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Russian Chemical Bulletin

, Volume 67, Issue 10, pp 1807–1813 | Cite as

Methane adsorption on various metal-organic frameworks and determination of the average adsorption heats at supercritical temperatures and pressures

  • A. A. Pribylov
  • K. O. Murdmaa
  • O. V. Solovtsova
  • M. K. Knyazeva
Article

Abstract

Adsorption of methane on three samples of metal-organic framework structures (MOF), which contain copper, aluminum or zinc atoms, was measured at temperatures ranging from 303 to 333 K and pressures up to 40 MPa using a precise volumetric-gravimetric unit. The determined values of adsorption volumes and characteristic energies served to evaluate the average heats of adsorption, which were compared to the average isosteric heats of adsorption.

Key words

adsorption metal-organic frameworks (MOF) methane adsorption isotherm average adsorption heats isosteric adsorption heats characteristic energy of adsorption 

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  • A. A. Pribylov
    • 1
  • K. O. Murdmaa
    • 1
  • O. V. Solovtsova
    • 1
  • M. K. Knyazeva
    • 1
  1. 1.A. N. Frumkin Institute of Physical Chemistry and ElectrochemistryRussian Academy of SciencesMoscowRussian Federation

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