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Reaction Kinetics, Mechanisms and Catalysis

, Volume 128, Issue 1, pp 289–314 | Cite as

Hierarchical ZSM-5 based on fly ash for the low-temperature purification of odorous volatile organic compound in cooking fumes

  • Jian Li
  • Yingjie ShiEmail author
  • Xiaoheng Fu
  • Jiayu Huang
  • Yanping Zhang
  • Shuang Deng
  • Fan Zhang
Article
  • 29 Downloads

Abstract

Hierarchical ZSM-5 (HZ) zeolites with different SiO2/Al2O3 ratios (SiO2/Al2O3 = 50, 100, 150, 200, 250 and 300) were synthesized using a two-step hydrothermal treatment method, and the Al and Si were obtained from fly ash by the alkali melting and acid leaching method. On this basis, the 10 wt% LaMnO3/HZ catalysts were prepared by impregnation. The all the synthesized catalysts were investigated for the low-temperature (200 °C) catalytic oxidation of pentanal, which was selected as a typical odorous volatile organic compound (VOC) in cooking fumes. In addition, the physicochemical properties of HZ zeolites were characterized by several techniques (XRD, N2 physical adsorption–desorption, ICP-OES, SEM,TEM,NH3-TPD and 27Al MAS-NMR). The results showed that the HZ zeolite, which was micro-mesoporous material and had high specific surface area, provided a higher diffuser efficiency for long-chain VOC gas. The catalytic performance of HZ zeolite was better than that of the traditional ZSM-5 zeolite. Compared with the dry atmosphere, HZ-100 zeolite, which possessed more proper medium strong acid sites and the appropriate amount of acid sites, had the higher pentanal catalytic combustion conversion of above 92% and the relatively superior stability with 2 V% water steam in air, indicating that the suitable acid sites can form the best synergistic catalytic effect with water molecules for purifying long-chainVOC gas. In addition, the catalytic conversion of pentanal on 10 wt% LaMnO3/HZ-100 was 100% with no deactivation, and compared with HZ under a dry atmosphere, the average CO2 yields of 10 wt% LaMnO3/HZ catalysts in the steady catalytic oxidation stage under a dry atmosphere and 2 V% water steam in air were improved by 6–18% and 13–20%.

Keywords

Hierarchical ZSM-5 Cooking fumes Catalytic oxidation Pentanal LaMnO3 perovskite 

Notes

Acknowledgements

This study was supported by Air Pollution of National Key Research and Development Special Programs of China (NO. 2017YFC0212606) and the National Nature Science Foundation of China (NO. 51608500).

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019

Authors and Affiliations

  • Jian Li
    • 1
  • Yingjie Shi
    • 2
    Email author
  • Xiaoheng Fu
    • 1
  • Jiayu Huang
    • 2
  • Yanping Zhang
    • 2
  • Shuang Deng
    • 2
  • Fan Zhang
    • 2
  1. 1.School of Chemical & Environmental EngineeringChina University of Mining &Technology (Beijing)BeijingChina
  2. 2.Research Center of Air Pollution Control TechnologyChinese Research Academy of Environmental SciencesBeijingChina

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