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Environmental Science and Pollution Research

, Volume 26, Issue 5, pp 4180–4191 | Cite as

Phosphorous-doped TiO2 nanoparticles: synthesis, characterization, and visible photocatalytic evaluation on sulfamethazine degradation

  • Sandra Yadira Mendiola-Alvarez
  • Ma. Aracely Hernández-Ramírez
  • Jorge Luis Guzmán-Mar
  • Lorena Leticia Garza-Tovar
  • Laura Hinojosa-ReyesEmail author
Advanced Oxidation Technologies: State-of-the-Art in Ibero-American Countries
  • 152 Downloads

Abstract

Mesoporous phosphorous-doped TiO2 (TP) with different wt% of P (0.5, 1.0, and 1.5) was synthetized by microwave-assisted sol–gel method. The obtained materials were characterized by XRD with cell parameters refinement approach, Raman, BET-specific surface area analysis, SEM, ICP-OES, UV–Vis with diffuse reflectance, photoluminescence, FTIR, and XPS. The photocatalytic activity under visible light was evaluated on the degradation of sulfamethazine (SMTZ) at pH 8. The characterization of the phosphorous materials (TP) showed that incorporation of P in the lattice of TiO2 stabilizes the anatase crystalline phase, even increasing the annealing temperature. The mesoporous P-doped materials showed higher surface area and lower average crystallite size, band gap, and particle size; besides, more intense bands attributed to O–H bond were observed by FTIR analysis compared with bare TiO2. The P was substitutionally incorporated in the TiO2 lattice network as P5+ replacing Ti4+ to form Ti–O–P bonds and additionally present as PO43− on the TiO2 surface. All these characteristics explain the observed superior photocatalytic activity on degradation (100%) and mineralization (32%) of SMTZ under visible radiation by TP catalysts, especially for P-doped TiO2 1.0 wt% calcined at 450 °C (TP1.0-450). Ammonium, nitrate, and sulfate ions released during the photocatalytic degradation were quantified by ion chromatography; the nitrogen and sulfur mass balance evidenced the partial mineralization of this recalcitrant molecule.

Keywords

Phosphorous-doped TiO2 Mesoporous material Heterogeneous photocatalysis Visible light Sulfamethazine Microwave-assisted sol–gel method 

Notes

Acknowledgements

Mendiola-Alvarez thanks the CONACYT for her doctorate scholarship.

Funding information

The authors gratefully acknowledge financial support from PAICYT UANL and Facultad de Ciencias Químicas, UANL.

Supplementary material

11356_2018_2314_MOESM1_ESM.docx (455 kb)
ESM 1 (DOCX 454 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Facultad de Ciencias Químicas, Cd. UniversitariaUniversidad Autónoma de Nuevo León, UANLSan Nicolás de los GarzaMéxico

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