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Research on Chemical Intermediates

, Volume 45, Issue 2, pp 379–400 | Cite as

Catalytic performance of ZnFe2O4 nanoparticles prepared from the [ZnFe2O(CH3COO)6(H2O)3]·2H2O complex under microwave irradiation

  • Mahdieh Ghobadifard
  • Saeed FarhadiEmail author
  • Sajjad MohebbiEmail author
Article
  • 36 Downloads

Abstract

Using the heterometallic oxo-centered trinuclear [ZnFe2O(CH3COO)6(H2O)3]·2H2O complex as a novel precursor, pure and single-phase ZnFe2O4 nanostructure was prepared under microwave irradiation [abbreviated as ZnFe2O4 (MW)] within a very short time of 10 min. Also, ZnFe2O4 nanostructure [abbreviated as ZnFe2O4 (CT)] was produced by the conventional thermal method of this precursor. The characteristics of ZnFe2O4 nanostructures were compared by XRD, SEM, EDS, FT-IR, VSM, DRS and UV–Vis spectroscopy. Both samples revealed a cubic spinel structure with nanosheet morphology and average particle sizes of 40 and 47 nm, respectively. The ZnFe2O4 (MW) nanostructure were used as a novel sonocatalyst for the degradation of methylene blue and rhodamine B with conversions of 95% and 91%, which is up to 40% more than ZnFe2O4 (CT) activity. The higher sonocatalytic activity of ZnFe2O4 (MW) is relevant to its higher porosity and smaller particle size. The trapping experiment results confirmed that the ultrasound assisted catalytic degradation proceeds mainly through ·OH radicals. Further, the ZnFe2O4 sonocatalyst was easily separated by a magnet and reused without significant loss of activity.

Keywords

ZnFe2O4 nanoparticles Oxo-centered trinuclear complex Microwave irradiation Sonocatalytic degradation Organic pollutants 

Notes

Acknowledgements

We are gratefully acknowledging the Lorestan University and the University of Kurdistan for financial support of this research.

Supplementary material

11164_2018_3607_MOESM1_ESM.docx (109 kb)
Supplementary material 1 (DOCX 108 kb)

References

  1. 1.
    N. Wang, H. Xu, L. Chen, X. Gu, J. Yang, Y. Qian, J. Power Sources 247, 163 (2014)CrossRefGoogle Scholar
  2. 2.
    J. Li, A. Wang, Y. Lin, X. Liu, J. Fu, L. Lin, Mater. J. Magn. Magn. 330, 96 (2013)CrossRefGoogle Scholar
  3. 3.
    F. Liu, X. Li, Q. Zhao, Y. Hou, X. Quan, G. Chen, Acta Mater. 57, 2684 (2009)CrossRefGoogle Scholar
  4. 4.
    Z. Li, X. Lai, H. Wang, D. Mao, C. Xing, D. Wang, J. Phys. Chem. C 113, 2792 (2009)CrossRefGoogle Scholar
  5. 5.
    A. Sutka, J. Zavickis, G. Mezinskisa, D. Jakovlevs, J. Barloti, Sens. Actuators B 176, 330 (2013)CrossRefGoogle Scholar
  6. 6.
    S. Sun, H. Zheng, D.B. Robinson, S. Raoux, P.M. Rice, S.X. Wang, G. Li, J. Am. Chem. Soc. 126, 273 (2004)CrossRefGoogle Scholar
  7. 7.
    M. Ghobadifard, S. Mohebbi, New J. Chem. 42, 9530 (2018)CrossRefGoogle Scholar
  8. 8.
    J.F. Hochepied, P. Bonville, M.P. Pileni, J. Phys. Chem. B 104, 905 (2000)CrossRefGoogle Scholar
  9. 9.
    S.-H. Yu, M. Yoshimura, Chem. Mater. 12, 3805 (2000)CrossRefGoogle Scholar
  10. 10.
    M. Pileni, Adv. Funct. Mater. 11, 323 (2001)CrossRefGoogle Scholar
  11. 11.
    X. Xu, L. Zhou, Q. Zhai, C. Lu, J. Am. Ceram. Soc. 90, 1959 (2007)CrossRefGoogle Scholar
  12. 12.
    Y.-J. Zhu, F. Chen, Chem. Rev. 114, 6462 (2014)CrossRefGoogle Scholar
  13. 13.
    H.J. Kitchen, S.R. Vallance, J.L. Kennedy, N. Tapia-Ruiz, L. Carassiti, A. Harrison, A.G. Whittaker, T.D. Drysdale, S.W. Kingman, D.H. Gregory, Chem. Rev. 114, 1170 (2013)CrossRefGoogle Scholar
  14. 14.
    V.K. Gupta, T.A. Saleh, D. Pathania, B.S. Rathore, G. Sharma, Ionics 21, 1787 (2015)CrossRefGoogle Scholar
  15. 15.
    A. Liu, W. Zhou, K. Shen, J. Liua, X. Zhang, RSC Adv. 5, 17336 (2015)CrossRefGoogle Scholar
  16. 16.
    J. Zhang, M.A. Gondal, W. Wei, T. Zhang, Q. Xu, K. Shen, J. Alloys Compd. 530, 107 (2012)CrossRefGoogle Scholar
  17. 17.
    G. Sharma, V. Kumar, S. Agarwal, A. Kumar, S. Thakur, D. Pathania, J. Mol. Liq. 219, 1137 (2016)CrossRefGoogle Scholar
  18. 18.
    P. Dhiman, M. Naushad, K.M. Batoo, A. Kumar, G. Sharma, A.A. Ghfar, G. Kumar, M. Singh, J. Clean. Prod. 165, 1542 (2017)CrossRefGoogle Scholar
  19. 19.
    A. Mittal, A. Malviya, D. Kaur, J. Mittal, L. Kurup, J. Hazard. Mater. 148, 229 (2007)CrossRefGoogle Scholar
  20. 20.
    S. Chen, J. Zhang, C. Zhang, Q. Yue, Y. Li, C. Li, Desalination 252, 149 (2010)CrossRefGoogle Scholar
  21. 21.
    R. Darvishi CheshmehSoltan, A.R. Khataee, M. Safari, S.W. Joo, Int. Biodeterior. Biodegrad 85, 383 (2013)CrossRefGoogle Scholar
  22. 22.
    R. Darvishi Cheshmeh Soltani, A. Rezaee, A. Khataee, Ind. Eng. Chem. Res. 52, 14133 (2013)CrossRefGoogle Scholar
  23. 23.
    R. Darvishi Cheshmeh Soltani, A. Rezaee, A.R. Khataee, M. Safari, J. Ind. Eng. Chem. 20, 1861 (2014)CrossRefGoogle Scholar
  24. 24.
    A.R. Khataee, S. Fathinia, M. Fathinia, Y. Hanifehpour, S.W. Joo, B. Soltani, Curr. Nanosci. 9, 780 (2013)CrossRefGoogle Scholar
  25. 25.
    M. Zhu, D. Meng, C. Wang, J. Di, G. Diao, Chin. J. Catal. 34, 2125 (2013)CrossRefGoogle Scholar
  26. 26.
    J. Yan, K. Wang, H. Xu, J. Qian, W. Liu, X. Yang, H. Li, Chin. J. Catal. 34, 1876 (2013)CrossRefGoogle Scholar
  27. 27.
    M.R. Hoffmann, S.T. Martin, W. Choi, D.W. Bahnemann, Chem. Rev. 95, 69 (1995)CrossRefGoogle Scholar
  28. 28.
    K. Nakata, A. Fujishima, J. Photochem. Photobiol. C Photochem. Rev. 13, 169 (2012)CrossRefGoogle Scholar
  29. 29.
    A. Khataee, A. Karimi, S. Arefi-Oskoui, R. Darvishi Cheshmeh Soltani, Y. Hanifehpour, B. Soltani, S.W. Joo, Ultrason. Sonochem. 22, 371 (2015)CrossRefGoogle Scholar
  30. 30.
    M. Ahmad, E. Ahmed, Z.L. Hong, W. Ahmed, A. Elhissi, N.R. Khalid, Ultrason. Sonochem. 21, 761 (2014)CrossRefGoogle Scholar
  31. 31.
    L. Zhu, J. Chung, W.-C. Oh, Ultrason. Sonochem. 27, 252 (2015)CrossRefGoogle Scholar
  32. 32.
    Y. Wang, L. Gai, W. Ma, H. Jiang, X. Peng, L. Zhao, Ind. Eng. Chem. Res. 54, 2279 (2015)CrossRefGoogle Scholar
  33. 33.
    L. Zhu, S.-B. Jo, S. Ye, K. Ullah, W.-C. Oh, Chin. J. Catal. 35, 1825 (2014)CrossRefGoogle Scholar
  34. 34.
    L. Zhu, T. Ghosh, C.-Y. Park, Z.-D. Meng, W.-C. Oh, Chin. J. Catal. 33, 1276 (2012)CrossRefGoogle Scholar
  35. 35.
    R. Weinland, H. Holtmeier, Z. Für Anorg. Und Allg. Chem 173(1), 49 (1928)CrossRefGoogle Scholar
  36. 36.
    G. Sharma, S. Bhogal, M. Naushad, A. Kumar, F.J. Stadler, J. Photochem. Photobiol. A Chem. 347, 235 (2017)CrossRefGoogle Scholar
  37. 37.
    G. Sharma, V.K. Gupta, S. Agarwal, S. Bhogal, M. Naushad, A. Kumar, F.J. Stadler, J. Mol. Liq. 260, 342 (2018)CrossRefGoogle Scholar
  38. 38.
    G. Sharma, A. Kumar, K. Devi, S. Sharma, M. Naushad, A.A. Ghfar, T. Ahamad, F.J. Stadler, Int. J. Biol. Macromol. 114, 295 (2018)CrossRefGoogle Scholar
  39. 39.
    M. Ghobadifard, S. Farhadi, S. Mohebbi, Polyhedron 155, 66 (2018)CrossRefGoogle Scholar
  40. 40.
    S. Farhadi, F. Siadatnasab, Desalin. Water Treat. 66, 299 (2017)CrossRefGoogle Scholar
  41. 41.
    G. Gliemann, K. Nakamoto, Ber. Der Bunsenges. Für Phys. Chem. 82, 1263 (1978)CrossRefGoogle Scholar
  42. 42.
    M.K. Johnson, D.B. Powell, R.D. Cannon, Spectrochim. Acta Part A Mol. Spectrosc. 37, 995 (1981)CrossRefGoogle Scholar
  43. 43.
    C. Fernandes, E. Stadler, V. Drago, C. Jorge da Cunha, I. Hiroko Kuwabara, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 52, 1815 (1996)CrossRefGoogle Scholar
  44. 44.
    M. Mouallem-Bahout, S. Bertrand, O. Peña, J. Solid State Chem. 178, 1080 (2005)CrossRefGoogle Scholar
  45. 45.
    S. Maensiri, C. Masingboon, B. Boonchom, S. Seraphin, Scr. Mater. 56, 797 (2007)CrossRefGoogle Scholar
  46. 46.
    M. Florea, M. Alifanti, V.I. Parvulescu, D. Mihaila-Tarabasanu, L. Diamandescu, M. Feder, C. Negrila, L. Frunza, Catal. Today 141, 361 (2009)CrossRefGoogle Scholar
  47. 47.
    M. Jalaly, M.H. Enayati, F. Karimzadeh, P. Kameli, Powder Technol. 193, 150 (2009)CrossRefGoogle Scholar
  48. 48.
    P. Duran, J. Tartaj, F. Rubio, C. Moure, O. Pena, Ceram. Int. 31, 599 (2005)CrossRefGoogle Scholar
  49. 49.
    N.C.S. Selvam, R.T. Kumar, L.J. Kennedy, J.J. Vijaya, J. Alloys Compd. 509, 9809 (2011)CrossRefGoogle Scholar
  50. 50.
    Z.-D. Meng, W.-C. Oh, Ultrason. Sonochem. 18, 757 (2011)CrossRefGoogle Scholar
  51. 51.
    E. Safaei, S. Mohebbi, J. Mater. Chem. A 4, 3933 (2016)CrossRefGoogle Scholar
  52. 52.
    J.B. Silva, W. De Brito, N.D.S. Mohallem, Mater. Sci. Eng. B 112, 182 (2004)CrossRefGoogle Scholar
  53. 53.
    T. Harifi, M. Montazer, Sep. Purif. Technol. 134, 210 (2014)CrossRefGoogle Scholar
  54. 54.
    M.V. Bagal, P.R. Gogate, Sep. Purif. Technol. 90, 92 (2012)CrossRefGoogle Scholar
  55. 55.
    J. Yang, J. Yu, J. Fan, D. Sun, W. Tang, X. Yang, J. Hazard. Mater. 189, 377 (2011)CrossRefGoogle Scholar
  56. 56.
    N. Wang, L. Zhu, M. Wang, D. Wang, H. Tang, Ultrason. Sonochem. 17, 78 (2010)CrossRefGoogle Scholar
  57. 57.
    L. Ai, C. Zhang, L. Li, J. Jiang, Appl. Catal. B Environ. 148–149, 191 (2014)CrossRefGoogle Scholar
  58. 58.
    R. Liang, S. Luo, F. Jing, L. Shen, N. Qin, L. Wu, Appl. Catal. B Environ. 176–177, 240 (2015)CrossRefGoogle Scholar
  59. 59.
    N. Ertugay, F. NuranAcar, Appl. Surf. Sci. 318, 121 (2014)CrossRefGoogle Scholar
  60. 60.
    S. Thangavel, N. Raghavan, G. Kadarkarai, S.-J. Kim, G. Venugopal, Ultrason. Sonochem. 24, 123 (2015)CrossRefGoogle Scholar
  61. 61.
    N. Zhang, G. Xian, X. Li, P. Zhang, G. Zhang, Front. Chem. 6, 12 (2018)CrossRefGoogle Scholar
  62. 62.
    H.L. Zhu, X.Y. Gu, D.T. Zuo, Z.K. Wang, N.Y. Wang, K.H. Yao, Nanotechnology 19, 405503 (2008)CrossRefGoogle Scholar
  63. 63.
    J.L. López, H. PFannes, R. Paniagob, J. Sinnecker, M. Novak, J. Magn. Magn. Mater. 320(14), 327 (2008)CrossRefGoogle Scholar
  64. 64.
    S. Kurinobua, K. Tsurusakib, Y. Natuic, M. Kimatac, M. Hasegawa, J. Magn. Magn. Mater. 310, 1025 (2007)CrossRefGoogle Scholar
  65. 65.
    P. Qiu, W. Li, K. Kang, B. Park, W. Luo, D. Zhao, J. Khim, J. Mater. Chem. A 2, 16452 (2014)CrossRefGoogle Scholar
  66. 66.
    P. Qiu, W. Li, B. Thokchom, B. Park, M. Cui, D. Zhao, J. Khim, J. Mater. Chem. A 3, 6492 (2015)CrossRefGoogle Scholar
  67. 67.
    A.H. Alwash, A.Z. Abdullah, N. Ismail, Mod. Res. Catal. 2, 100 (2013)CrossRefGoogle Scholar
  68. 68.
    Y. Segura, R. Molina, F. Martinez, J. Melero, Ultrason. Sonochem. 16, 417 (2009)CrossRefGoogle Scholar
  69. 69.
    M. Entezari, Z.S. Al-Hoseini, Ultrason. Sonochem. 14, 599 (2007)CrossRefGoogle Scholar
  70. 70.
    J. Saien, H. Delavari, A. Solymani, J. Hazard. Mater. 177, 1031 (2010)CrossRefGoogle Scholar
  71. 71.
    F.-J. Zhang, J. Liu, M.-L. Chen, W.-C. Oh, J. Korean Ceram. Soc. 46, 263 (2009)CrossRefGoogle Scholar
  72. 72.
    X. Zhang, M. Zhou, L. Lei, Carbon N. Y. 43, 1700 (2005)CrossRefGoogle Scholar
  73. 73.
    F.-J. Zhang, M.-L. Chen, K. Zhang, W.-C. Oh, Bull. Korean Chem. Soc. 31, 133 (2010)CrossRefGoogle Scholar
  74. 74.
    F. Soumia, C. Petrier, Ultrason. Sonochem. 32, 343 (2016)CrossRefGoogle Scholar
  75. 75.
    K. Zhang, F.J. Zhang, M.L. Chen, W.C. Oh, Ultrason. Sonochem. 18, 765 (2011)CrossRefGoogle Scholar
  76. 76.
    A.N.S. Evelyn, C. Luciana De Simone, B.C. Tiago Moreira, W.F. Flaviano, M. João Paulo Barros, T. Gilmar Patrocínio, Fuller. Nanotub. Carbon Nanostruct. 23, 725 (2015)CrossRefGoogle Scholar
  77. 77.
    S. Farhadi, F. Siadatnasab, A. Khataee, Ultrason. Sonochem. 37, 298 (2017)CrossRefGoogle Scholar
  78. 78.
    R. Darvishi Cheshmeh Soltani, S. Jorfi, H. Ramezani, S. Purfadakari, Ultrason. Sonochem. 28, 69 (2016)CrossRefGoogle Scholar
  79. 79.
    S. Sajjadi, A. Khataee, M. Kamali, Ultrason. Sonochem. 39, 676 (2017)CrossRefGoogle Scholar
  80. 80.
    J. Tavana, M. Edrisi, Mater. Res. Express 3, 035009 (2016)CrossRefGoogle Scholar
  81. 81.
    A. Kumar, A. Kumar, G. Sharma, A.H. Al-muhtaseb, M. Naushad, A.A. Ghfar, F.J. Stadler, Chem. Eng. J. 334, 462 (2018)CrossRefGoogle Scholar
  82. 82.
    M. Naushad, G. Sharma, A. Kumar, S. Sharma, A.A. Ghfar, A. Bhatnagar, F.J. Stadler, M.R. Khan, Int. J. Biol. Macromol. 106, 1 (2018)CrossRefGoogle Scholar
  83. 83.
    G. Sharma, B. Thakur, M. Naushad, A.H. Al-muhtaseb, A. Kumar, M. Sillanpaa, G.T. Mola, Mater. Chem. Phys. 193, 129 (2017)CrossRefGoogle Scholar

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© Springer Nature B.V. 2018

Authors and Affiliations

  1. 1.Department of ChemistryLorestan UniversityKhorramabadIran
  2. 2.Department of ChemistryUniversity of KurdistanSanandajIran

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