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Russian Chemical Bulletin

, Volume 67, Issue 11, pp 2044–2048 | Cite as

Synthesis and structural investigation of 4,4′-dimethyl-[3,3′-bi(1,2,5-oxadiazole)] 5,5′-dioxide

  • N. V. Obruchnikova
  • R. A. Novikov
  • S. G. Zlotin
  • P. V. Dorovatovskii
  • V. N. Khrustalev
  • O. A. RakitinEmail author
Full Articles
  • 18 Downloads

Abstract

The oxidation of hexane-2,3,4,5-tetraone tetraoxime with dinitrogen tetroxide was studied in different solvents. The primary furoxan ring closure was found to occur involving either two central or two terminal oxime groups to form 4,7-dimethyl[1,2,5]oxadiazolo[3,4-d]pyridazine 1,5,6-trioxide and the previously unknown 4,4′-dimethyl-[3,3′-bi(1,2,5-oxadiazole)] 5,5′-dioxide. The structure of the latter compound was established by X-ray diffraction.

Key words

difuroxanyls 2,3,4,5-tetraone tetraoximes oxidation dinitrogen tetroxide synthesis 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • N. V. Obruchnikova
    • 1
  • R. A. Novikov
    • 1
  • S. G. Zlotin
    • 1
  • P. V. Dorovatovskii
    • 2
  • V. N. Khrustalev
    • 2
    • 3
  • O. A. Rakitin
    • 1
    Email author
  1. 1.N. D. Zelinsky Institute of Organic ChemistryRussian Academy of SciencesMoscowRussian Federation
  2. 2.National Research Center “Kurchatov Institute”MoscowRussian Federation
  3. 3.Peoples’ Friendship University of Russia (RUDN University)MoscowRussian Federation

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