In this work, an ordered mesoporous carbon material CMK-3 was synthesized and tested in the adsorption of Cr(VI) in water with an activated carbon material (AC) as the control. Properties of CMK-3 have been characterized by means of Fourier transform infrared spectroscopy, scanning electron microscopy, and transmission electron microscopy. In the adsorption of Cr(VI) in water, the adsorption rate and adsorption capacity of CMK-3 were found to be better than that of AC. A careful study on the adsorption kinetics and isotherms of Cr(VI) on CMK-3 was taken. The adsorption data of Cr(VI) on CMK-3 had been analyzed by pseudo-first-order, pseudo-second-order, particle diffusion, Elovich, Double constant, and Exponential function kinetic models, which revealed that the kinetic adsorption of Cr(VI) on CMK-3 is well accorded with pseudo-second-order kinetic model. The corresponding parameters for each model are obtained. According to the fitting of Langmuir, Freundlich, and Temkin models, the adsorption of Cr(VI) on CMK-3 was well described by Langmuir model to be a single-molecule layer adsorption. The adaptation of the adsorption of Cr(VI) on CMK-3 to Langmuir adsorption model and pseudo-second-order model suggests that the adsorption of Cr(VI) on CMK-3 can be highly affected by its chemical property although its textural properties also can remarkably affect its adsorption behavior.
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Baikousi, M., Bourlinos, A. B., Douvalis, A., Bakas, T., Anagnostopoulos, D. F., Tucek, J., et al. (2012). Synthesis and characterization of gamma-Fe2O3/carbon hybrids and their application in removal of hexavalent chromium ions from aqueous solutions. Langmuir, 28(8), 3918–3930.
Barczak, M., Michalak-Zwierz, K., Gdula, K., Tyszczuk-Rotko, K., Dobrowolski, R., & Dąbrowski, A. (2015). Ordered mesoporous carbons as effective sorbents for removal of heavy metal ions. Microporous and Mesoporous Materials, 211, 162–173.
Chen, T., Wang, T., Wang, D. J., Zhao, J. Q., Ding, X. C., Wu, S. C., et al. (2010). Selective adsorption behavior of Cu(II) and Cr(VI) heavy metal ions by functionalized ordered mesoporous carbon. Acta Physico-Chimica Sinica, 26(12), 3249–3256.
Cheng, F. F. (2010). Study on the adsorption properties of alginate acid fibers to heavy metal ions. Qingdao: Qingdao University.
Crini, G., Peindy, H., Gimbert, F., & Robert, C. (2007). Removal of C.I. basic green 4 (malachite green) from aqueous solutions by adsorption using cyclodextrin-based adsorbent: kinetic and equilibrium studies. Separation and Purification Technology, 53(1), 97–110.
Dai, Y., Hu, Y. C., Jiang, B. J., Zou, J. L., Tian, G. H., & Fu, H. G. (2015). Carbothermal synthesis of ordered mesoporous carbon-supported nano zero-valent iron with enhanced stability and activity for hexavalent chromium reduction. Journal of Hazardous Materials, 309, 249–258.
Dayan, A. D., & Paine, A. J. (2001). Mechanisms of chromium toxicity, carcinogenicity and allergenicity: review of the literature from 1985 to 2000. Human & Experimental Toxicology, 20(9), 439–451.
Fu, J. W., Chen, Z. H., Wang, M. H., Liu, S. J., Zhang, J. H., Zhang, J. N., et al. (2015). Adsorption of methylene blue by a high-efficiency adsorbent (polydopamine microspheres): kinetics, isotherm, thermodynamics and mechanism analysis. Chemical Engineering Journal, 259, 53–61.
Ghasemi, Z., Seif, A., Ahmadi, T. S., Zargar, B., Rashidi, F., & Rouzbahani, G. M. (2012). Thermodynamic and kinetic studies for the adsorption of Hg(II) by nano-TiO2 from aqueous solution. Advanced Powder Technology, 23(2), 148–156.
Hua, M., Zhang, S. J., Pan, B. C., Zhang, W. M., Lv, L., & Zhang, Q. X. (2012). Heavy metal removal from water/wastewater by nanosized metal oxides: a review. Journal of Hazardous Materials, 211-212, 317–331.
Idris, S. A., Alotaibi, K. M., Peshkur, T. A., Anderson, P., Morris, M., & Gibson, L. T. (2013). Adsorption kinetic study: effect of adsorbent pore size distribution on the rate of Cr (VI) uptake. Microporous and Mesoporous Materials, 165, 99–105.
Jun, S., Joo, S. H., Ryoo, R., Kruk, M., Jaroniec, M., Liu, Z., et al. (2000). Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure. Journal of the American Chemical Society, 122, 10712–10713.
Kaur, S., Rani, S., Mahajan, R. K., Asif, M., & Gupta, V. K. (2015). Synthesis and adsorption properties of mesoporous material for the removal of dye safranin: kinetics, equilibrium, and thermodynamics. Journal of Industrial and Engineering Chemistry, 22, 19–27.
Kołodyńska, D. (2012). Adsorption characteristics of chitosan modified by chelating agents of a new generation. Chemical Engineering Journal, 179, 33–43.
Lad, J. B., & Makkawi, Y. T. (2014). Adsorption of dimethyl ether (DME) on zeolite molecular sieves. Chemical Engineering Journal, 256, 335–346.
Li, G. T. (2013). Study on the solute migration discipline of reciculated leachate by Li + tracer. Cheng du: Southwest Jiaotong University.
Li, S. X., Lian, Y. Q., Mai, J. F., Tan, J. X., Hu, S. J., Xia, W. Q., et al. (2012). Removal of hexavalent chromium and turbidity in drinking water by chitosan. Advanced Materials Research, 433-440, 793–797.
Liu, J., Li, Y., Xiao, H. N., & Ke, J. (2017). Facile preparation of α-Fe 2O 3 nanorods and the promotion in Cr(VI) adsorption. Materials Science and Engineering: Paper presented at the IOP Conference Series.
Maretto, M., Vignola, R., Williams, C. D., Bagatin, R., Latini, A., & Petrangeli Papini, M. (2015). Adsorption of hydrocarbons from industrial wastewater onto a silica mesoporous material: structural and thermal study. Microporous and Mesoporous Materials, 203, 139–150.
Mishra, S., & Bharagava, R. N. (2015). Toxic and genotoxic effects of hexavalent chromium in environment and its bioremediation strategies. Journal of Environmental Science and Health, 34(1), 1–32.
Mohammadi, N., Khani, H., Gupta, V. K., Amereh, E., & Agarwal, S. (2011). Adsorption process of methyl orange dye onto mesoporous carbon material-kinetic and thermodynamic studies. Journal of Colloid and Interface Science, 362(2), 457–462.
Robin Wilson, G., Sharma, A., Sachdev, D., & Dubey, A. (2015). Ferulic acid functionalized mesoporous silica polymer nanocomposites (SBA/FA) for the adsorption of Cr(VI). Journal of Porous Materials, 23(1), 195–200.
Sankararamakrishnan, N., Jaiswal, M., & Verma, N. (2014). Composite nanofloral clusters of carbon nanotubes and activated alumina: an efficient sorbent for heavy metal removal. Chemical Engineering Journal, 235, 1–9.
Sheng, G. D., Hu, J., Li, H., Li, J. X., & Huang, Y. Y. (2016). Enhanced sequestration of Cr(VI) by nanoscale zero-valent iron supported on layered double hydroxide by batch and XAFS study. Chemosphere, 148, 227–232.
Tang, L., Yang, G. D., Zeng, G. M., Cai, Y., Li, S. S., Zhou, Y. Y., et al. (2014). Synergistic effect of iron doped ordered mesoporous carbon on adsorption-coupled reduction of hexavalent chromium and the relative mechanism study. Chemical Engineering Journal, 239, 114–122.
Wang, J. J., Zhang, R., Yang, X. X., Liu, X. Y., & Zhang, H. X. (2018). Facile synthesis of copper(II)-decorated functional mesoporous material for specific adsorption of histidine-rich proteins. Talanta, 176, 308–317.
Yang, Y., Wang, D., & Yang, J. X. (2017). The synthesis of novel thiol/amino bifunctionalized SBA-15 and application on the Cr(VI) absorption. Earth and Environmental Science: Paper presented at the IOP Conference Series.
Zhai, Y. P., Wan, Y., Cheng, Y., Shi, Y. F., Zhang, F. Q., Tu, B., et al. (2007). The influence of carbon source on the wall structure of ordered mesoporous carbons. Journal of Porous Materials, 15(5), 601–611.
Zhang, H. D., Wang, Y. M., Zhang, L., Gerritsen, G., Abbenhuis, H., Vansanten, R., et al. (2008). Enantioselective epoxidation of β-methylstyrene catalyzed by immobilized Mn(salen) catalysts in different mesoporous silica supports. Journal of Catalysis, 256(2), 226–236.
This work was financially supported by the National Natural Science Foundation of China (U1362105, 21606028); Chongqing Science & Technology Commission Research Projects (cstc2017jcyjAX0192, cstc2017jcyjAX0209, cstc2018jcyjAX0638); Research Project (CQCM-2017-05) of the Key Laboratory of Catalysis Science and Technology, Science Project (KJZD-K201900805), and Chongqing Innovation team project (CXQT19023) of Chongqing Education Commission.
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Zhou, Y., Zhang, X., Zhang, H. et al. On the Removal of the Cr(VI) in Water by an Ordered Mesoporous Carbon Material: Kinetic and Isotherm Studies. Water Air Soil Pollut 231, 78 (2020). https://doi.org/10.1007/s11270-020-4421-5