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Environmental Science and Pollution Research

, Volume 26, Issue 18, pp 17891–17900 | Cite as

Organic ligand induced release of vanadium from the dissolution of stone coal oxide ore

  • Xingyun Hu
  • Yuyan Yue
  • Xianjia PengEmail author
Environmental Pollution and Energy Management

Abstract

The effects of low-molecular-weight dissolved organic matters (LMWDOMs) on the release of vanadium (V) under environmental conditions are part of a broader study on the environmental geochemistry behavior of V. Eight typical naturally occurring LMWDOMs with carboxyl, hydroxyl, and amidogen groups were chosen: citric acid, oxalic acid, EDTA, salicylic acid, catechol, glycine, cysteine, and glucose. The results showed that the release of V was largely promoted by LMWDOMs with carboxyl functional groups under acidic conditions and with catechol under basic conditions. In the presence of citric acid, oxalic acid, or EDTA at pH 4.0, the initial release rates of V were approximately 25–39 times greater than the rates in the control experiments; the steady release rates were 164, 95, and 49 times than the rates in the control experiments, respectively. For catechol, the release rate at pH 8.0 was approximately 20 times the rate at pH 4.0. Amino acids and alcohols had a minimal effect on the release of V. Ligand-promoted release rates of V were found primarily due to the faster detachment of surface complexes, the protonated sites from the mineral surface and the reduction of dissolved V (V) in the presence of citric acid, oxalic acid, EDTA, and catechol. This study helps understand the pollution risk of V in some mine areas and the fate of V in the environment.

Keywords

Vanadium Stone coal Dissolved organic matters Kinetics Dissolution Complexation 

Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China [grant numbers 41641034, 21607166, and 41473113] and the National Water Pollution Control and Treatment Science and Technology Major Project [grant number 2015ZX07205-003].

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Copyright information

© Springer-Verlag GmbH Germany 2017

Authors and Affiliations

  1. 1.National Engineering Laboratory for Industrial Wastewater Treatment, Beijing Key Laboratory of Industrial Wastewater Treatment and Resource Recovery, Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijingChina
  2. 2.School of EnvironmentHenan Normal UniversityXinxiangChina
  3. 3.University of Chinese Academy of SciencesBeijingChina

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