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Russian Chemical Bulletin

, Volume 67, Issue 11, pp 2003–2009 | Cite as

Mechanochemical synthesis of platinum(IV) complexes with N-heterocyclic carbenes

  • I. E. Chikunov
  • G. S. Ranny
  • A. V. Astakhov
  • V. A. Tafeenko
  • V. M. ChernyshevEmail author
Full Articles
  • 14 Downloads

Abstract

A new method for the synthesis of complexes PtIV(NHC)X4L (NHC is N-heterocyclic carbene of imidazole or benzimidazole series; X = Cl, Br; L is N-coordinated pyridine or NHC) based on mechanochemical oxidation of complexes PtII(NHC)X2L with dichloroiodobenzene (PhICl2) or pyridinium hydrobromide perbromide (PyHBr3) was proposed. Mechanochemical activation led to reduction in the synthesis time and increase in the selectivity of halogenation and yields of the target PtIV complexes (74–98%) as compared to the reaction in solutions.

Key words

mechanochemical synthesis N-heterocyclic carbenes (NHC) platinum coordination compounds oxidation halogenation 

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Copyright information

© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • I. E. Chikunov
    • 1
  • G. S. Ranny
    • 1
  • A. V. Astakhov
    • 1
  • V. A. Tafeenko
    • 2
  • V. M. Chernyshev
    • 1
    Email author
  1. 1.Platov South-Russian State Polytechnic University (NPI)NovocherkasskRussian Federation
  2. 2.Lomonosov Moscow State UniversityMoscowRussian Federation

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