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A hybrid composite of rhenium complexes covalently grafted on reduced graphene oxide/hydrogenated TiO2 as an efficient catalyst for CO2 reduction under visible light

  • Chen-Xi Tian
  • Shi-Cong CuiEmail author
  • Xiang-Yu Liu
  • Jin-Gang LiuEmail author
Article
  • 18 Downloads

Abstract

The photocatalytic conversion of CO2 to fuels by light is of research interest owing to its relevance to environment and energy concerns. In this work, a hybrid H-TiO2–rGO–Re(bpy)(CO)3Cl composite consisting of a rhenium 2,2′-bipyridine compound, Re(bpy)(CO)3Cl, which was covalently grafted on reduced graphene oxide (rGO) and hydrogenated TiO2 (H-TiO2) was prepared. H-TiO2–rGO–Re(bpy)(CO)3Cl demonstrated high efficiency for visible light photo-conversion of CO2 into CO in triethanolamine/N,N-dimethylformamide (V:V = 1:9) solution with total turnover numbers larger than 580. In addition, the composite showed high stability with no leveling-off tendency after four catalytic experimental runs. The experimental results indicate that the suitable assembly of the Re(bpy)(CO)3Cl, rGO, and H-TiO2 components in the H-TiO2–rGO–Re(bpy)(CO)3Cl composite is necessary for the observed high performance of the catalyst for CO2 reduction under visible light irradiation.

Graphic abstract

Keywords

Hydrogenated TiO2 Rhenium complex Reduced graphene oxide Covalent grafting CO2 photoreduction 

Notes

Acknowledgements

This study was financially supported by the NSF of China (Nos. 21571063 to SCC, 21571062 to JGL), the Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning to JGL.

Supplementary material

11164_2019_4028_MOESM1_ESM.pdf (802 kb)
Supplementary material 1 (PDF 802 kb)

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.Key Lab for Advanced Materials, School of Chemistry & Molecular EngineeringEast China University of Science and TechnologyShanghaiPeople’s Republic of China

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