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Phase Transformations in the Mixed Lithiummagnesium Imide Li2Mg(NH)2

  • Z. A. Matysina
  • S. Yu. ZaginaichenkoEmail author
  • D. V. Schur
  • Al. D. Zolotarenko
  • An. D. Zolotarenko
  • M. T. Gabdulin
  • L. I. Kopylova
  • T. I. Shaposhnikova
Article

A statistical theory of structural-phase transformations in imide Li2Mg(NH)2 is developed, free energies of three phases of imide α, β, γ are calculated, and their state diagrams are determined. Also, the isotherm, isobar, and isopleth curves are examined. Possible manifestation of the hysteretic effect is demonstrated for α- and β-phases. The results of calculations are compared with the experimental data.

Keywords

phase transformations lithium-magnesium imide hydrogen-sorptive properties isotherms isobars and isopleths 

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References

  1. 1.
    Y. Nakamura, M. H. Sorby, H. W. Brinks, and B. C. Hauback, Diffraction Study of Li/Mg Amides and Imides, FUNMAT Meeting Presentation (2006).Google Scholar
  2. 2.
    W. Osborn, T. Markmaitree, and L. L. Shaw, J. Power Sources, 172, No. 1, 376–378 (2007).ADSCrossRefGoogle Scholar
  3. 3.
    R. R. Shahi, T. P. Yadav, M. A. Shaz, and O. N. Srivastava, Int. J. Hydrogen Energy, 33, No. 21, 6188–6194 (2008).CrossRefGoogle Scholar
  4. 4.
    M. Aoki, T. Noritake, Y. Nakamori, et al., Alloys Соmр., 446447, 328–331 (2007).Google Scholar
  5. 5.
    Y. Kojima, Mater. Sci. Forum, 654656, 2935–2938 (2010).Google Scholar
  6. 6.
    O. Dolotko, N. Paulson, and V. K. Pecharsky, Int. J. Hydrogen Energy, 35, No. 10, 4562–4568 (2010).CrossRefGoogle Scholar
  7. 7.
    C. M. Graca Araujo, R. H. Scheicher, P. Jena, and R. Ahuja, Appl. Phys. Lett., 91, No. 9, 091924-1–3 (2007).Google Scholar
  8. 8.
    J. Liu, K. Zhong, M. Gao, et al., Chem. Mater., 20, No. 10, 3521–3527 (2008).CrossRefGoogle Scholar
  9. 9.
    Yo. Liu, Ji. Hu, G. Wu, et al., J. Phys. Chem. C, 112, No. 4, 1293–1298 (2008).CrossRefGoogle Scholar
  10. 10.
    W. F. Luo, J. Alloys Comp., 381, No. 1–2, 284–287 (2004).CrossRefGoogle Scholar
  11. 11.
    R. Janot, J.-В. Eymery, and J.-Μ. Tarascon, J. Power Sources, 164, No. 2, 496–502 (2007).ADSCrossRefGoogle Scholar
  12. 12.
    Z. A. Matysina, S. Yu. Zginaichenko, D. V Schur, et al., Hydrogen in Crystals [in Russian], KIM Publ., Kiev (2017).Google Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2019

Authors and Affiliations

  • Z. A. Matysina
    • 1
  • S. Yu. Zaginaichenko
    • 1
    Email author
  • D. V. Schur
    • 1
  • Al. D. Zolotarenko
    • 1
  • An. D. Zolotarenko
    • 1
  • M. T. Gabdulin
    • 2
    • 3
  • L. I. Kopylova
    • 1
  • T. I. Shaposhnikova
    • 1
  1. 1.I. N. Franzevich Institute of Materials Science Problems of the National Academy of Sciences of UkraineKievUkraine
  2. 2.Kazakh-British Technical UniversityAlmatyKazakhstan
  3. 3.Al-Farabi Kazakh National UniversityAlmatyKazakhstan

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