Comparative Analysis of the Properties of ZrO2–SiO2 and ZrO2–Al2O3–SiO2 Composition Fiber Composite Materials
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Strength, morphology, and phase composition are analyzed for a ceramic composite system based on fibers of tetragonal ZrO2 and a matrix with different content of SiO2 and Al2O3. It is shown that with an Al2O3 content from 0 to 20 wt.% there is formation of a precipitation-hardened structure and an increase in material ultimate strength in bending. The reduction in strength with a further increase in Al2O3 content is due to a deficiency in SiO2 binder and inadequate Al2O3 and mullite particle sintering with each other. Features of the structure and phase composition are demonstrated for a composite based on ZrO2 fibers with a different Al2O3:SiO2 ratio in the matrix.
Keywordsceramic composite materials (CCM) discrete ZrO2 fibers SiO2 matrix sol-gel precursor
Work was carried out within the scope of implementing comprehensive scientific area 14.3 “multifunctional heatproof and heat insulation materials” (1) within the scope of project No. 13-08-12110 ofi m with the Russian fund for fundamental research.
- 1.E. N. Kablov, “Innovative development FGUP VIAM GNTs RF “Strategic areas of development of materials and technology for their development in the period up to 2030,” Aviats. Mater. Technol, No. 1(34) (2015), 3 – 33. DOI: https://doi.org/10.18577/2071-9140-2015-0-1-3-33.
- 2.E. N. Kablov, “Russian needs of new generation materials,” Redkie Zemli, No. 3, 813 (2014).Google Scholar
- 3.D. V. Grashchenkov and L. V. Chursova, “Strategy of developing composite and functional materials,” Aviats. Mater. Technol, No. S, 231 – 242 (20012).Google Scholar
- 4.E. N. Kablov, D. V. Grashchenkov, N. V. Isaeva, et al., “High-temperature structural composite materials based on glass and ceramic for prospective aviation technology objects,” Steklo Keram., No. 4, 7 – 11 (2012).Google Scholar
- 5.E. N. Kablov, D. V. Grashchenkov,, N. V. Isaeva, et al., “Prospective high-temperature composite ceramic materials,” Ross. Khim. Zh., LIV(1), 20 – 24 (2010).Google Scholar
- 6.E. N. Kablov, O. G. Ospennikova, and B. S. Lomberg, “Strategic areas for developing structural materials and their processing technology for aero engines of the present and future,” Avtomat Svarka, No. 10, 23 – 32 (2013).Google Scholar
- 7.N. M. Varrik, Yu. A. Ivakhnenko, and V. G. Maksimov, “Oxide-oxide composite materials for gas turbine engines (review),” Trudy VIAM: Elektron,. Nauch. Tekhn. Zh., No. 8, Art. 03 (2014). DOI: https://doi.org/10.18577/2307-6046-2014-0- 3-3.Google Scholar
- 8.Yu. A. Ivakhnenko, V. G. Babashov, A.M. Zimichev, and E. V. Tinyakova, “High-temperature heat insulation and heat protection materials based on refractory compound fibers,” Aviats. Mater. Technol, No. S, 380 – 386 (2012).Google Scholar
- 9.Proceeding of the 15th Annual Conference on Composites and Advanced Ceramic Materials. Part 2 of 2: Ceramic Engineering and Science Proceeding, 12(9/10) (2009).Google Scholar
- 10.Ceramics and Composite materials, Proc. VII All-Russia Sci. Conf, Syktyvkar (2010).Google Scholar
- 11.US Patent 2608525. Catalytic cracking of hydrocarbons with a silica-alumina-zirconia composite, Claim 01.11.46, Publ. 08.26.52.Google Scholar
- 12.G. Aguila, F. Gracia, and P. Araya, “CuO and CeO2 catalysts supported on Al2O3, ZrO2 and SiO2 in the oxidation of CO at low temperature,” Applied Catalysis A-General, 343, 16 – 24 (2008). URL: http://repositorio.uchile.cl/bitstream/handle/2250/125036/AguilaGonzalo.pdf?sequence=1&isAllowed=y (access date 14.09.2017). DOI: https://doi.org/10.1016/j.apcata.2008.03.015 CrossRefGoogle Scholar
- 13.W. Wang, K. Wu, P. Lui, et al., “Hydrodeoxygenation of p-cresol over Pt/Al2O3 catalyst promoted by ZrO2, CeO2 and CeO2. ZrO2,” Ind. Eng. Chem. Res., 55, 7598 – 7603 (2016) http://pubs.acs.org/doi/abs/10.1021/acs.iecr.6b00515.Google Scholar
- 15.E. D. Banus, M. A. Ulla, E. E. Miro, and V. G. Milt, “Structured catalyst for soot combustion for diesel engines. Diesel engine — combustion, emissions and condition monitoring,” InTech.. 118 – 142 (2013). URL: http://cdn.intechopen.com/pdfs/44436/InTech-structuredcatalystsforsootcombustionfordieselengines.pdf (access date 04.09.2017). DOI: https://doi.org/10.5772/54516.Google Scholar
- 16.Yu. I. Golovin, D. G. Kuznetsov, V. M. Vasyukov, et al., “Composites based on zirconium oxide and their use for immobilization of radioactive waste,” Vestn. TGU, 18(6), 3150 (2013).Google Scholar
- 18.Q. P. Wang, X. S. Tian, S. X. Liu, et al., “Phase transformation of Al2O3–SiO2–ZrO2 composite membranes,” Adv. Mater. Res., 177, 329 – 333 (2010). URL: https://www.scientific.net/AMR.177.329 (access date 08.25.2017). DOI: https://doi.org/10.4028/www.scientific.net/AMR.177.329.
- 19.C. C. Barry and N. M. Grant, Ceramic Materials. Science and Engineering, Springer (2007).Google Scholar
- 20.R. Zhang, Y. Changshou, and W. Baoling, “Novel Al2O3–SiO2 aerogel / porous zirconia composite with ultra-low thermal conductivity,” J. Porous Mater, 1 – 8 (2017).Google Scholar
- 21.R. Zhang, “Enhanced mechanical and thermal properties of anisotropic fibrous porous mullite-zirconia composites produced using sol-gel impregnation,” J. Alloys Compd., 699, 511 – 516 (2017). URL: http://www.sciencedirect.com/science/article/pii/S0925838817300099 (access date 04.09.2017). DOI: https://doi.org/10.1016/j.jallcom.2017.01.007.CrossRefGoogle Scholar
- 22.Abdul-Ghani Olabi “Characterisation of alumina-zirconia composites produced by micron-sized powders,” DCU, 115 (2005).Google Scholar
- 23.P. Bosh and J.-C. Niepsce, “Ceramic materials. Processes, properties and applications,” ISTE, 573 (2007).Google Scholar
- 24.R. E. Loehman, Characterization of Ceramics Momentum Press, N. Y. (2010).Google Scholar
- 25.S. W. Freiman and J. J. Mecholsky, The Fracture of Brittle Materials. Testing and Analysis, Wiley (2012).Google Scholar