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Russian Chemical Bulletin

, Volume 68, Issue 1, pp 40–47 | Cite as

Binding of gold(iii) with silver(i) dipropyldithiocarbamate: supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S2CNPr2)2][AgCl2])n

  • E. V. Korneeva
  • A. I. Smolentsev
  • O. N. Antzutkin
  • A. V. IvanovEmail author
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Abstract

The double ionic-polymer complex ([Au(S2CNPr2)2][AgCl2])n (1) was prepared as an individual fixation form of gold(III) from NaCl solutions with silver(I) dipropyldithiocarbamate and was characterized by single-crystal X-ray diffraction and 13C magic-angle spinning (MAS) NMR spectroscopy. The structure of 1 comprises two nonequivalent centrosymmetric complex cations [Au(S2CNPr2)2]+ (A and B) and the discrete linear anion [AgCl2]. Gold(III) cations are linked by pairs of unsymmetrical secondary Au…S bonds to form linear supramolecular chains (…A…B…)n. Neighboring cations are additionally linked by [AgCl2] anions via secondary Ag…S and Cl…S bonds, the anions being involved in the overall stabilization of the supramolecular structure. The cation–anion interactions lead to a distortion of the linear configuration of the [AgCl2] anion. The character of thermolysis of 1 accompanied by quantitative regeneration of bound Au and Ag was established by simultaneous thermal analysis.

Key words

dialkyldithiocarbamates binary complexes noble metals gold silver compounds supramolecular self-assembly secondary interactions 13C MAS NMR spectroscopy thermal behavior 

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Copyright information

© Springer Science+Business Media, Inc. 2019

Authors and Affiliations

  • E. V. Korneeva
    • 1
  • A. I. Smolentsev
    • 2
    • 3
  • O. N. Antzutkin
    • 4
    • 5
  • A. V. Ivanov
    • 1
    Email author
  1. 1.Institute of Geology and Nature ManagementFar-Eastern Branch of the Russian Academy of SciencesBlagoveschenskRussian Federation
  2. 2.Nikolaev Institute of Inorganic ChemistrySiberian Branch of the Russian Academy of SciencesNovosibirskRussian Federation
  3. 3.Novosibirsk State UniversityNovosibirskRussian Federation
  4. 4.Luleå University of TechnologyLuleåSweden
  5. 5.University of WarwickCoventryUnited Kingdom

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