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Exploring the Synthesis of Mesoporous Stannosilicates as Catalysts for the Conversion of Mono- and Oligosaccharides into Methyl Lactate

  • Irene Tosi
  • Annalisa Sacchetti
  • Juan S. Martinez-Espin
  • Sebastian Meier
  • Anders RiisagerEmail author
Original Paper

Abstract

Sn-beta zeolites are among the most promising catalysts for the conversion of biomasses due to their high Lewis acidity, which allows coordination to functionalized molecules and promotes cleavage and rearrangement reactions. For applications in biorefining zeolite porosity would ideally be optimized to avoid diffusional limitations, which otherwise may decrease reaction rates and restrict the conversion of bulky substrates. The synthesis of mesoporous zeolites can help alleviating limitations and is a central topic in heterogeneous catalysis, with many synthetic procedures for mesoporous zeolites proposed over the last decades. Here, we explore different syntheses routes to prepare Lewis acidic Sn-containing zeolites, and the main features of the prepared mesoporous materials are characterized. We investigate the correlation between different types of porosity and the activity for the conversion of sugars into methyl lactate. The monomer glucose, the dimer sucrose and the oligomer inulin are applied as model substrates for the reaction in order to probe the accessibility of molecules with different sizes to active sites in zeolites with different pore systems.

Keywords

Biomass conversion Inulin Mesoporous zeolites Methyl lactate Sn-beta 

Notes

Acknowledgements

This work was funded by the Innovation Fund Denmark (Case Number 5150-00023B). 800 MHz NMR spectra were recorded by using the spectrometer of the NMR center DTU supported by the Villum foundation. AS acknowledges the Erasmus + Programme for the traineeship grant.

Supplementary material

11244_2019_1135_MOESM1_ESM.docx (2 mb)
Supplementary material 1 (DOCX 2030 KB)

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Department of ChemistryTechnical University of DenmarkKgs. LyngbyDenmark
  2. 2.Dipartimento di Chimica Industriale “Toso Montanari”Alma Mater Studiorum-University of BolognaBolognaItaly
  3. 3.Haldor Topsøe A/SKgs. LyngbyDenmark

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