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Russian Chemical Bulletin

, Volume 68, Issue 2, pp 293–300 | Cite as

Influence of the composition on the electrochemical properties of cathode materials xLi2MnO3•(1–x)LiMn1/3Ni1/3Co1/3O2 for lithium-ion batteries

  • L. S. PechenEmail author
  • E. V. Makhonina
  • A. M. Rumyantsev
  • Yu. M. Koshtyal
  • V. V. Volkov
  • A. S. Goloveshkin
  • V. S. Pervov
  • I. L. Eremenko
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Abstract

Lithium-rich transition metal complex oxides of the general composition xLi2MnO3• •(1–x)LiMO2 (M = MnaNibCoc, a + b + c = 1) were synthesized by coprecipitation and modified Pechini method. The influence of the oxide phase composition on their electrochemical performance as cathode materials was studied in lithium half-cells. Effects of the synthetic approach and synthesis conditions on the morphology and electrochemical characteristics of the materials obtained were considered. The composition 0.35Li2MnO3• •0.65LiMn1/3Ni1/3Co1/3O2 demonstrates the highest discharge capacity retention during cycling. The samples with discharge capacity of 290 mA h g–1 were obtained.

Key words

complex inorganic oxides coprecipitation method Pechini method cathode material lithium-ion batteries 

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Copyright information

© Springer Science+Business Media, Inc. 2019

Authors and Affiliations

  • L. S. Pechen
    • 1
    Email author
  • E. V. Makhonina
    • 1
  • A. M. Rumyantsev
    • 2
    • 3
  • Yu. M. Koshtyal
    • 2
    • 3
  • V. V. Volkov
    • 1
  • A. S. Goloveshkin
    • 4
  • V. S. Pervov
    • 1
  • I. L. Eremenko
    • 1
  1. 1.N. S. Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.A. F. Ioffe Physico-Technical InstituteRussian Academy of SciencesSt. PetersburgRussian Federation
  3. 3.Peter the Great St. Petersburg Polytechnic UniversitySt. PetersburgRussian Federation
  4. 4.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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