Advertisement

Research on Chemical Intermediates

, Volume 44, Issue 10, pp 5833–5855 | Cite as

MPEC-IMI as an effective green inhibitor to protect Q235 steel in 0.5 M HCl medium

  • Li Song
  • Yuming Zhou
  • Xiaoli Sheng
  • Qingzhao Yao
  • Xiaoyong Xi
Article

Abstract

Imidazole (IMI)-based polyethylene glycol monomethyl ether (MPEC-IMI) as a novel green corrosion inhibitor was synthesized to protect the Q235 steel in 0.5 M HCl corrosive medium at 318 K. The inhibition performance of MPEC-IMI was investigated by weight loss measurement, the electrochemical method (Tafel and EIS) and surface analysis (SEM and EDX). The results reveal that the MPEC-IMI shows enhanced anticorrosion performance for carbon steel, which is attributed to the formation of the adsorptive protection film on the surface, and the type of adsorption basically obeys the Langmuir monolayer adsorption. Furthermore, when the concentration of MPEC-IMI is 300 mg L−1, the corrosion inhibition efficiency can reach up to 92.00%. In support of further study of the corrosion inhibition behavior by virtue of quantum chemical calculation and molecular dynamics simulations, the results show that the MPEC-IMI molecule has high reactivity and strong interaction on the iron surface.

Keywords

Green corrosion inhibitor Acid corrosion medium Polyethylene glycol monomethyl ether Quantum chemical calculations Molecular dynamics simulations 

Notes

Acknowledgements

This work was supported by the National Nature Science Foundation of China (51673040), the Prospective Joint Research Project of Jiangsu Province (BY2016076-01), the Scientific Innovation Research Foundation of College Graduate in Jiangsu Province (KYLX16_0266), and by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD; 1107047002). This work was also supported by the Fundamental Research Funds for the Central Universities (2242015k30001), the Fund Project for Transformation of Scientific and Technological Achievements of Jiangsu Province of China (BA2016105), based on scientific research of SRTP of Southeast University (T16192020), and the Scientific Research Foundation of the Graduate School of Southeast University (YBJJ1417).

Supplementary material

11164_2018_3459_MOESM1_ESM.docx (1.5 mb)
Supplementary material 1 (DOCX 1496 kb)

References

  1. 1.
    B.D. Mert, A.O. Yüce, G. Kardaş, B. Yazıcı, Corros. Sci. 85, 287 (2014)CrossRefGoogle Scholar
  2. 2.
    K. Zhang, B. Xu, W. Yang, X. Yin, Y. Liu, Y. Chen, Corros. Sci. 90, 284 (2015)CrossRefGoogle Scholar
  3. 3.
    M.A. Hegazy, A.Y. El-Etre, M. El-Shafaie, K.M. Berry, J. Mol. Liq. 214, 347 (2016)CrossRefGoogle Scholar
  4. 4.
    Ş. Erdoğan, Z.S. Safi, S. Kaya, D.Ö. Işın, L. Guo, C. Kaya, J. Mol. Struct. 1134, 751 (2017)CrossRefGoogle Scholar
  5. 5.
    L.L. Liao, S. Mo, J.L. Lei, H.Q. Luo, N.B. Li, J. Colloid Interface Sci. 474, 68 (2016)CrossRefPubMedGoogle Scholar
  6. 6.
    Q. Yang, H. Choi, Y. Chen, D.D. Dionysiou, Appl. Catal. B 77, 300 (2008)CrossRefGoogle Scholar
  7. 7.
    T.A.R.G. Bhargava, I. Gouzman, E. Abelev, S.L. Bernasek, Corros. Sci. Sect. 65, 308 (2009)CrossRefGoogle Scholar
  8. 8.
    C.L. Ksenija Babic, A.R. Barron, N. Hackerman, A.R. Barron, A. Luttge, Langmuir 21, 12187 (2005)CrossRefGoogle Scholar
  9. 9.
    N. Muhammad, Y.A. Elsheikh, M.I.A. Mutalib, A.A. Bazmi, R.A. Khan, H. Khan, S. Rafiq, Z. Man, I. Khan, J. Ind. Eng. Chem. 21, 1 (2015)CrossRefGoogle Scholar
  10. 10.
    G. Broussard, O. Bramanti, F.M. Marchese, Occup. Med. 47, 337 (1997)CrossRefGoogle Scholar
  11. 11.
    G. Gece, Corros. Sci. 53, 3873 (2011)CrossRefGoogle Scholar
  12. 12.
    M.A. Chidiebere, E.E. Oguzie, L. Liu, Y. Li, F. Wang, J. Ind. Eng. Chem. 26, 182 (2015)CrossRefGoogle Scholar
  13. 13.
    N.K. Gupta, C. Verma, M.A. Quraishi, A.K. Mukherjee, J. Mol. Liq. 215, 47 (2016)CrossRefGoogle Scholar
  14. 14.
    Y. Liu, C. Zou, X. Yan, R. Xiao, T. Wang, M. Li, Ind. Eng. Chem. Res. 54, 5664 (2015)CrossRefGoogle Scholar
  15. 15.
    C. Verma, L.O. Olasunkanmi, E.E. Ebenso, M.A. Quraishi, I.B. Obot, J. Phys. Chem. C 120, 11598 (2016)CrossRefGoogle Scholar
  16. 16.
    Y. He, Y. Zhou, R. Yang, L. Ma, Z. Chen, Russ. J. Appl. Chem. 88, 1192 (2015)CrossRefGoogle Scholar
  17. 17.
    C.L. Ksenija Babic, I. Samardz, N. Hackerman, A.R. Barron, A. Luttge, Langmuir 21, 12187 (2005)CrossRefGoogle Scholar
  18. 18.
    M.N. El-Haddad, A.S. Fouda, J. Mol. Liq. 209, 480 (2015)CrossRefGoogle Scholar
  19. 19.
    P.M. Nouri, M.M. Attar, Chem. Eng. Commun. 203, 505 (2015)CrossRefGoogle Scholar
  20. 20.
    G.K. Gomma, M.H. Wahdan, Mater. Chem. Phys. 47, 176 (1997)CrossRefGoogle Scholar
  21. 21.
    E.S.A. Popova, S. Raicheva, M. Christov, Corros. Sci. 45, 33 (2003)CrossRefGoogle Scholar
  22. 22.
    S. Salimi, M. Nasr-Esfahani, S.A. Umoren, E. Saebnoori, J. Mater. Eng. Perform. 24, 4696 (2015)CrossRefGoogle Scholar
  23. 23.
    H.M. Abd El-Lateef, M.A. Abo-Riya, A.H. Tantawy, Corros. Sci. 108, 94 (2016)CrossRefGoogle Scholar
  24. 24.
    K. Hu, J. Zhuang, C. Zheng, Z. Ma, L. Yan, H. Gu, X. Zeng, J. Ding, J. Mol. Liq. 222, 109 (2016)CrossRefGoogle Scholar
  25. 25.
    I.B. Obot, N.A. Wazzan, S. Kaya, J. Mol. Liq. 221, 579 (2016)CrossRefGoogle Scholar
  26. 26.
    S. Kaya, L. Guo, C. Kaya, B. Tüzün, I.B. Obot, R. Touir, N. Islam, J. Taiwan Inst. Chem. Eng. 65, 522 (2016)CrossRefGoogle Scholar
  27. 27.
    L. Guo, S.T. Zhang, T.M. Lv, W.J. Feng, Res. Chem. Intermed. 41, 3729 (2013)CrossRefGoogle Scholar
  28. 28.
    J. Zeng, W. Shi, G. Sun, S. Chen, J. Mol. Liq. 223, 150 (2016)CrossRefGoogle Scholar
  29. 29.
    M.A. Amin, S.S. Abd El-Rehim, E.E.F. El-Sherbini, R.S. Bayoumi, Electrochim. Acta 52, 3588 (2007)CrossRefGoogle Scholar
  30. 30.
    J.-J. Fu, S.-N. Li, L.-H. Cao, Y. Wang, L.-H. Yan, L.-D. Lu, J. Mater. Sci. 45, 979 (2009)CrossRefGoogle Scholar
  31. 31.
    N. Chafai, S. Chafaa, K. Benbouguerra, D. Daoud, A. Hellal, M. Mehri, J. Taiwan Inst. Chem. Eng. 70, 331 (2017)CrossRefGoogle Scholar
  32. 32.
    R. Yıldız, Corros. Sci. 90, 544 (2015)CrossRefGoogle Scholar
  33. 33.
    S. Hari Kumar, S. Karthikeyan, Ind. Eng. Chem. Res. 52, 7457 (2013)CrossRefGoogle Scholar
  34. 34.
    D.K. Yadav, M.A. Quraishi, Ind. Eng. Chem. Res. 51, 8194 (2012)CrossRefGoogle Scholar
  35. 35.
    X. Zheng, S. Zhang, M. Gong, W. Li, Ind. Eng. Chem. Res. 53, 16349 (2014)CrossRefGoogle Scholar
  36. 36.
    J. Fu, H. Zang, Y. Wang, S. Li, T. Chen, X. Liu, Ind. Eng. Chem. Res. 51, 6377 (2012)CrossRefGoogle Scholar
  37. 37.
    M. Chellouli, D. Chebabe, A. Dermaj, H. Erramli, N. Bettach, N. Hajjaji, M.P. Casaletto, C. Cirrincione, A. Privitera, A. Srhiri, Electrochim. Acta 204, 50 (2016)CrossRefGoogle Scholar
  38. 38.
    D.K. Yadav, M.A. Quraishi, B. Maiti, Corros. Sci. 55, 254 (2012) CrossRefGoogle Scholar
  39. 39.
    D.B. Hmamou, R. Salghi, A. Zarrouk, M.R. Aouad, O. Benali, H. Zarrok, M. Messali, B. Hammouti, M.M. Kabanda, M. Bouachrine, E.E. Ebenso, Ind. Eng. Chem. Res. 52, 14315 (2013)CrossRefGoogle Scholar
  40. 40.
    A. Rochdi, R. Touir, M.E. Bakri, M. Ebn Touhami, S. Bakkali, B. Mernari, J. Environ. Chem. Eng. 3, 233 (2015)CrossRefGoogle Scholar
  41. 41.
    S.F.L.M.M. Hosseini, M. Ghorbani, M.R. Arshadi, Mater. Chem. Phys. 78, 800 (2003)CrossRefGoogle Scholar
  42. 42.
    B. Xu, W. Yang, Y. Liu, X. Yin, W. Gong, Y. Chen, Corros. Sci. 78, 260 (2014)CrossRefGoogle Scholar
  43. 43.
    S.A. Umoren, Y. Li, F.H. Wang, Corros. Sci. 52, 1777 (2010)CrossRefGoogle Scholar
  44. 44.
    T.M. Lv, S.H. Zhu, L. Guo, S.T. Zhang, Res. Chem. Intermed. 41, 7073 (2014)CrossRefGoogle Scholar
  45. 45.
    S. John, A. Joseph, Res. Chem. Intermed. 38, 1359 (2011)CrossRefGoogle Scholar
  46. 46.
    E. Kowsari, M. Payami, R. Amini, B. Ramezanzadeh, M. Javanbakht, Appl. Surf. Sci. 289, 478 (2014)CrossRefGoogle Scholar
  47. 47.
    F.S. de Souza, A. Spinelli, Corros. Sci. 51, 642 (2009)CrossRefGoogle Scholar
  48. 48.
    D.M.D.L.M. Vracar, Corros. Sci. 44(8), 1669 (2002)CrossRefGoogle Scholar
  49. 49.
    M. Prabakaran, S.-H. Kim, N. Mugila, V. Hemapriya, K. Parameswari, S. Chitra, I.-M. Chung, J. Ind. Eng. Chem. 52, 235 (2017)CrossRefGoogle Scholar
  50. 50.
    S. Kaya, C. Kaya, L. Guo, F. Kandemirli, B. Tüzün, İ. Uğurlu, L.H. Madkour, M. Saraçoğlu, J. Mol. Liq. 219, 497 (2016)CrossRefGoogle Scholar
  51. 51.
    N.A. Wazzan, I.B. Obot, S. Kaya, J. Mol. Liq. 221, 579 (2016)CrossRefGoogle Scholar
  52. 52.
    N.O. Eddy, J. Adv. Res. 2, 35 (2011)CrossRefGoogle Scholar
  53. 53.
    G. Gece, S. Bilgiç, Corros. Sci. 52, 3435 (2010)CrossRefGoogle Scholar
  54. 54.
    I.B. Obot, D.D. Macdonald, Z.M. Gasem, Corros. Sci. 99, 1 (2015)CrossRefGoogle Scholar
  55. 55.
    S.K. Saha, A. Dutta, P. Ghosh, D. Sukul, P. Banerjee, Phys. Chem. Chem. Phys. 17(8), 5679 (2015)CrossRefPubMedGoogle Scholar
  56. 56.
    S. Martinez, Mater. Chem. Phys. 77, 97 (2002)CrossRefGoogle Scholar
  57. 57.
    K.F. Khaled, Corros. Sci. 52, 3225 (2010)CrossRefGoogle Scholar
  58. 58.
    M.K. Awad, M.R. Mustafa, M.M.A. Elnga, J. Mol. Struct. (Thoechem) 959, 66 (2010)CrossRefGoogle Scholar
  59. 59.
    M. Dehdab, M. Shahraki, S.M. Habibi-Khorassani, Amino Acids 48, 291 (2016)CrossRefPubMedGoogle Scholar
  60. 60.
    A. Dutta, S.K. Saha, P. Banerjee, D. Sukul, Corros. Sci. 98, 541 (2015)CrossRefGoogle Scholar
  61. 61.
    H. Lgaz, R. Salghi, S. Jodeh, B. Hammouti, J. Mol. Liq. 225, 271 (2017)CrossRefGoogle Scholar
  62. 62.
    A.M. Kumar, R.S. Babu, I.B. Obot, Z.M. Gasem, RSC Adv. 5, 19264 (2015)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of Chemistry and Chemical EngineeringSoutheast UniversityNanjingPeople’s Republic of China
  2. 2.Cheng Xian CollegeSoutheast UniversityNanjingPeople’s Republic of China
  3. 3.Jianghai Environmental Protection Co., Ltd.ChangzhouPeople’s Republic of China

Personalised recommendations