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Russian Chemical Bulletin

, Volume 68, Issue 2, pp 217–253 | Cite as

Mercury derivatives of polyhedral boranes, carboranes, and metallacarboranes

  • I. B. SivaevEmail author
  • M. Yu. Stogniy
Reviews
  • 5 Downloads

Abstract

The review concerns the synthesis, structure, and chemical transformations of mercury derivatives of various polyhedral boron hydrides (carboranes, metallacarboranes, and boranes) and covers a period of time since the pioneering studies of Prof. V. I. Bregadze on chemistry of C- and B-substituted derivatives of icosahedral carboranes C2B10H12 up to date. The emphasis is placed on recent results obtained in this field, in particular, Hg-promoted substitution in nido-carboranes as well as the synthesis and properties of mercury derivatives of monocarbon carborane anion [CB11H12].

Key words

carboranes metallacarboranes mercury derivatives synthesis structure 

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© Springer Science+Business Media, Inc. 2019

Authors and Affiliations

  1. 1.A. N. Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussian Federation

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