Research on Chemical Intermediates

, Volume 44, Issue 5, pp 2929–2950 | Cite as

Removal of methylene blue by silver nanoparticles loaded on activated carbon by an ultrasound-assisted device: optimization by experimental design methodology

Article

Abstract

Ultrasonic waves superimposed with Ag nanoparticles festooned on AC was used as a new economical and green methodological adsorbent for the efficient removal of noxious methylene blue (MB) from the solvent phase. The developed adsorbent was characterized using various analytical techniques namely SEM, XRD, and BET. The impact of influential variables such as pH, sonication time, temperature, initial dye concentration, and adsorbent dosage on MB removal and adsorption were well investigated and optimized using central composite design. Additionally, the optimized operating conditions were obtained through the desirability function superimposed with response surface methodology. It was observed that the very low amount of the adsorbent dose (0.015 g) is applicable for successful removal of MB (RE >95 %) in a very short span of time (4.0 min) with maximum adsorption capacity (75.2 mg g−1). The modeling of the adsorption process is carried out using MLR and RF models. The optimal tuning parameters for the RF model were achieved based on n tree = 100, m try = 2. For the testing data set, the MSE values of 0.0013, the correlation coefficient (R 2) values for RF and MLR model, are 0.9783 and 0.7573 respectively.

Graphical Abstract

Pictorial presentation of surface, response and absorbance behavior of MB

Keywords

Adsorption Experimental design Ag–NP–AC Methylene blue Noxious dyes 

Notes

Acknowledgments

The authors express their appreciation to the Graduate School and Research Council of the University of Yasouj for financial support of this work.

Supplementary material

11164_2015_2285_MOESM1_ESM.docx (206 kb)
Supplementary material 1 (DOCX 206 kb)

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Copyright information

© Springer Science+Business Media Dordrecht 2015

Authors and Affiliations

  1. 1.Chemistry DepartmentYasouj UniversityYasoujIran
  2. 2.Department of Chemistry, Gachsaran BranchIslamic Azad UniversityGachsaranIran
  3. 3.Department of ChemistryIndian Institute of Technology RoorkeeRoorkeeIndia
  4. 4.Department of Applied ChemistryUniversity of JohannesburgJohannesburgSouth Africa
  5. 5.Center for Environment and Water, The Research InstituteKing Fahd University of Petroleum and MineralsDhahranSaudi Arabia

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