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Environmental Science and Pollution Research

, Volume 25, Issue 34, pp 34319–34331 | Cite as

Date palm ash-MgAl-layered double hydroxide composite: sustainable adsorbent for effective removal of methyl orange and eriochrome black-T from aqueous phase

  • Nawaf I. Blaisi
  • Mukarram Zubair
  • Ihsanullah
  • Sadaqat Ali
  • Taye Saheed Kazeem
  • Mohammad Saood Manzar
  • Walid Al-Kutti
  • Mamdouh A. Al Harthi
Research Article
  • 137 Downloads

Abstract

Date palm ash (DPA) and MgAl-layered double hydroxide (LDH) composites were synthesized by the co-precipitation method and characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), X-ray diffraction (XRD), and Brunauer–Emmett–Teller (BET). The DPA-MgAl-LDH (DPA/MgAl) composites were employed for the removal of methyl orange (MO) and eriochrome black-T (EBT) from aqueous phase. Incorporation of 33.33% (w/w) DPA into the layers of MgAl increased the surface area from 44.46 to 140.65 m2/g, which leads to the improved adsorption performance. The maximum adsorption capacity of DPA/MgAl (1:2) at 298 K was 242.98 and 425.16 (mg/g) for MO and EBT, respectively. The adsorption data of dyes were adequately fitted by a pseudo-second-order and Langmuir isotherm model. The composite showed excellent reusability performance up to three cycles. Addition of DPA into MgAl-LDH resulted in an effective low-cost adsorbent for decontamination of dyes from wastewater.

Graphical abstract

Keywords

Date palm ash Layered double hydroxide Dyes Adsorption Sustainable material 

Supplementary material

11356_2018_3367_MOESM1_ESM.docx (244 kb)
ESM 1 (DOCX 243 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Environmental Engineering, College of EngineeringImam Abdulrahman Bin Faisal UniversityDammamSaudi Arabia
  2. 2.Center for Environment and Water, Research InstituteKing Fahd University of Petroleum & MineralsDhahranSaudi Arabia
  3. 3.Department of Mechanical and Energy Engineering, College of EngineeringImam Abdulrahman Bin Faisal UniversityDammamSaudi Arabia
  4. 4.Department of Chemical EngineeringKing Fahd University of Petroleum & MineralsDhahranSaudi Arabia
  5. 5.Department of Civil and Construction Engineering, College of EngineeringImam Abdulrahman Bin Faisal UniversityDammamSaudi Arabia
  6. 6.Center of Research Excellence in NanotechnologyKing Fahd University of Petroleum & MineralsDhahranSaudi Arabia

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