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Poly N,N-dimethylaniline-formaldehyde supported on silica-coated magnetic nanoparticles: a novel and retrievable catalyst for green synthesis of 2-amino-3-cyanopyridines

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Abstract

Preparation and application of novel and reusable magnetic nanoparticles with poly N,N-dimethylaniline-formaldehyde support as a heterogeneous basic catalyst have been described. The reported catalyst was characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, X-ray diffraction patterns, transmission electron microscopy, energy dispersive X-ray spectroscopy, thermogravimetric analysis and vibrating sample magnetometry. The catalytic performance of this organic-inorganic hybrid nanomaterial has been studied for the green synthesis of 2-amino-3-cyanopyridine derivatives through one-pot four-component reactions. An eco-friendly method, short reaction time, high yield and easy work-up procedure are the advantages of this new methodology over earlier ones.

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Acknowledgements

We gratefully acknowledge the financial support of this work by the research council of Arak University.

Author information

Correspondence to Mohammad Ali Bodaghifard.

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Asadbegi, S., Bodaghifard, M.A. & Mobinikhaledi, A. Poly N,N-dimethylaniline-formaldehyde supported on silica-coated magnetic nanoparticles: a novel and retrievable catalyst for green synthesis of 2-amino-3-cyanopyridines. Res Chem Intermed 46, 1629–1643 (2020). https://doi.org/10.1007/s11164-017-3200-4

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Keywords

  • 2-Amino-3-cyanopyridines
  • Magnetic nanoparticles
  • Multi-component reactions
  • Green synthesis