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Research on Chemical Intermediates

, Volume 45, Issue 2, pp 199–222 | Cite as

Fe3O4-supported N-pyridin-4-amine-grafted graphene oxide as efficient and magnetically separable novel nanocatalyst for green synthesis of 4H-chromenes and dihydropyrano[2,3-c]pyrazole derivatives in water

  • Davood AzarifarEmail author
  • Masoud Khaleghi-Abbasabadi
Article
  • 48 Downloads

Abstract

Fe3O4-magnetized N-pyridin-4-amine-functionalized graphene oxide [Fe3O4@GO-N-(pyridin-4-amine)] was readily prepared via a three-step procedure. The synthesized nanofilms were characterized by scanning electron microscopy, powder X-ray diffraction analysis, Fourier-transform infrared spectroscopy, energy-dispersive X-ray spectroscopy, vibrating-sample magnetometry, and elemental analysis. The prepared magnetic amine-functionalized graphene oxide exhibited high catalytic activity for one-pot three-component synthesis of dihydropyrano[2,3-c]pyrazole and tetrahydrobenzo[b]pyran (4H-chromene) derivatives. Excellent product yield, short reaction time, use of water as green solvent, and easy workup procedure are the main advantages of the present protocol. In addition, the catalyst could be easily separated by magnetic decantation and reused for six cycles without significant loss of catalytic activity.

Graphical abstract

Keywords

Magnetite-supported N-pyridin-4-amine-grafted Graphene oxide Magnetic nanocatalyst Dihydropyrano[2,3-c]pyrazoles Tetrahydrobenzo[b]pyrans 

Notes

Acknowledgements

The authors wish to thank the Research Council of Bu-Ali Sina University for financial support to carry out this research. Also, Islamic Azad University, North Tehran Branch, is sincerely appreciated for technical support.

Supplementary material

11164_2018_3597_MOESM1_ESM.docx (5.3 mb)
Supplementary material 1 (DOCX 5428 kb)

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© Springer Nature B.V. 2018

Authors and Affiliations

  1. 1.Department of ChemistryBu-Ali Sina UniversityHamedanIran

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