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Topics in Catalysis

, Volume 61, Issue 15–17, pp 1721–1733 | Cite as

Effect of Ni on MCM-41 in the Adsorption of Nitrogen and Sulfur Compounds to Obtain Ultra-Low-Sulfur Diesel

  • Julio César García-Martínez
  • H. A. González-Uribe
  • M. M. González-Brambila
  • N. G. Flores del Río
  • A. López-Gaona
  • L. Alvarado-Perea
  • J. A. Colín-Luna
Original Paper
  • 108 Downloads

Abstract

Adsorption of heterocyclic sulfur and nitrogen compounds like dibenzothiophene (DBT) and quinoline (Q), respectively, was carried out using mesostructured adsorbent MCM-41 and Ni/MCM-41 in calcined (C) and reduced (R) form. These materials were proved in a batch adsorption system using a model fuel diesel: a mixture of dodecane, DBT and Q with the same concentrations of ppmw of sulfur and nitrogen at 313 K and atmospheric pressure. When MCM-41 was impregnated with Ni, an important modification of the adsorption properties was observed, for example, the uptake of DBT was increased and this adsorption was twice in Ni/MCM-41 in reduce form than in the calcined form. On the other hand, for the nitrogen adsorption of Q diminished by 62 and 58%, considering Ni/MCM-41 in reduce form and in calcined form as adsorbent, respectively. This is a significant achievement regarding the desulfurization and denitrogenation, especially for commercial diesel without pretreatment. Moreover, the kinetic results were adjusted with second order considering Q as nitrogen and DBT as sulfur molecule. Data fitting for Q was achieved better by the Langmuir model for all materials than the Freundlich model, meanwhile the experimental adsorption data of DBT was fitted to the Freundlich model for Ni/MCM-41 calcinated and reduced form.

Keywords

Dibenzothiophene Quinoline Adsorption Langmuir Freundlich Hydrodesulfurization 

Notes

Acknowledgements

Julio César García-Martínez would like to thank the Universidad Autónoma Metropolitana Azcapotzalco to the Energy Department and the Programa para el desarrollo profesional Docente (PRODEP) from México.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • Julio César García-Martínez
    • 1
  • H. A. González-Uribe
    • 1
  • M. M. González-Brambila
    • 1
  • N. G. Flores del Río
    • 2
  • A. López-Gaona
    • 3
  • L. Alvarado-Perea
    • 4
  • J. A. Colín-Luna
    • 1
  1. 1.Departamento de EnergíaUniversidad Autónoma Metropolitana AzcapotzalcoMexico CityMexico
  2. 2.Maestría en Ciencias de la IngenieríaUniversidad Autónoma de ZacatecasZacatecasMexico
  3. 3.Departamento de QuímicaUniversidad Autónoma Metropolitana IztapalapaMexico CityMexico
  4. 4.Unidad Académica de Ciencias Químicas y Maestría en Ciencias de la IngenieríaUniversidad Autónoma de ZacatecasZacatecasMexico

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