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Ion Exchange Modeling of the Competitive Adsorption of Cu(II) and Pb(II) Using Chemically Modified Solid Waste Coffee

  • J. Botello-González
  • F. J. Cerino-CórdovaEmail author
  • N. E. Dávila-Guzmán
  • J. J. Salazar-Rábago
  • E. Soto-Regalado
  • R. Gómez-González
  • M. Loredo-Cancino
Article
  • 141 Downloads

Abstract

The presence of potentially toxic metals such as Cu(II) and Pb(II) in aquifers and industrial effluents represents a serious health problem due to their high toxicity, non-biodegradability, and ability to bioaccumulate. In this study, the removal of these pollutants individually and as a binary mixture has been studied, using solid coffee waste modified with 0.6 M citric acid as the adsorbent, and a mathematical model based on the ion exchange mechanism was implemented to elucidate the adsorption equilibrium. The characterization of modified coffee waste showed a pH value at the point of zero charge of 2.97 and a high concentration of carboxylic groups, which are susceptible to ion exchange. Furthermore, the quantification of interchangeable ions confirmed that the main mechanism of adsorption is the ion exchange of metal ions with the protons present on the adsorbent’s surface. The experimental data of the individual and binary adsorption equilibrium using a model based on a phenomenological approach was analyzed. The phenomenological model was compared with the Freundlich and Langmuir empirical solid-liquid adsorption models. The results showed that the adsorption capacities of Cu(II) and Pb(II) individually were 1.46 and 1.18 meq/g, and in a binary mixture were 1.43 and 1.24 meq/g, respectively, at pH 5 and 30 °C. In addition, the separation coefficients from ion exchange model revealed the predominance of protons as an exchangeable ion, which is in accordance with the experimental evidence. Finally, the correlation coefficient showed that the proposed model predicts accurately the adsorption equilibrium.

Keywords

Mathematical modeling Ion exchange Binary mixture Coffee residues Chemical modification 

Notes

Acknowledgments

The authors would like to acknowledge the Department of Chemistry, Facultad de Ciencias Químicas, UANL, for the laboratory space

Funding Information

The study was financially supported by Facultad de Ciencias Químicas, UANL. A partial scholarship support was also received from CONACYT (329590).

Compliance with Ethical Standards

Conflict of Interest

The authors declare that they have no conflict of interest.

Supplementary material

11270_2019_4106_MOESM1_ESM.docx (126 kb)
ESM 1 (DOCX 126 kb)

References

  1. An, H. (2001). Crab shell for the removal of heavy metals from aqueous solution. Water Research, 35(15), 3551–3556.  https://doi.org/10.1016/S0043-1354(01)00099-9.CrossRefGoogle Scholar
  2. Babić, B. M., Milonjić, S. K., Polovina, M. J., & Kaludierović, B. V. (1999). Point of zero charge and intrinsic equilibrium constants of activated carbon cloth. Carbon, 37(3), 477–481.  https://doi.org/10.1016/S0008-6223(98)00216-4.CrossRefGoogle Scholar
  3. Cerino-Córdova, F. J., Díaz-Flores, P. E., García-Reyes, R. B., Soto-Regalado, E., Gómez-González, R., Garza-González, M. T., & Bustamante-Alcántara, E. (2013a). Biosorption of Cu(II) and Pb(II) from aqueous solutions by chemically modified spent coffee grains. International Journal of Environmental Science and Technology.  https://doi.org/10.1007/s13762-013-0198-z.
  4. Cerino-Córdova, F. J., Díaz-Flores, P. E., García-Reyes, R. B., Soto-Regalado, E., Gómez-González, R., Garza-González, M. T., & Bustamante-Alcántara, E. (2013b). ERRATUM: Biosorption of Cu(II) and Pb(II) from aqueous solutions by chemically modified spent coffee grains. International Journal of Environmental Science and Technology.  https://doi.org/10.1007/s13762-013-0198-z.
  5. Chong, K. H., & Volesky, B. (1995). Description of two-metal biosorption equilibria by Langmuir-type models. Biotechnology and Bioengineering, 47(4), 451–460.  https://doi.org/10.1002/bit.260470406.CrossRefGoogle Scholar
  6. Crittenden, J. C., & John C., & Montgomery Watson Harza (Firm). (2012). MWH’s water treatment: principles and design. Hoboken: Wiley https://www.wiley.com/en-us/MWH%27s+Water+Treatment%3A+Principles+and+Design%2C+3rd+Edition-p-9780470405390. Accessed 1 June 2018.CrossRefGoogle Scholar
  7. da Silva, M. G. C., Canevesi, R. L. S., Welter, R. a., Vieira, M. G. a., & da Silva, E. A. (2015). Chemical equilibrium of ion exchange in the binary mixture Cu2+ and Ca2+ in calcium alginate. Adsorption, (cm).  https://doi.org/10.1007/s10450-015-9682-8.
  8. Das Graças Nunes Matos, M., Gouveia Diniz, V., De Abreu, C. A. M., Knoechelmann, A., & Da Silva, V. L. (2009). Bioadsorption and ion exchange of Cr3+ and Pb2+ solutions with algae. Adsorption, 15(1), 75–80.  https://doi.org/10.1007/s10450-009-9152-2.CrossRefGoogle Scholar
  9. Dávila-Guzmán, N. E., De Jesús Cerino-Cordova, F., Soto-Regalado, E., Rangel-Mendez, J. R., Díaz-Flores, P. E., Garza-Gonzalez, M. T., & Loredo-Medrano, J. A. (2013). Copper biosorption by spent coffee ground: equilibrium, kinetics, and mechanism. Clean - Soil, Air, Water, 41(6), 557–564.  https://doi.org/10.1002/clen.201200109.CrossRefGoogle Scholar
  10. Davila-Guzman, N. E., Cerino-Cordova, F. J., Loredo-Cancino, M., Rangel-Mendez, J. R., Gómez-González, R., Soto-Regalado, E. (2016). Studies of adsorption of heavy metals onto spent coffee ground: equilibrium, regeneration, and dynamic performance in a fixed-bed column. International Journal of Chemical Engineering, 2016, 1–11.  https://doi.org/10.1155/2016/9413879.CrossRefGoogle Scholar
  11. Fei, Q., & Bei, W. (2007). Single- and multi-component adsorption of Pb, Cu, and Cd on peat. Bulletin of Environmental Contamination and Toxicology, 78(3–4), 265–269.  https://doi.org/10.1007/s00128-007-9127-5.CrossRefGoogle Scholar
  12. Freundlich, H. (1927). New conceptions in colloidal chemistry. Journal of Chemical Education, 4(9), 1202.  https://doi.org/10.1021/ed004p1202.1.CrossRefGoogle Scholar
  13. Hossain, M. A., Ngo, H. H., Guo, W. S., Nghiem, L. D., Hai, F. I., Vigneswaran, S., & Nguyen, T. V. (2014). Competitive adsorption of metals on cabbage waste from multi-metal solutions. Bioresource Technology, 160, 79–88.  https://doi.org/10.1016/j.biortech.2013.12.107.CrossRefGoogle Scholar
  14. Joshi, M., Kremling, A., & Seidel-Morgenstern, A. (2006). Model based statistical analysis of adsorption equilibrium data. Chemical Engineering Science, 61(23), 7805–7818.  https://doi.org/10.1016/j.ces.2006.08.052.CrossRefGoogle Scholar
  15. Kaur, R., Singh, J., Khare, R., & Ali, A. (2012). Biosorption the possible alternative to existing conventional technologies for sequestering heavy metal ions from aqueous streams : a review. Universal Journal of Environmental Research and Technology, 2(4), 325–335.Google Scholar
  16. Kononova, O. N., Bryuzgina, G. L., Apchitaeva, O. V., & Kononov, Y. S. (2015). Ion exchange recovery of chromium (VI) and manganese (II) from aqueous solutions. Arabian Journal of Chemistry.  https://doi.org/10.1016/j.arabjc.2015.05.021.
  17. Kyzas, G. Z. (2012). Commercial coffee wastes as materials for adsorption of heavy metals from aqueous solutions. Materials, 5(10), 1826–1840.  https://doi.org/10.3390/ma5101826.CrossRefGoogle Scholar
  18. Langmuir, I. (1918). The adsorption of gases on plane surfaces of glass, mica and platinum. Journal of the American Chemical Society, 40(9), 1361–1403.  https://doi.org/10.1021/ja02242a004.CrossRefGoogle Scholar
  19. Liu, C., Pujol, D., Olivella, M., De La Torre, F., Fiol, N., Poch, J., & Villaescusa, I. (2015). The role of exhausted coffee compounds on metal ions sorption. Water, Air, and Soil Pollution, 226(9).  https://doi.org/10.1007/s11270-015-2568-2.
  20. Minamisawa, M., Minamisawa, H., Yoshida, S., & Takai, N. (2004). Adsorption behavior of heavy metals on biomaterials. Journal of Agricultural and Food Chemistry, 52(18), 5606–5611.  https://doi.org/10.1021/jf0496402.CrossRefGoogle Scholar
  21. Montgomery, D. C. (1987). Design and analysis of experiments-second edition. Quality and Reliability Engineering International.  https://doi.org/10.1002/qre.4680030319.
  22. Murthy, P. S., & Madhava Naidu, M. (2012). Sustainable management of coffee industry by-products and value addition - a review. Resources, Conservation and Recycling, 66, 45–58.  https://doi.org/10.1016/j.resconrec.2012.06.005.CrossRefGoogle Scholar
  23. OIC. (2017). Domestic consumption by all exporting countries. http://www.ico.org/historical/1990%20onwards/PDF/1b-domestic-consumption.pdf. Accessed 14 Dec 2017.
  24. Oliveira, L. S., Franca, A. S., Alves, T. M., & Rocha, S. D. F. (2008a). Evaluation of untreated coffee husks as potential biosorbents for treatment of dye contaminated waters. Journal of Hazardous Materials, 155(3), 507–512.  https://doi.org/10.1016/j.jhazmat.2007.11.093.CrossRefGoogle Scholar
  25. Oliveira, W. E., Franca, A. S., Oliveira, L. S., & Rocha, S. D. (2008b). Untreated coffee husks as biosorbents for the removal of heavy metals from aqueous solutions. Journal of Hazardous Materials, 152(3), 1073–1081.  https://doi.org/10.1016/j.jhazmat.2007.07.085.CrossRefGoogle Scholar
  26. Pagnanelli, F., Esposito, A., & Vegliò, F. (2002). Multi-metallic modelling for biosorption of binary systems. Water Research, 36(16), 4095–4105.  https://doi.org/10.1016/S0043-1354(02)00112-4.CrossRefGoogle Scholar
  27. Pourret, O., & Bollinger, J.-C. (2018). “Heavy metal” - what to do now: To use or not to use? Science of the Total Environment, 610–611, 419–420.  https://doi.org/10.1016/J.SCITOTENV.2017.08.043.CrossRefGoogle Scholar
  28. Pujol, D., Liu, C., Gominho, J., Olivella, M. À., Fiol, N., Villaescusa, I., & Pereira, H. (2013). The chemical composition of exhausted coffee waste. Industrial Crops and Products, 50, 423–429.  https://doi.org/10.1016/j.indcrop.2013.07.056.CrossRefGoogle Scholar
  29. Sawyer, C. N., McCarty, P. L., & Parkin, G. F. (2003). Chemistry for environmental engineering and science. McGraw-Hill.Google Scholar
  30. Schiewer, S., & Volesky, B. (1995). Modeling of the proton-metal ion exchange in biosorption. Environmental Science & Technology, 29(12), 3049–3058.  https://doi.org/10.1021/es00012a024.CrossRefGoogle Scholar
  31. Secretaría de Medio Ambiente y Recursos. (2003). En Materia de Aguas Residuales | Secretaría de Medio Ambiente y Recursos Naturales. http://biblioteca.semarnat.gob.mx/janium/Documentos/Ciga/agenda/DOFsr/DO2470.pdf. Accessed 20 Oct 2017.
  32. Singh, U., & Kaushal, R. K. (2013). Treatment of wastewater with low cost adsorbent – a review. Journal of Technical & Non-Technical Research, 4(3), 33–42.Google Scholar
  33. Sud, D., Mahajan, G., & Kaur, M. P. (2008). Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions - a review. Bioresource Technology.  https://doi.org/10.1016/j.biortech.2007.11.064.
  34. Sulaymon, A. H., Mohammed, A. A., & Al-Musawi, T. J. (2013). Competitive biosorption of lead, cadmium, copper, and arsenic ions using algae. Environmental Science and Pollution Research, 20(5), 3011–3023.  https://doi.org/10.1007/s11356-012-1208-2.CrossRefGoogle Scholar
  35. The Perkin-Elmer Corporation. (1996). Analytical Methods for Atomic Absorption Spectroscopy. United States of America. Waltham: Perkin-Elmer Corporation.Google Scholar
  36. Tokimoto, T., Kawasaki, N., Nakamura, T., Akutagawa, J., & Tanada, S. (2005). Removal of lead ions in drinking water by coffee grounds as vegetable biomass. Journal of Colloid and Interface Science, 281(1), 56–61.  https://doi.org/10.1016/j.jcis.2004.08.083.CrossRefGoogle Scholar
  37. Utomo, H. D., & Hunter, K. a. (2006). Adsorption of heavy metals by exhausted coffee grounds as a potential treatment method for waste waters. e-Journal of Surface Science and Nanotechnology, 4(May), 504–506.  https://doi.org/10.1380/ejssnt.2006.504.CrossRefGoogle Scholar
  38. Vaughan, T., Seo, C. W., & Marshall, W. E. (2001). Removal of selected metal ions from aqueous solution using modified corncobs. Bioresource Technology, 78, 133–139.  https://doi.org/10.1016/s0960-8524(01)00007-4.CrossRefGoogle Scholar
  39. Wartelle, L., & Marshall, W. (2000). Citric acid modified agricultural by-products as copper ion adsorbents. Advances in Environmental Research, 4(1), 1–7.  https://doi.org/10.1016/S1093-0191(00)00002-2.CrossRefGoogle Scholar
  40. Waterloo Maple Inc. (2014). Maple, 18 https://www.maplesoft.com.
  41. Webb, M. (1987). In H. Eccles & S. Hunt (Eds.), Immobilisation of ions by bio-sorption. Chichester, 1986; 266pp, £32.50. Journal of Applied Toxicology, 7(5), 353–353: Ellis Horwood Ltd.  https://doi.org/10.1002/jat.2550070511.CrossRefGoogle Scholar
  42. Won, S. W., Kotte, P., Wei, W., Lim, A., & Yun, Y. (2014). Biosorbents for recovery of precious metals. Bioresource Technology, 160, 203–212.  https://doi.org/10.1016/j.biortech.2014.01.121.CrossRefGoogle Scholar
  43. Yu, J., Feng, L., Cai, X., Wang, L., & Chi, R. (2014). Adsorption of Cu2+, Cd2+ and Zn2+ in a modified leaf fixed-bed column: competition and kinetics. Environmental Earth Sciences.  https://doi.org/10.1007/s12665-014-3529-6.
  44. Yun, Y. S., Park, D., Park, J. M., & Volesky, B. (2001). Biosorption of trivalent chromium on the brown seaweed biomass. Environmental Science and Technology, 35(21), 4353–4358.  https://doi.org/10.1021/es010866k.CrossRefGoogle Scholar
  45. Zhou, Y., Zhang, R., Gu, X., & Lu, J. (2015). Adsorption of divalent heavy metal ions from aqueous solution by citric acid modified pine sawdust. Separation Science and Technology, 50(2), 245–252.  https://doi.org/10.1080/01496395.2014.956223.CrossRefGoogle Scholar
  46. Zhu, B., Fan, T., & Zhang, D. (2008). Adsorption of copper ions from aqueous solution by citric acid modified soybean straw. Journal of Hazardous Materials, 153(1–2), 300–308.  https://doi.org/10.1016/j.jhazmat.2007.08.050.CrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  • J. Botello-González
    • 1
  • F. J. Cerino-Córdova
    • 1
    Email author
  • N. E. Dávila-Guzmán
    • 1
  • J. J. Salazar-Rábago
    • 1
  • E. Soto-Regalado
    • 1
  • R. Gómez-González
    • 1
  • M. Loredo-Cancino
    • 1
  1. 1.Facultad de Ciencias QuímicasUniversidad Autónoma de Nuevo LeónSan Nicolás de los GarzaMexico

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