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Russian Chemical Bulletin

, Volume 67, Issue 10, pp 1903–1907 | Cite as

Polyheteroarylenes based on 2,3,7,8-tetraaminodibenzo-p-dioxin and aromatic polyfunctional carboxylic acids

  • D. M. Mognonov
  • O. Zh. Ayurova
  • O. V. Il’ina
  • V. V. Khakhinov
Article
  • 4 Downloads

Abstract

Polynaphthoylene benzimidazole and polybenzimidazole were obtained via polycondensation of 2,3,7,8-tetraaminodibenzo-p-dioxin with aromatic di- and tetracarboxylic acids in polyphosphoric acid. From a solution of polynaphthoylene benzimidazole in methanesulfonic acid a heat-resistant fiber with high tensile strength was obtained. Aromatic polybenzimidazoles are promising materials for producing membranes of medium-temperature fuel cells.

Key words

2,3,7,8-tetraaminodibenzo-p-dioxin isophthalic acid terephthalic acid 1,4,5,8-naphth alenetetracarboxylic acid dianhydride polynaphthoylene benzimidazole polybenzimidazoles polycondensation solubility thermal stability mechanical properties proton conductivity heat-resistant fibers 

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Baikal Institute of Nature ManagementSiberian Branch of the Russian Academy of SciencesUlan-UdeRussian Federation
  2. 2.Buryat State UniversityUlan-UdeRussian Federation

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