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An efficiently and quickly synthesized NiO@g-C3N4 nanocomposite-catalyzed green synthesis of spirooxindole derivatives

  • Zahra Amini Moqadam
  • Ali Allahresani
  • Hassan HassaniEmail author
Article
  • 19 Downloads

Abstract

NiO@g-C3N4 as an efficient catalyst for the synthesis of spirooxindole derivatives was prepared by impregnation of g-C3N4 with NiO nanoparticles and characterized by various techniques including thermogravimetric analysis, transmission electron microscopy, X-ray diffraction and Fourier transform infrared spectroscopy. The one-pot synthesis of spirooxindole derivatives using 1 mmol isatin, 1 mmol dimedone (or 4-hydroxycoumarin or ethyl acetoacetate) and 1 mmol malononitrile was carried out in the presence of 50 mg NiO@g-C3N4 in EtOH media at reflux conditions. The results showed that both series of reactions had short reaction times (less than 7 min) and high reaction efficiency (greater than 87%). Some advantages can be cited for this method, including short reaction time, excellent yields, easy workup and a reusable and inexpensive nanocatalyst.

Keywords

4-Hydroxycoumarin Dimedone Isatin Malononitrile NiO@g-C3N4 Spirooxindole derivatives 

Notes

Acknowledgements

The authors are grateful to the University of Birjand and Payam Noor University of Mashhad for financial support.

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  • Zahra Amini Moqadam
    • 1
  • Ali Allahresani
    • 2
  • Hassan Hassani
    • 1
    Email author
  1. 1.Department of ChemistryPayam Noor UniversityMashhadIran
  2. 2.Department of Chemistry, Faculty of SciencesUniversity of BirjandBirjandIran

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