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One-step synthesis of an environment-friendly cyclodextrin-based nanosponge and its applications for the removal of dyestuff from aqueous solutions

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Abstract

Cyclodextrin-based nanosponges (CDNS) are a novel kind of polymers belonged to cross-linked derivatives of cyclodextrins, and they are safe, biodegradable materials with appreciable toxicity to the environment. In this work, CDNS were fabricated in one-step solvothermal method by β-cyclodextrin (β-CD) and diphenyl carbonate (DPC), for the removal of dyestuffs from wastewater using two of the familiar dyes as the model contaminant. It was systematically investigated by the influence of the amount of adsorbent, the molar ratio of β-CD and DPC, pH, time, and initial concentration. Experimental results showed the maximum adsorption capacities of Basic red 46 and Rhodamine B were 101.43 mg/g and 52.33 mg/g, the adsorption behavior of two contaminants followed pseudo-second-order model and the Langmuir monolayer adsorption models. The differences in adsorption capacities on two model contaminants might due to the influence of dye structure. In conclusion, cyclodextrin-based nanosponges are a promising kind of environment-friendly materials in water treatment.

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References

  1. 1.

    H. Ali, Water Air Soil Pollut. 213, 1 (2010)

  2. 2.

    T. Robinson, G. McMullan, R. Marchant, P. Nigam, Bioresour. Technol. 77, 3 (2001)

  3. 3.

    S. Chen, M. Cai, X. Ma, J. Alloys Compd. 689, 36 (2016)

  4. 4.

    V.K. Gupta, G. Sharma, D. Pathania, N.C. Kothiyal, J. Ind. Eng. Chem. 21, 957 (2015)

  5. 5.

    H.S. Lin, M.C. Lin, Water Res. 27, 12 (1993)

  6. 6.

    S.A. Mirbagheri, A. Charkhestani, Desalin. Water Treat. 57, 20 (2016)

  7. 7.

    J. Shah, M.R. Jan, F. Khitab, Process Saf. Environ. 116, 149 (2018)

  8. 8.

    Z. Karim, A.P. Mathew, M. Grahn, J. Mouzon, K. Oksman, Carbohydr. Polym. 112, 668 (2014)

  9. 9.

    X. Liang, Y. Lu, Z. Li, C. Yang, C. Niu, X. Su, Microporous Mesoporous Mater. 241, 107 (2017)

  10. 10.

    E. Errais, J. Duplay, F. Darragi, I. M’Rabet, A. Aubert, F. Huber, G. Morvan, Desalination 275, 1 (2011)

  11. 11.

    L. Fan, Y. Zhang, C. Luo, F. Lu, H. Qiu, M. Sun, Biol. Macromol. 50, 2 (2012)

  12. 12.

    R.A. Osmani, P. Kulkarni, S. Manjunatha, V. Gowda, U. Hani, R. Vaghela, R. Bhosale, Cyclodextrin nanosponges in drug delivery and nanotherapeutics. (2018). https://doi.org/10.1007/978-3-319-76090-2_9

  13. 13.

    L. Guo, G. Ge, X. Liu, F. Liu, Mater. Chem. Phys. 111, 2 (2008)

  14. 14.

    S. Borini, S. D’Auria, M. Rossi, A.M. Rossi, Lab Chip 5, 10 (2005)

  15. 15.

    V. Davankov, M.M. Ilyin, M.P. Tsyurupa, G.I. Timofeeva, L.V. Dubrovina, Macromolecules 29, 26 (1996)

  16. 16.

    H. Bricout, F. Hapiot, A. Ponchel, S. Tilloy, E. Monflier, Sustainability 1, 4 (2009)

  17. 17.

    R. Cavalli, F. Trotta, W. Tumiatti, J. Incl. Phenom. Macrocycl. 56, 1 (2006)

  18. 18.

    L. Seglie, K. Martina, M. Devecchi, C. Roggero, F. Trotta, V. Scariot, Postharvest Biol. Technol. 59, 2 (2010)

  19. 19.

    S. Sadjadi, M.M. Heravi, M. Daraie, Res. Chem. Intermed. 43, 2 (2017)

  20. 20.

    A. Rostami-Vartooni, M. Nasrollahzadeh, M. Salavati-Niasari, M. Atarod, J. Alloys Compd. 689, 15 (2016)

  21. 21.

    Y. Tingting, X. Zhimin, Z. Xinhui, C. Wenjun, M. Tiancheng, New J. Chem. 42, 16154 (2018)

  22. 22.

    J.L. Atwood, J.-M. Lehn, Cryst. Eng. 6, 3 (1996)

  23. 23.

    A.E.H.P. D. Chirality 19, 2 (2007)

  24. 24.

    N. Morin-Crini, G. Crini, Prog. Polym. Sci. 38, 2 (2013)

  25. 25.

    K.A. Ansari, S.J. Torne, P.R. Vavia, F. Trotta, R. Cavalli. Curr. Drug Deliv. 8, 194 (2011)

  26. 26.

    Z. Yanbo, L. Jian, Z. Yi, L. Yongdi. Environ. Pollut. (Barking, Essex: 1987) 252, Pt A (2019)

  27. 27.

    R. Zhang, Y. Zhou, X. Gu, J. Lu, Clean Soil Air Water 43, 1 (2014)

  28. 28.

    R. Pushpalatha, S. Selvamuthukumar, D. Kilimozhi, J. Drug Deliv. Sci. Technol. 45, 45 (2018)

  29. 29.

    Z. Feiping, R. Eveliina, Y. Dulin, M. Yong, J. Shila, S. Mika, Environ. Sci. Technol. 49, 17 (2015)

  30. 30.

    A. Alsbaiee, B.J. Smith, L. Xiao, Y. Ling, D.E. Helbling, W.R. Dichtel, Nature 529, 190 (2016)

  31. 31.

    H. Amjad, S. Miklas, Environ. Sci. Pollut. Res. 25, 7 (2018)

  32. 32.

    C. Yang, S. Wu, J. Cheng, Y. Chen, J. Alloys Compd. 687, 804 (2016)

  33. 33.

    V. Singh, T. Guo, L. Wu, J. Xu, B. Liu, R. Gref, J. Zhang, RSC Adv. 34, 7 (2017)

  34. 34.

    F. Trotta, V. Tumiatti, R. Cavalli, C. Roggero, B. Mognetti, G. Berta, WO 3656, A1 (2009)

  35. 35.

    A.R. Kiasat, S. Nazari, J. Mol. Catal. A Chem. 365, 80 (2012)

  36. 36.

    X. He, Z. Wu, Z. Sun, X. Wei, Z. Wu, X. Ge, G. Cravotto, J. Mol. Liq. 255, 160 (2018)

  37. 37.

    C. Qi, H. Liu, S. Deng, A.H. Yang, Z. Li, Res. Chem. Intermed. 44, 4 (2018)

  38. 38.

    R. Mirzajani, N. Pourreza, S.S.A. Najjar, Res. Chem. Intermed. 40, 8 (2014)

  39. 39.

    Y. He, Z. Xu, F. Wu, Q. Yang, J. Zhang, J. Chem. Technol. Biotechnol. 90, 2257 (2014)

  40. 40.

    P.L. Meo, G. Lazzara, L. Liotta, S. Riela, R. Noto, Polym Chem. 5, 15 (2014)

  41. 41.

    S. Çoruh, E.H. Gürkan, Environ. Prog. Sustain. 33, 4 (2014)

  42. 42.

    C. Demirbilek, C.Ö. Dinç, Desalin. Water Treat. 57, 15 (2016)

  43. 43.

    P.K. Shende, F. Trotta, R.S. Gaud, K. Deshmukh, R. Cavalli, M. Biasizzo, J. Polym. Environ. 74, 1 (2012)

  44. 44.

    S. Shankar, P. Linda, S. Loredana, T. Francesco, V. Pradeep, A. Dino, T. Michele, Z. Gianpaolo, C. Roberta, Eur. J. Pharm. Biopharm. 74, 2 (2009)

  45. 45.

    F. Deniz, S. Karaman, Chem. Eng. J. 170, 1 (2011)

  46. 46.

    A. Lunhong, Z. Chunying, C. Zhonglan, J. Hazard. Mater. 192, 2 (2016)

  47. 47.

    X. Li, X.-J. Nie, Y.-N. Zhu, W.-C. Ye, Y.-L. Jiang, S.-L. Su, B.-T. Yan, Colloid Surf. A 578, 123582 (2019)

  48. 48.

    Y. Bulut, H. Aydın, Desalination 194, 1 (2005)

  49. 49.

    A. Lunhong, Z. Chunying, C. Zhonglan, J. Hazard. Mater. 192, 3 (2011)

  50. 50.

    M. Mohammadi, A.J. Hassani, A.R. Mohamed, G.D. Najafpour, J. Chem. Eng. Data 55, 12 (2010)

  51. 51.

    A.Z.M. Badruddoza, G.S.S. Hazel, K. Hidajat, M.S. Uddin, Colloid Surf. A 367, 1 (2010)

  52. 52.

    L. Yaoyue, Z. Yanbo, Z. Yi, L. Juying, P. Shengyan, Water Sci. Technol. 78, 12 (2018)

  53. 53.

    S.H. Mousavi, A. Mohammadi, Process Saf. Environ. 114, 1 (2018)

  54. 54.

    L. Qiming, L. Yaoyue, C. Huafeng, L. Jian, Y. Guangsuo, M. Maxim, Z. Yanbo, J. Hazard. Mater. 382, 121040 (2020)

  55. 55.

    Y. Wang, L. Zhao, J. Hou, H. Peng, Water Sci. Technol. 77, 2699 (2018)

  56. 56.

    F. Deniz, S.D. Saygideger, Desalination 262, 1 (2010)

  57. 57.

    L. Laila, E.M. Khalid, C. Omar, Environ. Sci. Pollut. Res. 14, 4 (2007)

  58. 58.

    F. Deniz, S.D. Saygideger, Desalination 268, 1 (2010)

  59. 59.

    A.B. Karim, B. Mounir, M. Hachkar, M. Bakasse, A. Yaacoubi, J. Hazard. Mater. 168, 1 (2009)

  60. 60.

    T.A. Khan, S. Dahiya, I. Ali, Appl. Clay Sci. 69, 58 (2012)

  61. 61.

    S.M. Al-Rashed, A.A. Al-Gaid, J Saudi Chem Soc. 16, 2 (2012)

  62. 62.

    S.H. Chang, K.S. Wang, H.C. Li, M.Y. Wey, J.D. Chou, J. Hazard. Mater. 172, 2 (2009)

  63. 63.

    J.H. Huang, K.L. Huang, S.-Q. Liu, A.-T. Wang, C. Yan, Colloid Surf. A 330, 55 (2008)

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Acknowledgements

We acknowledged the financial support of this work by National Natural Science Foundation of China (No. 11375084) and Nature Science Foundation of Hunan (No. 2017JJ4046).

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Correspondence to Huijun Liu.

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Li, L., Liu, H., Li, W. et al. One-step synthesis of an environment-friendly cyclodextrin-based nanosponge and its applications for the removal of dyestuff from aqueous solutions. Res Chem Intermed 46, 1715–1734 (2020). https://doi.org/10.1007/s11164-019-04059-w

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Keywords

  • Cyclodextrin-based nanosponge
  • Basic red 46
  • Rhodamine B
  • Adsorption
  • Environment-friendly