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Research on Chemical Intermediates

, Volume 45, Issue 5, pp 2927–2945 | Cite as

Synthesis of Mn-doped TiO2 by novel route and photocatalytic mineralization/intermediate studies of organic pollutants

  • Khalid UmarEmail author
  • Mohamad Nasir Mohamad IbrahimEmail author
  • Akil Ahmad
  • Mohd Rafatullah
Article

Abstract

The doping of TiO2 particles with various manganese (Mn) concentrations (0.25–1.0%) were synthesized using simple sol–gel and modified sol–gel technique. The characteristics of synthesized particles were found employing standard analytical techniques such as X-ray diffraction, scanning electron microscopy and UV–Vis spectroscopy. The photocatalytic activity of the synthesized particles was compared by investigating the mineralization of two selected organic pollutants like ketoprofen and chlorothalonil. The photocatalysts which were produced by improved sol–gel technique show the lower value of band gap energy and small size crystallite and, hence, exhibit better photocatalytic activity. The outcomes also designate that the concentration of dopant Mn 0.75% indicated the highest photocatalytic activity than other concentrations of dopant in the mineralization of both the compounds. The mineralization kinetics of both compounds was studied under various situations like reaction pH and catalyst dosage. The mineralization rates were highly affected by all the above parameters. An effort has also been performed to highlight the intermediates produced during the photooxidation of both the compounds using the GC–MS analysis method. Both compounds show the production of several intermediates. A possible pathway for the production of different products has been suggested.

Keywords

Ketoprofen Chlorothalonil Doped-titanium dioxide Semiconductor Intermediate products 

Notes

Acknowledgements

The authors gratefully acknowledge the post doctoral financial support (USM/PPSK/FPD(BW) 1/06 (2018) and a research grant (304/PKIMIA/6316174) by School of Chemical Science, Universiti Sains Malaysia.

References

  1. 1.
    A. Jakimska, M. Śliwka-Kaszyńska, J. Reszczyńska, J. Namieśnik, A. Kot-Wasik, Anal. Bioanal. Chem. 406, 3667 (2014)CrossRefPubMedPubMedCentralGoogle Scholar
  2. 2.
    T. Heberer, U. Dunnbier, C. Reilich, H.J. Stan, Fresen. Environ. Bull. 6, 438 (1997)Google Scholar
  3. 3.
    T. Kosjek, E. Heath, B. Kompare, Anal. Bioanal. Chem. 387, 1379 (2007)CrossRefPubMedGoogle Scholar
  4. 4.
    M. Klavarioti, D. Mantzavinos, D. Kassinos, Environ. Int. 35, 402 (2009)CrossRefPubMedGoogle Scholar
  5. 5.
    N. Vieno, T. Tunkanen, L. Kronberg, Water Res. 41, 1001 (2007)CrossRefPubMedGoogle Scholar
  6. 6.
    F. Mendez-Arriaga, S. Esplugas, J. Gimenez, Water Res. 42, 585 (2008)CrossRefPubMedGoogle Scholar
  7. 7.
    P.K. Gupta, Toxicity of Fungicides Veterinary Toxicology (Third Edition) Basic and Clinical Principles, 2018, p. 569Google Scholar
  8. 8.
    G.A. Peñuelas, D. Barcelo, J. Chromatogr. A 823, 81 (1998)CrossRefGoogle Scholar
  9. 9.
    N. Voulvoulis, M.D. Scrimshaw, J.N. Lester, Chemosphere 38, 3503 (1999)CrossRefGoogle Scholar
  10. 10.
    V.A. Sakkas, D.A. Lambropoulou, T.A. Albanis, Chemosphere 48, 939 (2002)CrossRefPubMedGoogle Scholar
  11. 11.
    K. Kummerer, in Pharmaceuticals in the environment, 2nd edn., ed. by K. Kummerer (Springer, Berlin, 2004), p. 3CrossRefGoogle Scholar
  12. 12.
    M. Neumann, R. Schulz, K. Schafer, W. Muller, W. Mannheller, M. Liess, Water Res. 36, 835 (2002)CrossRefPubMedGoogle Scholar
  13. 13.
    M.E. DeLorenzo, G.I. Scott, P.E. Ross, Environ. Toxicol. Chem. 20, 84 (2000)CrossRefGoogle Scholar
  14. 14.
    A.C. Affam, M. Chaudhuri, J. Environ. Manag. 130, 160 (2013)CrossRefGoogle Scholar
  15. 15.
    J. Zhou, Y. Zhang, X.S. Zhao, A.K. Ray, Ind. Eng. Chem. Res. 45, 3503 (2006)CrossRefGoogle Scholar
  16. 16.
    K. Umar, A. Aris, T. Parveen, J. Jaafar, Z.A. Majid, A.V.B. Reddy, J. Talib, Appl. Catal. A 505, 507 (2015)CrossRefGoogle Scholar
  17. 17.
    K. Umar, A. Aris, H. Ahmad, T. Parveen, J. Jaafar, Z.A. Majid, A.V.B. Reddy, J. Talib, J. Anal. Sci. Technol. 7, 29 (2016)CrossRefGoogle Scholar
  18. 18.
    S.E.M. Ghahfarokhi, E.M. Shobegar, J. Alloys Compd. 768, 65 (2018)CrossRefGoogle Scholar
  19. 19.
    M. Taheri, H. Abdizadeh, M.R. Golobostanfard, J. Alloys Compd. 725, 291 (2017)CrossRefGoogle Scholar
  20. 20.
    S. Gnanam, V. Rajendran, J. Alloys Compd. 735, 1854 (2018)CrossRefGoogle Scholar
  21. 21.
    N.A. Mir, M.M. Haque, A. Khan, K. Umar, M. Muneer, S. Vijayalakshmi, J. Adv. Oxid. Technol. 15, 252 (2012)Google Scholar
  22. 22.
    A.A. Dar, K. Umar, N.A. Mir, M.M. Haque, M. Muneer, C. Boxall, Res. Chem. Intermed. 37, 567 (2011)CrossRefGoogle Scholar
  23. 23.
    N.A. Mir, A. Khan, K. Umar, M. Muneer, Energy Environ. 2, 208 (2013)Google Scholar
  24. 24.
    K. Umar, M.M. Haque, M. Muneer, T. Harada, M. Matsumura, J. Alloys Compd. 578, 431 (2013)CrossRefGoogle Scholar
  25. 25.
    L.G. Devi, N. Murthy, Catal. Lett. 125, 320 (2008)CrossRefGoogle Scholar
  26. 26.
    T. Peng, D. Zhao, H. Song, C. Yan, J. Mol. Catal. A Chem. 238, 119 (2005)CrossRefGoogle Scholar
  27. 27.
    L.G. Devi, N. Kottam, S.G. Kumar, J. Phys. Chem. C 113, 15593 (2009)CrossRefGoogle Scholar
  28. 28.
    L.G. Devi, S.G. Kumar, B.N. Murthy, N. Kottam, Catal. Commun. 10, 794 (2009)CrossRefGoogle Scholar
  29. 29.
    Y.W. Wang, L. Zhang, S. Li, P. Jena, J. Phys. Chem. C 113, 9210 (2009)CrossRefGoogle Scholar
  30. 30.
    V. Stengl, S. Bakardjieva, N. Murafa, Mater. Chem. Phys. 114, 217 (2009)CrossRefGoogle Scholar
  31. 31.
    A.D. Paola, G. Marci, L. Palmisano, M. Schiavello, K. Uosaki, S. Ikeda, B. Ohtani, J. Phys. Chem. B 106, 637 (2002)CrossRefGoogle Scholar
  32. 32.
    J. Augustynski, Structural Bonding (Springer, Berlin, 1988)Google Scholar
  33. 33.
    G.C. Martinez, J. Lydia, J.C. Sacaiano, Phys. Chem. Chem. Phys. 1, 3533 (1999)CrossRefGoogle Scholar
  34. 34.
    K. Umar, A.A. Dar, M.M. Haque, N.A. Mir, M. Muneer, Desalin. Water Treat. 46, 205 (2012)CrossRefGoogle Scholar
  35. 35.
    K. Umar, M.M. Haque, N.A. Mir, M. Muneer, J. Adv. Oxid. Technol. 16, 252 (2013)Google Scholar

Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  1. 1.School of Chemical SciencesUniversiti Sains MalaysiaGelugorMalaysia
  2. 2.School of Industrial TechnologyUniversiti Sains MalaysiaGelugorMalaysia

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