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Mizoroki–Heck cross-coupling reactions using palladium immobilized on DABCO-functionalized silica

  • Sanjay Jadhav
  • Seema Patil
  • Arjun Kumbhar
  • Santosh Kamble
  • Rajashri SalunkheEmail author
Article

Abstract

A heterogeneous palladium catalyst supported on silica modified by DABCO has been prepared by post-synthetic modification of silica gel. This heterogeneous catalytic system exhibits high activity and stability in the Mizoroki–Heck cross-coupling reaction of various aryl halides with olefins. The reaction proceeds efficiently under efficiently under mild mild reaction conditions and high yield, with the formation of E-isomers selectively. Moreover, we successfully established a gram-scale synthesis, and the catalyst was reused for up to ten catalytic cycles.

Notes

Acknowledgements

Author Sanjay Jadhav thanks the University Grants Commission, New Delhi, India, for the award of SAP-BSR fellowship.

Compliance with ethical standards

Conflicts of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Springer Nature Switzerland AG 2019

Authors and Affiliations

  • Sanjay Jadhav
    • 1
  • Seema Patil
    • 2
  • Arjun Kumbhar
    • 2
  • Santosh Kamble
    • 3
  • Rajashri Salunkhe
    • 1
    Email author
  1. 1.Department of ChemistryShivaji UniversityKolhapurIndia
  2. 2.Department of ChemistryP.D.V.P. CollegeTasgaonIndia
  3. 3.Department of ChemistryYashvantrao Chavan Institute of ScienceSataraIndia

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