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Two cubane-like [M4O4] {M = nickel(II), cobalt(II)} complexes: syntheses, crystal structures and magnetic properties

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Abstract

Two cubane-like complexes, namely [Ni4L4(HOEt)4] (1), [Co4L4(HOEt)4] (2) (H2L = (E)-2-((3-hydroxypropylimino)methyl)-6-methoxyphenol), were prepared under solvothermal conditions. Structural analyses show that complexes 12 are tetranuclear complexes with a cubane topology in which four M atoms and four µ3-O atoms occupy the alternate vertices of the cubane. The magnetic properties of them have been investigated. Antiferromagnetic interactions were observed for complexes 1 and 2.

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References

  1. 1.

    Nakano M, Oshio H (2011) Magnetic anisotropies in paramagnetic polynuclear metal complexes. Chem Soc Rev 40:3239–3248

  2. 2.

    Zhao J, Wang Y-N, Dong W-W, Wu Y-P, Li D-S, Liu B, Zhang Q-C (2015) A new surfactant-introduction strategy for separating the pure single-phase of metal–organic frameworks. Chem Commun 51:9479–9482

  3. 3.

    Wang L-J, Zhang C-S, Xing Y-H, Li Z, Xing N, Wan L-Y, Shan H (2012) Neutral mononuclear, dinuclear, tetranuclear d7/d10 metal complexes containing bis-pyrazole/pyridine ligands supported by 2,6-bis(3-pyrazolyl)pyridine: synthesis, structure, spectra, and catalytic activity. Inorg Chem 51:6517–6528

  4. 4.

    Zhang S-H, Feng C (2010) Microwave-assisted synthesis, crystal structure and fluorescence of novel coordination complexes with Schiff base ligands. J Mol Struct 977:62–66

  5. 5.

    Ungur L, Thewissen M, Costes JP, Wernsdorfer W, Chibotaru LF (2013) Interplay of strongly anisotropic metal ions in magnetic blocking of complexes. Inorg Chem 52:6328–6337

  6. 6.

    Nayak S, Roubeau O, Teat SJ, Beavers CM, Gamez P, Reedijk J (2010) An S-shaped [Fe4Dy2] complex exhibiting slow relaxation of magnetization: synthesis, magnetism, and crystal structures of a family of [Fe4Ln2][Ln] coordination compounds (Ln = Nd, Gd, Tb, Dy, and Ho). Inorg Chem 49:216–221

  7. 7.

    Serna Z, De la Pinta N, Urtiaga MK, Lezama L, Madariaga G, Juan JM, Coronado E, Cortés R (2010) Defective dicubane-like tetranuclear nickel(II) cyanate and azide nanoscale magnets. Inorg Chem 49:11541–11549

  8. 8.

    Petit S, Neugebauer P, Pilet G, Chastanet G, Barra A-L, Antunes AB, Wernsdorfer W, Luneau D (2012) Condensation of a nickel tetranuclear cubane into a heptanuclear single-molecule magnet. Inorg Chem 51:6645–6654

  9. 9.

    Cadiou C, Murrie M, Paulsen C, Villar V, Wernsdorfer W, Winpenny REP (2001) Studies of a nickel-based single molecule magnet: resonant quantum tunnelling in an S = 12 molecule. Chem Commun 24:2666–2667

  10. 10.

    Zhang W-H, Sulaiman NB, Tio PXS, Hor TSA (2011) Nuclearity growth towards Ni(II) cubane in self-assembly with 2-hydroxymethyl pyridine (hmpH) and 5-ethoxycarbonyl-2-hydroxymethyl pyridine (5-ehmpH). CrystEngComm 13:2915–2922

  11. 11.

    Herchel R, Nemec I, Machata M, Trávníček Z (2016) Solvent-induced structural diversity in tetranuclear Ni(ii) Schiff-base complexes: the first Ni4 single-molecule magnet with a defective dicubane-like topology. Dalton Trans 45:18622–18634

  12. 12.

    Das M, Herchel R, Trávníček Z, Bertolasi V, Ray D (2018) Anion coordination directed synthesis patterns for [Ni4] aggregates: structural changes for thiocyanate coordination and ligand arm hydrolysis. New J Chem 42:16717–16728

  13. 13.

    Zhao F-H, Li Z-L, He Y-C, Huang L-W, Jia X-M, Yan X-Q, Wang Y-F, You J-M (2019) 1D water cages in a double-walled framework based on cubic [Ni4(µ 3-OH)4] units: synthesis, structure, and magnetism. J Solid State Chem 271:309–313

  14. 14.

    Zhao F-H, Jia X-M, He Y-C, Huang L-W, Yan X-Q, Li Z-L, Li J-X, Feng R, You J-M (2019) Syntheses and magnetic properties of three transition metal complexes based on 4′-p-tolyl-2,2′:6′,2″-terpyridine and SCN. Polyhedron 173:114124

  15. 15.

    Mitra M, Maji AK, Ghosh BK, Kaur G, Choudhury AR, Lin CH, Ribas J, Ghosh R (2013) Synthesis, crystallographic characterization and catecholase activity of a monocopper(II) and a dimanganese(III) complex with an anionic Schiff base ligand. Polyhedron 61:15–19

  16. 16.

    Chen W-H, Wei H-H, Lee G-H, Wang Y (2001) Dimeric iron(III) complexes with salicylaldimine ligands: structures, magnetic properties, and activity of H2O2 disproportionation. Polyhedron 20:515–521

  17. 17.

    Bhowmik P, Núria AA, Gómez V, Corbella M, Chattopadhyay S (2013) Methylene spacer regulated variation in structures and magnetic properties in copper(II) compounds with O, N, O donor Schiff bases. Polyhedron 49:269–276

  18. 18.

    Lu Z-L, Fan T, Guo W-W, Lu J, Fan C-H (2013) Synthesis, structure and magnetism of three cubane Cu(II) and Ni(II) complexes based on flexible Schiff-base ligands. Inorg Chim Acta 400:191–196

  19. 19.

    Bain GA, Berry JF (2008) Diamagnetic corrections and Pascal’s constants. J Chem Educ 85:532–536

  20. 20.

    Dolomanov OV, Bourhis LJ, Gildea RJ, Howard JAK, Puschmann H (2009) OLEX2: a complete structure solution, refinement and analysis program. J Appl Crystallogr 42:339–341

  21. 21.

    Sheldrick GM (2015) SHELXT-integrated space-group and crystal-structure determination. Acta Cryst A 71:3–8

  22. 22.

    Gatteschi D, Sessoli R (2003) Quantum tunneling of magnetization and related phenomena in molecular materials. Angew Chem Int Ed 42:268–297

  23. 23.

    Song Y, Zhang P, Ren X-M, Shen X-F, Li Y-Z, You X-Z (2005) Octacyanometallate-based single-molecule magnets: CoII9MV6 (M = W, Mo). J Am Chem Soc 127:3708–3709

  24. 24.

    Zhang S-H, Ma L-F, Zou H-H, Wang Y-G, Liang H, Zeng M-H (2011) Anion induced diversification from heptanuclear to tetranuclear clusters: syntheses, structures and magnetic properties. Dalton Trans 40:11402–11409

  25. 25.

    Habib F, Cook C, Korobkov I, Murugesu M (2012) Novel in situ manganese-promoted double-aldol addition. Inorg Chim Acta 380:378–385

  26. 26.

    Gole B, Mondal KC, Mukherjee PS (2014) Tuning nuclearity of clusters by positional change of functional group: synthesis of polynuclear clusters, crystal structures and magnetic properties. Inorg Chim Acta 415:151–164

  27. 27.

    Oshio H, Hoshino N, Ito T, Nakano M (2004) Single-molecule magnets of ferrous cubes: structurally controlled magnetic anisotropy. J Am Chem Soc 126:8805–8812

  28. 28.

    Wang X-T, Wang B-W, Wang Z-M, Zhang W, Gao S (2008) Azide and oxo bridged ferromagnetic clusters: three face-shared tetracubane Ni(II)/Co(II) hexamers and a wheel-shaped SMM-like Co(II) heptamer. Inorg Chim Acta 361:3895–3902

  29. 29.

    Saha S, Pal S, Gómez-García CJ, Clemente-Juan JM, Harms K, Nayek HP (2014) A ferromagnetic tetranuclear nickel(II) Schiff-base complex with an asymmetric Ni4O4 cubane core. Polyhedron 74:1–5

  30. 30.

    Gao Y-Z, Zhang Y-A, Zhang J (2015) Synthesis, structures, and magnetic properties of tetranuclear nickel and cobalt complexes with 2-mercaptobenzoxazole. Inorg Chem Commun 54:85–88

  31. 31.

    Wang H-S, Song Y (2013) Conversion of tetranuclear Ni complexes from a defect dicubane core to a [Ni4O4] cubane-like core via addition of 2-hydroxymethylpyridine: synthesis, crystal structures, and magnetic properties. Inorg Chem Commun 35:86–88

  32. 32.

    Mandal D, Hong C, Kim HC, Fun HK, Ray D (2008) A new [Ni 4 II ] distorted cubane assembly on four solvent derived μ3-OMe corners: solvent dependent formation and cleavage of exogenous bridges. Polyhedron 27:2372–2378

  33. 33.

    Halcrow MA, Sun JS, Huffman JC, Christou G (1995) Structural and magnetic properties of [Ni4(mu3-OMe)4(dbm)4(MeOH)4] and [Ni4(eta1, mu3-N3)4(dbm)4(EtOH)4]. Magnetostructural correlations for [Ni4X4]4 + cubane complexes. Inorg Chem 34:4167–4177

  34. 34.

    Paine TK, Rentschler E, Weyhermuller T, Chaudhuri P (2003) Polynuclear nickel(II) complexes: preparation and magnetic properties of Ni 4 II , Ni 5 II , and Ni 6 II species with ligands containing OXO (X = S, Se or N) donor atoms. Eur J Inorg Chem 2003:3167–3178

  35. 35.

    Zhang S-Y, Chen W-Q, Hu B, Chen Y-M, Li Y-H (2012) A unique tetranuclear cubane-like [Ni4O4] complex supported by hydroxyl-rich ligands: synthesis, crystal structure and magnetic property. Inorg Chem Commun 16:74–77

  36. 36.

    Chilton NF, Anderson RP, Turner LD, Soncini A, Murray KS (2013) PHI: a powerful new program for the analysis of anisotropic monomeric and exchange-coupled polynuclear d- and f- block complexes. J Comput Chem 34:1164–1175

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Acknowledgements

We gratefully acknowledge the financial support from the National Science Foundation of China (Grant No.: 21771061), and A Project of Shandong Province Higher Educational Science and Technology Program (J12LD54), the Youths Science Foundation of Jining University (No. 2017BSZX09) and Talent Culturing Plan for Leading Disciplines of University in Shandong Province.

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Correspondence to Haifeng Zhang.

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Wang, Y., Wang, D., Shu, W. et al. Two cubane-like [M4O4] {M = nickel(II), cobalt(II)} complexes: syntheses, crystal structures and magnetic properties. Transit Met Chem (2020) doi:10.1007/s11243-020-00376-x

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