Research on Chemical Intermediates

, Volume 44, Issue 5, pp 3641–3657 | Cite as

Cobalt porphyrin supported on N and P co-doped graphene quantum dots/graphene as an efficient photocatalyst for aerobic oxidation of alcohols under visible-light irradiation

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Abstract

The research and development of the new heterogeneous photocatalysts for selective organic transformations under visible-light irradiation and environmentally friendly conditions is still considered as one of the hot topics in the fine chemical industry. Here, we report the synthesis of cobalt porphyrin-supported nitrogen and phosphorus co-doped graphene quantum dots/graphene (CoPP@N, P: GQD/G) and their impressive performance as efficient, recyclable, and noble metal free heterogeneous photocatalysts in the aerobic oxidation reaction of alcohols under visible-light irradiation. In terms of catalytic activity, these catalysts afford much higher conversion (ca. 92%) and selectivity (ca. 86%) than most reported photocatalysts under the same reaction conditions. This work notes the considerable potential of CoPP@N, P: GQD/G photocatalysts in the aerobic oxidation reaction owning to high activity and selectivity, short reaction time, reusability and easy separation under ambient and green conditions.

Graphical Abstract

Keywords

Photocatalysis Graphene quantum dots Selective aerobic oxidation Biomimetic photocatalyst 

Notes

Acknowledgements

The financial support provided by the Iran National Science Foundation (INSF) is gratefully acknowledged.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Springer Science+Business Media B.V., part of Springer Nature 2018

Authors and Affiliations

  1. 1.Malek-Ashtar University of TechnologyTehranIran
  2. 2.Department of Polymer Engineering and Color TechnologyAmirkabir University of TechnologyTehranIran

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