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Reaction Kinetics, Mechanisms and Catalysis

, Volume 128, Issue 1, pp 139–147 | Cite as

Immobilizaion of Preyssler type heteropoly acids on siliceous mesporous supports and their catalytic activities in the dehydration of ethanol

  • Mahuya BandyopadhyayEmail author
  • Divya Jadav
  • Nao Tsunoji
  • Tsuneji Sano
  • Masahiro Sadakane
Article
  • 19 Downloads

Abstract

Porous materials with different pore structure were synthesized and modified with Preyssler-type heteropolyacid material by post-synthetic wet-impregnation method. The functionalized materials were thoroughly characterized by different physic-chemical techniques. As reveled by characterization, the structures were well preserved after the modification. All the materials were catalytically active as proved by the catalytic results in dehydration of alcohol to ethylene. On comparison with Preyssler (without any support), which did not show activity at all, mesoporous matrices provided active support for hosting heteropolyacids which was found to be an excellent catalyst for this reaction.

Keywords

Porous materials Polyoxometalates Ethanol Ethylene Preyssler modified mesoporous materials 

Notes

Acknowledgement

One of the authors (MS) would like to thank JSPS KAKENHI Grant Number JP18H02058 and JSPS Core-to-Core Program.

Supplementary material

11144_2019_1646_MOESM1_ESM.docx (305 kb)
Supplementary material 1 (DOCX 304 kb)

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019

Authors and Affiliations

  1. 1.Institute of Infrastructure, Technology, Research and Management, IITRAMAhmedabadIndia
  2. 2.Department of Applied Chemistry, Graduate School of EngineeringHiroshima UniversityHigashi-HirosimaJapan

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