mechanism of nine different heavy metals onto biomatrix from rice husk. J Hazard Mater 153:1222–1234CrossRefGoogle Scholar
  24. Kulkarni VV, Golder AK, Ghosh PK (2018) Synthesis and characterization of carboxylic cation exchange bio-resin for heavy metal remediation. J Hazard Mater 341:207–217CrossRefGoogle Scholar
  25. Lei C, Zhu X, Zhu B, Jiang C, Le Y, Yu J (2017) Superb adsorption capacity of hierarchical calcined Ni/Mg/Al layered double hydroxides for Congo red and Cr (VI) ions. J Hazard Mater 321:801–811CrossRefGoogle Scholar
  26. Li Z, Kong Y, Ge Y (2015) Synthesis of porous lignin xanthate resin for Pb2+ removal from aqueous solution. Chem Eng J 270:229–234CrossRefGoogle Scholar
  27. Luo M, Lin H, Li B, Dong Y, He Y, Wang L (2018) A novel modification of lignin on corncob-based biochar to enhance removal of cadmium from water. Bioresour Technol 259:312–318CrossRefGoogle Scholar
  28. Lyu H, Gong Y, Tang J, Huang Y, Wang Q (2016) Immobilization of heavy metals in electroplating sludge by biochar and iron sulfide. Environ Sci Pollut Res 23:14472–14488CrossRefGoogle Scholar
  29. Mallakpour S, Dinari M (2015) Intercalation of amino acid containing chiral dicarboxylic acid between Mg–Al layered double hydroxide. J Therm Anal Calorim 119:1123–1130CrossRefGoogle Scholar
  30. Morosanu I, Teodosiu C, Paduraru C, Ibanescu D, Tofan L (2017) Biosorption of lead ions from aqueous effluents by rapeseed biomass. New Biotechnol 39:110–124CrossRefGoogle Scholar
  31. Pérez M, Pavlovic I, Barriga C, Cornejo J, Hermosin M, Ulibarri M (2006) Uptake of Cu2+, Cd2+ and Pb2+ on Zn–Al layered double hydroxide intercalated with EDTA. Appl Clay Sci 32:245–251CrossRefGoogle Scholar
  32. Qian JW, Li DP, Zhan GQ, Zhang L, Su WT, Gao P (2012) Simultaneous biodegradation of Ni–citrate complexes and removal of nickel from solutions by Pseudomonas alcaliphila. Bioresour Technol 116:66–73CrossRefGoogle Scholar
  33. Qu L, Huang H, Xia F, Liu Y, Dahlgren RA, Zhang M, Mei K (2018) Risk analysis of heavy metal concentration in surface waters across the rural-urban interface of the Wen-Rui Tang River, China. Environ Pollut 237:639–649CrossRefGoogle Scholar
  34. Rahmanian O, Amini S, Dinari M (2018a) Preparation of zinc/iron layered double hydroxide intercalated by citrate anion for capturing Lead (II) from aqueous solution. J Mol Liq 256:9–15CrossRefGoogle Scholar
  35. Rahmanian O, Dinari M, Abdolmaleki MK (2018b) Carbon quantum dots/layered double hydroxide hybrid for fast and efficient decontamination of Cd (II): the adsorption kinetics and isotherms. Appl Surf Sci 428:272–279CrossRefGoogle Scholar
  36. Rahmanian O, Maleki MH, Dinari M (2017) Ultrasonically assisted solvothermal synthesis of novel Ni/Al layered double hydroxide for capturing of Cd(II) from contaminated water. J Phys Chem Solids 110:195–201CrossRefGoogle Scholar
  37. Reguyal F, Sarmah AK (2018) Adsorption of sulfamethoxazole by magnetic biochar: effects of pH, ionic strength, natural organic matter and 17α-ethinylestradiol. Sci Total Environ 628-629:722–730CrossRefGoogle Scholar
  38. Rosa LMT, Botero WG, Santos JCC, Cacuro TA, Waldman WR, do Carmo JB, de Oliveira LC (2018) Natural organic matter residue as a low cost adsorbent for aluminum. J Environ Manag 215:91–99CrossRefGoogle Scholar
  39. Shukla SR, Pai RS (2005) Adsorption of Cu(II), Ni(II) and Zn(II) on modified jute fibres. Bioresour Technol 96:1430–1438CrossRefGoogle Scholar
  40. Son H-J, Jin S, Patwardhan S, Wezenberg SJ, Jeong NC, So M, Wilmer CE, Sarjeant AA, Schatz GC, Snurr RQ (2013) Light-harvesting and ultrafast energy migration in porphyrin-based metal–organic frameworks. J Am Chem Soc 135:862–869CrossRefGoogle Scholar
  41. Tan L, Wang Y, Liu Q, Wang J, Jing X, Liu L, Liu J, Song D (2015) Enhanced adsorption of uranium (VI) using a three-dimensional layered double hydroxide/graphene hybrid material. Chem Eng J 259:752–760CrossRefGoogle Scholar
  42. Tomina VV, Stolyarchuk NV, Melnyk IV, Zub YL, Kouznetsova TF, Prozorovich VG, Ivanets AI (2017) Composite sorbents based on porous ceramic substrate and hybrid amino- and mercapto-silica materials for Ni(II) and Pb(II) ions removal. Sep Purif Technol 175:391–398CrossRefGoogle Scholar
  43. Visa M, Chelaru AM (2014) Hydrothermally modified fly ash for heavy metals and dyes removal in advanced wastewater treatment. Appl Surf Sci 303:14–22CrossRefGoogle Scholar
  44. Viseras C, Cerezo P, Sanchez R, Salcedo I, Aguzzi C (2010) Current challenges in clay minerals for drug delivery. Appl Clay Sci 48:291–295CrossRefGoogle Scholar
  45. Wang H, Yuan X, Wu Y, Chen X, Leng L, Wang H, Li H, Zeng G (2015) Facile synthesis of polypyrrole decorated reduced graphene oxide–Fe3O4 magnetic composites and its application for the Cr (VI) removal. Chem Eng J 262:597–606CrossRefGoogle Scholar
  46. Wang J, Song Y, Li Z, Liu Q, Zhou J, Jing X, Zhang M, Jiang Z (2010) In situ Ni/Al layered double hydroxide and its electrochemical capacitance performance. Energy Fuel 24:6463–6467CrossRefGoogle Scholar
  47. Wyrzykowski D, Hebanowska E, Nowak-Wiczk G, Makowski M, Chmurzynski L (2011) Thermal behaviour of citric acid and isomeric aconitic acids. J Therm Anal Calorim 104:731–735CrossRefGoogle Scholar
  48. Xiong J, Jiao C, Li C, Zhang D, Lin H, Chen Y (2014) A versatile amphiprotic cotton fiber for the removal of dyes and metal ions. Cellulose 21:3073–3087CrossRefGoogle Scholar
  49. Xu ZP, Lu GM (2006) Layered double hydroxide nanomaterials as potential cellular drug delivery agents. Pure Appl Chem 78:1771–1779CrossRefGoogle Scholar
  50. Yahia MB, Knani S, Hsan LBH, Yahia MB, Nasri H, Ben Lamine A (2017) Statistical studies of adsorption isotherms of iron nitrate and iron chloride on a thin layer of porphyrin. J Mol Liq 248:235–245CrossRefGoogle Scholar
  51. Yu X-L, He Y (2018) Optimal ranges of variables for an effective adsorption of lead (II) by the agricultural waste pomelo (Citrus grandis) peels using Doehlert designs. Sci Rep 8:729CrossRefGoogle Scholar
  52. Zhang X, Wang Y, Yang S (2014) Simultaneous removal of Co (II) and 1-naphthol by core–shell structured Fe3O4@ cyclodextrin magnetic nanoparticles. Carbohydr Polym 114:521–529CrossRefGoogle Scholar
  53. Zhang Y, Cao B, Zhao L, Sun L, Gao Y, Li J, Yang F (2018) Biochar-supported reduced graphene oxide composite for adsorption and coadsorption of atrazine and lead ions. Appl Surf Sci 427:147–155CrossRefGoogle Scholar
  54. Zhou K, Wu B, Su L, Xin W, Chai X (2018) Enhanced phosphate removal using nanostructured hydrated ferric-zirconium binary oxide confined in a polymeric anion exchanger. Chem Eng J 345:640–647CrossRefGoogle Scholar
  55. Zhou Y, Xia S, Zhang J, Zhang Z, Hermanowicz SW (2016a) Adsorption characterizations of biosorbent extracted from waste activated sludge for Pb (II) and Zn (II). Desalin Water Treat 57:9343–9353CrossRefGoogle Scholar
  56. Zhou Y, Xia S, Zhang Z, Zhang J, Hermanowicz SW (2016b) Associated adsorption characteristics of Pb (II) and Zn (II) by a novel biosorbent extracted from waste-activated sludge. J Environ Eng 142:04016032CrossRefGoogle Scholar
  57. Zhou Y, Zhang Z, Zhang J, Xia S (2016c) Understanding key constituents and feature of the biopolymer in activated sludge responsible for binding heavy metals. Chem Eng J 304:527–532CrossRefGoogle Scholar
  58. Zhou Y, Zhang Z, Zhang J, Xia S (2016d) New insight into adsorption characteristics and mechanisms of the biosorbent from waste activated sludge for heavy metals. J Environ Sci 45:248–256CrossRefGoogle Scholar
  59. Zhou Y, Xia S, Zhang J, Nguyen BT, Zhang Z (2017) Insight into the influences of pH value on Pb (II) removal by the biopolymer extracted from activated sludge. Chem Eng J 308:1098–1104CrossRefGoogle Scholar
  60. Zhu K, Gao Y, Tan X, Chen C (2016) Polyaniline-modified Mg/Al layered double hydroxide composites and their application in efficient removal of Cr (VI). ACS Sustain Chem Eng 4:4361–4369CrossRefGoogle Scholar
  61. Zhu L, Bratlie KM (2017) pH sensitive methacrylated chitosan hydrogels with tunable physical and chemical properties. Biochem Eng JGoogle Scholar
  62. Zargoosh K, Kondori S, Dinari M, Mallakpour S (2015) Synthesis of layered double hydroxides containing a biodegradable amino acid derivative and their application for effective removal of cyanide from industrial wastes. Ind Eng Chem Res 54:1093–1102CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Environmental Health, Faculty of HealthHormozgan University of Medical SciencesBandar AbbasIran
  2. 2.Department of ChemistryIsfahan University of TechnologyIsfahanIran

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