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Research on Chemical Intermediates

, Volume 45, Issue 2, pp 663–686 | Cite as

The promotional effects of cerium on the catalytic properties of Al2O3-supported MnFeOx for NO oxidation and fast SCR reaction

  • Yan GaoEmail author
  • Tao Luan
  • Wenke Zhang
  • Hui Li
Article
  • 82 Downloads

Abstract

To reveal the cooperative effects of cerium with manganese and iron on the catalytic oxidation of NO to NO2 and the catalytic activity in the fast selective catalytic reduction (SCR) reaction, Ce–MnFeOx/Al2O3 catalysts were prepared with different amounts of cerium doping. The results showed that the oxidation rate of NO to NO2 achieved by MnFeOx/Al2O3 was obviously improved with cerium doping. The highest catalytic activity, corresponding to NOx conversion >95.5% within the range of 100–350 °C and NO oxidation rate of 55.1% at 350 °C, was obtained when using Ce1.0–MnFeOx/Al2O3 (Ce:Fe:Mn = 1:2:16), Furthermore, according to characterization by scanning electron microscopy (SEM), X-ray diffraction (XRD), H2-temperature-programmed reduction (TPR), NH3-temperature-programmed desorption (TPD), NO-TPD, and X-ray photoelectron spectroscopy (XPS) techniques, the active element dispersion and combination of iron and manganese were both enhanced with cerium doping, while the metal oxide crystallinity was reduced. Cerium doping improved the Mn4+/(Mn2+ + Mn3+ + Mn4+) and Fe3+/(Fe2+ + Fe3+) ratios, while increasing the amounts of lattice oxygen and oxygen vacancies, thereby promoting the oxidation rate of NO to NO2 and ultimately facilitating the fast SCR reaction. However, excess cerium doping led to crystallization of ceria. This study revealed that Ce1.0–MnFeOx/Al2O3 has potential for application as an excellent catalyst with efficient catalytic activity in NO preoxidation and the fast SCR reaction.

Graphical abstract

Keywords

NO oxidation Fast SCR NOx conversion Cerium MnFeOx 

Notes

Acknowledgements

This work was supported by the Shandong Provincial Natural Science Foundation (ZR2016EEB28), the Shandong Provincial Science and Technology Development Plan (2011GSF11716), and the Shandong Electric Power Engineering Consulting Institute science and technology project (37-K2014-33).

Compliance with ethical standards

Conflict of interest

The authors declare that there are no conflicts of interest.

References

  1. 1.
    Q. Yan, S. Chen, C. Zhang, D. O’Hare, Q. Wang, J. Colloid Interface Sci. 526, 63 (2018)Google Scholar
  2. 2.
    X. Wang, Y. Shi, S. Li, W. Li, Appl. Catal. B: Environ. 220, 234 (2018)Google Scholar
  3. 3.
    L. Cao, L. Chen, X. Wu, R. Ran, T. Xu, Z. Chen, D. Weng, Appl. Catal. A: Gen. 557, 46 (2018)Google Scholar
  4. 4.
    M. Koebel, M. Elsener, Chem. Eng. Sci. 53(4), 657 (1998)Google Scholar
  5. 5.
    M. Bendrich, A. Scheuer, R.E. Hayes, M. Votsmeier, Appl. Catal. B: Environ. 222, 76 (2018)Google Scholar
  6. 6.
    Z. Zhou, X. Liu, Y. Hu, J. Xu, X.E. Cao, Z. Liao, M. Xu, Fuel 225, 134 (2018)Google Scholar
  7. 7.
    R. Pérez Vélez, I. Ellmers, H. Huang, U. Bentrup, V. Schünemann, W. Grünert, A. Brückner, J. Catal. 316, 103 (2014)Google Scholar
  8. 8.
    S. Roy, M.S. Hegde, G. Madras, Appl. Energy 86(11), 2283 (2009)Google Scholar
  9. 9.
    Y. Gao, T. Luan, T. Lu, K. Cheng, H. Xu, Chin. J. Chem. Eng. 21(1), 1 (2013)Google Scholar
  10. 10.
    G. Li, B. Wang, H. Wang, J. Ma, W.Q. Xu, Y. Li, Y. Han, Q. Sun, Catal. Commun. 108, 82 (2018)Google Scholar
  11. 11.
    S. Deng, T. Meng, B. Xu, F. Gao, Y. Ding, L. Yu, Y. Fan, ACS Catal. 6(9), 5807 (2016)Google Scholar
  12. 12.
    T.-J. Huang, Y.-P. Zhang, K. Zhuang, B. Lu, Y.-W. Zhu, K. Shen, J. Fuel Chem. Technol. 46(3), 319 (2018)Google Scholar
  13. 13.
    J. Zuo, Z. Chen, F. Wang, Y. Yu, L. Wang, X. Li, Ind. Eng. Chem. Res. 53(7), 2647 (2014)Google Scholar
  14. 14.
    S. Zou, Y. Liao, S. Xiong, N. Huang, Y. Geng, S. Yang, Environ. Sci. Technol. 51(6), 3426 (2017)Google Scholar
  15. 15.
    X. Zhou, X. Huang, A. Xie, S. Luo, C. Yao, X. Li, S. Zuo, Chem. Eng. J. 326, 1074 (2017)Google Scholar
  16. 16.
    M. Zhang, C. Li, L. Qu, M. Fu, G. Zeng, C. Fan, J. Ma, F. Zhan, Appl. Surf. Sci. 300, 58 (2014)Google Scholar
  17. 17.
    W. Zhao, C. Li, P. Lu, Q. Wen, Y. Zhao, X. Zhang, C. Fan, S. Tao, Environ. Technol. 34(1), 81 (2013)Google Scholar
  18. 18.
    Z. Ke, Y. Feng, Z. Mingyuan, D. Jianming, W. Xugen, Z. Jinli, D. Bin, Catalysts (Switzerland) 8(3), 100 (2018)Google Scholar
  19. 19.
    X. Wang, S. Wu, W. Zou, S. Yu, K. Gui, L. Dong, Chin. J. Catal. 37(8), 1314 (2016)Google Scholar
  20. 20.
    N. Fang, J. Guo, S. Shu, H. Luo, Y. Chu, J. Li, Chem. Eng. J. 325, 114 (2017)Google Scholar
  21. 21.
    T. Wang, Z. Wan, X. Yang, X. Zhang, X. Niu, B. Sun, Fuel Process. Technol. 169, 112 (2018)Google Scholar
  22. 22.
    C. Wang, F. Yu, M. Zhu, X. Wang, J. Dan, J. Zhang, P. Cao, B. Dai, Chem. Eng. J. 346, 182 (2018)Google Scholar
  23. 23.
    J. Liu, R.-T. Guo, M.-Y. Li, P. Sun, S.-M. Liu, W.-G. Pan, S.-W. Liu, X. Sun, Fuel 223, 385 (2018)Google Scholar
  24. 24.
    L.J. France, Q. Yang, W. Li, Z. Chen, J. Guang, D. Guo, L. Wang, X. Li, Appl. Catal. B: Environ. 206, 203 (2017)Google Scholar
  25. 25.
    P.N. Panahi, G. Delahay, S.M. Mousavi, Turk. J. Chem. 41(2), 272 (2017)Google Scholar
  26. 26.
    W. Zhao, Y. Tang, Y. Wan, L. Li, S. Yao, X. Li, J. Gu, Y. Li, J. Shi, J. Hazard. Mater. 278, 350 (2014)Google Scholar
  27. 27.
    H. Zhou, M.Y. Ge, S.G. Wu, B.C. Ye, Y.X. Su, Fuel 220, 330 (2018)Google Scholar
  28. 28.
    H. Xu, S. Liu, Y. Wang, Q. Lin, C. Lin, L. Lan, Q. Wang, Y. Chen, Appl. Surf. Sci. 427, 656 (2018)Google Scholar
  29. 29.
    R. Jin, Y. Liu, Z. Wu, H. Wang, T. Gu, Chemosphere 78(9), 1160 (2010)Google Scholar
  30. 30.
    Y. Li, Y. Li, P. Wang, W. Hu, S. Zhang, Q. Shi, S. Zhan, Chem. Eng. J. 330, 213 (2017)Google Scholar
  31. 31.
    P.S. Metkar, V. Balakotaiah, M.P. Harold, Catal. Today 184(1), 115 (2012)Google Scholar
  32. 32.
    M.C. Álvarez-Galván, B. Pawelec, V.A. de la Peña O’Shea, J.L.G. Fierro, P.L. Arias, App. Catal. B: Environ. 51(2), 83 (2004)Google Scholar
  33. 33.
    W. Wang, W. Li, R. Guo, Q. Chen, Q. Wang, W. Pan, G. Hu, J. Rare Earths 34(9), 876 (2016)Google Scholar
  34. 34.
    F. Cao, S. Su, J. Xiang, P. Wang, S. Hu, L. Sun, A. Zhang, Fuel 139, 232 (2015)Google Scholar
  35. 35.
    R.M. Heck, Catal. Today 53(4), 519 (1999)Google Scholar
  36. 36.
    C. Wang, F. Yu, M. Zhu, C. Tang, L. Dong, B. Dai, ACS Omega 3(5), 5692 (2018)Google Scholar
  37. 37.
    F. Kapteijn, L. Singoredjo, A. Andreini, J.A. Moulijn, Appl. Catal. B: Environ. 3(2), 173 (1994)Google Scholar
  38. 38.
    G. Qi, R.T. Yang, R. Chang, Catal. Lett. 87(1), 67 (2003)Google Scholar
  39. 39.
    M. Schwidder, S. Heikens, A. De Toni, S. Geisler, M. Berndt, A. Brückner, W. Grünert, J. Catal. 259(1), 96 (2008)Google Scholar
  40. 40.
    L. Ma, C.Y. Seo, M. Nahata, X. Chen, J. Li, J.W. Schwank, Appl. Catal. B: Environ. 232, 246 (2018)Google Scholar
  41. 41.
    T. Boningari, D.K. Pappas, P.R. Ettireddy, A. Kotrba, P.G. Smirniotis, Ind. Eng. Chem. Res. 54(8), 2261 (2015)Google Scholar
  42. 42.
    M. Stanciulescu, G. Caravaggio, A. Dobri, J. Moir, R. Burich, J.P. Charland, P. Bulsink, Appl. Catal. B: Environ. 123–124, 229 (2012)Google Scholar
  43. 43.
    Z. Chen, F. Wang, H. Li, Q. Yang, L. Wang, X. Li, Ind. Eng. Chem. Res. 51(1), 202 (2012)Google Scholar
  44. 44.
    S. Ramana, B.G. Rao, P. Venkataswamy, A. Rangaswamy, B.M. Reddy, J. Mol. Catal. A: Chem. 415, 113 (2016)Google Scholar
  45. 45.
    M.P. Ruggeri, A. Grossale, I. Nova, E. Tronconi, H. Jirglova, Z. Sobalik, Catal. Today 184(1), 107 (2012)Google Scholar
  46. 46.
    X. Yao, R. Zhao, L. Chen, J. Du, C. Tao, F. Yang, L. Dong, Appl. Catal. B: Environ. 208, 82 (2017)Google Scholar
  47. 47.
    S. Yang, Y. Liao, S. Xiong, F. Qi, H. Dang, X. Xiao, J. Li, J. Phys. Chem. C 118(37), 21500 (2014)Google Scholar
  48. 48.
    S. Yang, F. Qi, S. Xiong, H. Dang, Y. Liao, P.K. Wong, J. Li, Appl. Catal. B: Environ. 181, 570 (2016)Google Scholar

Copyright information

© Springer Nature B.V. 2018

Authors and Affiliations

  1. 1.Department of Thermal EngineeringShandong Jianzhu UniversityJinanChina
  2. 2.Key Laboratory of Renewable Energy Building Application Technology of the Education MinistryShandong Jianzhu UniversityJinanChina
  3. 3.Engineering Laboratory of Power Plant Thermal System Energy Saving of Shandong ProvinceShandong UniversityJinanChina

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