Abstract
Frictional heating is common during the dry sliding of polymers against steel, which further makes it complex to understand the friction and wear performance of polymers at high temperature. Towards the goal of addressing the tribological response of polymers to such combined temperatures, the counter steel was heated crossing the glass transition (150 °C) of polyetheretherketone (PEEK), and tribological tests were conducted during temperature ramping or at constant counterbody temperatures. With increasing temperature, different friction responses were revealed depending on the variation manner of temperature (sliding during ramping or at controlled counterbody temperature). Even so, counterbody temperature around PEEK’s glass transition defined a transition, from which distinct friction and wear of PEEK was exhibited. Based on real-time analysis of temperature in the counterbody and PEEK near to the sliding interface, the completion between frictional and external heating is discussed. In combination with worn surface characterization, this also helped understand the mechanisms behind such kind of tribological response to temperatures.
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References
Panda, J.N., Bijwe, J., Pandey, R.K.: Comparative potential assessment of solid lubricants on the performance of poly aryl ether ketone (PAEK) composites. Wear 384–385, 192–202 (2017). https://doi.org/10.1016/j.wear.2016.11.044
Zhao, G., Wu, C., Zhang, L., Song, J., Ding, Q.: Friction and wear behavior of PI and PTFE composites for ultrasonic motors. Polym. Adv. Technol. 29(5), 1487–1496 (2018). https://doi.org/10.1002/pat.4260
Voss, H., Friedrich, K.: On the wear behaviour of short-fibre-reinforced peek composites. Wear 116(1), 1–18 (1987). https://doi.org/10.1016/0043-1648(87)90262-6
Briscoe, B.: Wear of polymers: an essay on fundamental aspects. Tribol. Int. 14(4), 231–243 (1981). https://doi.org/10.1016/0301-679X(81)90050-5
Wu, C., Wei, C., Jin, X., Akhtar, R., Zhang, W.: Carbon spheres as lubricant additives for improving tribological performance of polyetheretherketone. J. Mater. Sci. 54(6), 5127–5135 (2019). https://doi.org/10.1007/s10853-018-3177-4
Song, H., Li, N., Li, Y., Min, C., Wang, Z.: Preparation and tribological properties of graphene/poly(ether ether ketone) nanocomposites. J. Mater. Sci. 47(17), 6436–6443 (2012). https://doi.org/10.1007/s10853-012-6574-0
Hanchi, J., Eiss, N.S.: Dry sliding friction and wear of short carbon-fiber-reinforced polyetheretherketone (PEEK) at elevated temperatures. Wear 203–204, 380–386 (1997). https://doi.org/10.1016/S0043-1648(96)07347-4
Lu, Z.P., Friedrich, K.: On sliding friction and wear of PEEK and its composites. Wear 181–183, 624–631 (1995). https://doi.org/10.1016/0043-1648(95)90178-7
Hou, X., Hu, Y., Hu, X., Jiang, D.: Poly (ether ether ketone) composites reinforced by graphene oxide and silicon dioxide nanoparticles: mechanical properties and sliding wear behavior. High Perform. Polym. 30(4), 406–417 (2017). https://doi.org/10.1177/0954008317701549
Zhang, G., Yu, H., Zhang, C., Liao, H., Coddet, C.: Temperature dependence of the tribological mechanisms of amorphous PEEK (polyetheretherketone) under dry sliding conditions. Acta Mater. 56(10), 2182–2190 (2008). https://doi.org/10.1016/j.actamat.2008.01.018
Hoskins, T.J., Dearn, K.D., Chen, Y.K., Kukureka, S.N.: The wear of PEEK in rolling–sliding contact—Simulation of polymer gear applications. Wear 309(1), 35–42 (2014). https://doi.org/10.1016/j.wear.2013.09.014
Zuo, Z., Yang, Y., Qi, X., Su, W., Yang, X.: Analysis of the chemical composition of the PTFE transfer film produced by sliding against Q235 carbon steel. Wear 320, 87–93 (2014). https://doi.org/10.1016/j.wear.2014.08.019
Wang, W., Wen, H., He, N., Chen, W.: Effect of load on tribological properties of silicon nitride/steel under rolling-sliding contact condition. Tribol. Int. 125, 27–38 (2018). https://doi.org/10.1016/j.triboint.2018.04.022
Laux, K.A., Jean-Fulcrand, A., Sue, H.J., Bremner, T., Wong, J.S.S.: The influence of surface properties on sliding contact temperature and friction for polyetheretherketone (PEEK). Polymer 103, 397–404 (2016). https://doi.org/10.1016/j.polymer.2016.09.064
Aldousiri, B., Shalwan, A., Chin, C.W.: A review on tribological behaviour of polymeric composites and future reinforcements. Adv. Mat. Sci. Eng. 2013, 8 (2013). https://doi.org/10.1155/2013/645923
Shen, J.T., Pei, Y.T., De Hosson, J.T.M.: Structural changes in polytetrafluoroethylene molecular chains upon sliding against steel. J. Mater. Sci. 49(4), 1484–1493 (2014). https://doi.org/10.1007/s10853-013-7829-0
Onodera, T., Park, M., Souma, K., Ozawa, N., Kubo, M.: Transfer-film formation mechanism of polytetrafluoroethylene: a computational chemistry approach. J. Phys. Chem. C 117(20), 10464–10472 (2013). https://doi.org/10.1021/jp400515j
Zalaznik, M., Kalin, M., Novak, S., Jakša, G.: Effect of the type, size and concentration of solid lubricants on the tribological properties of the polymer PEEK. Wear 364–365, 31–39 (2016). https://doi.org/10.1016/j.wear.2016.06.013
Urueña, J.M., Pitenis, A.A., Harris, K.L., Sawyer, W.G.: Evolution and wear of fluoropolymer transfer films. Tribol. Lett. 57(1), 9 (2015). https://doi.org/10.1007/s11249-014-0453-6
Abdelbary, A.: Wear of Polymers and Composites. Woodhead Publishing, Cambridge (2015)
Häger, A.M., Friedrich, K., Junghans, R.: Selected thermoplastic bearing materials for use at elevated temperatures. Wear 162–164, 649–655 (1993). https://doi.org/10.1016/0043-1648(93)90062-Q
Chang, L., Zhang, G., Wang, H., Fu, K.: Comparative study on the wear behaviour of two high-temperature-resistant polymers. Tribol. Lett. 65(2), 34 (2017). https://doi.org/10.1007/s11249-017-0819-7
Pei, X.-Q., Lin, L.-Y., Schlarb, A.K., Bennewitz, R.: Novel experiments reveal scratching and transfer film mechanisms in the sliding of the PEEK/steel tribosystem. Tribol. Lett. 63(3), 40 (2016). https://doi.org/10.1007/s11249-016-0732-5
Zhang, G., Schlarb, A.K.: Correlation of the tribological behaviors with the mechanical properties of poly-ether-ether-ketones (PEEKs) with different molecular weights and their fiber filled composites. Wear 266(1), 337–344 (2009). https://doi.org/10.1016/j.wear.2008.07.004
Yang, E.L., Hirvonen, J.P., Toivanen, R.O.: Effect of temperature on the transfer film formation in sliding contact of PTFE with stainless steel. Wear 146(2), 367–376 (1991). https://doi.org/10.1016/0043-1648(91)90075-6
Briscoe, B.J., Sinha, S.K.: Wear of polymers. Proc. Inst. Mech. Eng. J 216(6), 401–413 (2002). https://doi.org/10.1243/135065002762355325
Acknowledgements
The authors acknowledge financial support of the German Research Foundation (Grant Nos. SCHL280/22-2 and BE4238/7-2) and Evonik Industries AG, Germany, for the donation of the experimental materials. We also thank Dr. T. Löber at the Nano Structuring Center (NSC), Technische Universität Kaiserslautern, for his help on the FIB investigations.
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Lin, L., Pei, XQ., Bennewitz, R. et al. Tribological Response of PEEK to Temperature Induced by Frictional and External Heating. Tribol Lett 67, 52 (2019). https://doi.org/10.1007/s11249-019-1169-4
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DOI: https://doi.org/10.1007/s11249-019-1169-4