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Synthesis, structural analysis, and photophysical properties of bi-1,2,3-triazoles

  • Ivette Santana-Martínez
  • María Teresa Ramírez-Palma
  • Javier Sánchez-Escalera
  • Diego Martínez-Otero
  • Marco A. García-Eleno
  • Alejandro Dorazco-González
  • Erick Cuevas-YañezEmail author
Original Research
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Abstract

Structural insights of a group of bi-1,2,3-triazoles derived from oxidative CuAAC are described through an X-ray crystallography study, distinguishing a dihedral angle which is ranged from 76.45 to 86.39° between the two 1,2,3-triazole rings. In addition, compound 1 containing a phenyl moiety displays a strong blue emission (λem = 394 nm); this structure-related photoluminescence is attributed to the rigidity of the molecule and the conjugation between phenyl groups and the triazole fragments.

Keywords

Bi-1,2,3-triazole Crystal structure Dihedral angle Fluorescent emission 

Notes

Acknowledgments

The authors would like to thank N. Zavala, A. Nuñez, and L. Triana for the technical support.

Funding information

Financial support from CONACYT is gratefully acknowledged.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no competing interests.

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Ivette Santana-Martínez
    • 1
  • María Teresa Ramírez-Palma
    • 1
  • Javier Sánchez-Escalera
    • 1
  • Diego Martínez-Otero
    • 1
  • Marco A. García-Eleno
    • 1
  • Alejandro Dorazco-González
    • 1
  • Erick Cuevas-Yañez
    • 1
    Email author
  1. 1.Centro Conjunto de Investigación en Química Sustentable UAEM-UNAMUniversidad Autónoma del Estado de MéxicoTolucaMexico

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