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Russian Chemical Bulletin

, Volume 68, Issue 2, pp 394–399 | Cite as

Substrate-induced luminescence response of terbium-containing polymeric vesicles doped with the tetra- and bis-1,3-diketone derivatives of calix[4]arenes bearing nonyl substituents at the lower rims

  • Yu. G. ElistratovaEmail author
  • B. S. Akhmadeev
  • G. Sh. Gimazetdinova
  • S. N. Podyachev
  • A. R. Mustafina
Full Articles
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Abstract

Polymeric aggregates (~100 nm) based on polydiacetylenic acid doped with the luminescent TbIII complexes with the tetra- and bis-1,3-diketonate derivatives of calix[4]arenes with nonyl substituents at the lower rims are considered as potential nanosensors. The obtained colloidally stable mixed aggregates can generate a substrate-induced luminescent response in aqueous solutions of 2,2´,6´,2´´-terpyridine in the micromolar concentration range due to the coordination of the latter by TbIII ions on the aggregate surface.

Key words

polydiacetylenic acid terbium complexes aggregation luminescence calix[4]-arenes 1,3-diketones mixed-ligand complexation 

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Copyright information

© Springer Science+Business Media, Inc. 2019

Authors and Affiliations

  • Yu. G. Elistratova
    • 1
    Email author
  • B. S. Akhmadeev
    • 2
  • G. Sh. Gimazetdinova
    • 3
  • S. N. Podyachev
    • 1
  • A. R. Mustafina
    • 1
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryFederal Research Center “Kazan Scientific Center of the Russian Academy of Sciences,”KazanRussian Federation
  2. 2.Kazan (Volga Region) Federal UniversityKazanRussian Federation
  3. 3.Kazan National Research Technological UniversityKazanRussian Federation

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