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A magnetically recoverable copper–salen complex as a nano-catalytic system for amine protection via acetylation using thioacetic acid

  • Elahe Yazdani
  • Maryam Kazemi Miraki
  • Arefe Salamatmanesh
  • Jamshid Azarnia
  • Kobra Azizi
  • Leila Ghandi
  • Akbar HeydariEmail author
Article
  • 12 Downloads

Abstract

A novel copper(II)–salen complex was immobilized on the surface of magnetite nanoparticles using chitosan as a linker. This system exhibits superior catalytic activity in acetyl protection of various amines with thioacetic acid as the acetylating reagent. The method has advantages over others in high selectivity, simple work-up, green reaction medium and the application of an easily recoverable heterogeneous catalyst.

Keywords

Thioacetic acid Copper–salen complex Magnetite Nano catalyst N-Acetylation 

Notes

Acknowledgement

We acknowledge Tarbiat Modares University for partial support of this work.

Supplementary material

11164_2018_3702_MOESM1_ESM.docx (2.3 mb)
Supplementary material 1 (DOCX 2334 kb)

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Copyright information

© Springer Nature B.V. 2019

Authors and Affiliations

  • Elahe Yazdani
    • 1
  • Maryam Kazemi Miraki
    • 1
  • Arefe Salamatmanesh
    • 1
  • Jamshid Azarnia
    • 1
  • Kobra Azizi
    • 1
  • Leila Ghandi
    • 1
  • Akbar Heydari
    • 1
    Email author
  1. 1.Chemistry DepartmentTarbiat Modares UniversityTehranIran

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