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Reaction Kinetics, Mechanisms and Catalysis

, Volume 126, Issue 2, pp 987–1001 | Cite as

Chemical fixation of CO2: the influence of linear amphiphilic anions on surface active ionic liquids (SAILs) as catalysts for synthesis of cyclic carbonates under solvent-free conditions

  • Michele O. Vieira
  • Wesley F. Monteiro
  • Bruna S. Neto
  • Vitaly V. Chaban
  • Rosane Ligabue
  • Sandra EinloftEmail author
Article

Abstract

Carbon dioxide (CO2) conversion is an efficient option to mitigate environmental impacts caused by CO2 high concentration in the atmosphere. In this work are described catalytic activities of surface active ionic liquids (SAILs) composed of well-known cations 1-butyl-3-methylimidazolium ([bmim+]) and tetra-n-butylammonium ([TBA+]) and long alkyl chain anions: lauryl sulfate ([C12SO4]), lauryl ether sulfate ([C12ESO4]), lauryl benzene sulfonate ([C12BSO3]) and lauroyl sarcosinate ([C12SAR]) for cyclic carbonate synthesis. Results evidenced that [TBA+] is more active as a catalyst due to its higher molecular volume increasing the cation–anion distance and weakening the electrostatic interaction resulting in a more electrophilic cation. The [TBA][C12BSO3] SAIL presented better catalytic activity for styrene carbonate (SC) synthesis, reaching 81.4% of conversion and 87.0% of selectivity as well as the high recycle capacity and possible application as catalyst for the syntheses of different cyclic carbonates: glycidyl isopropyl ether carbonate (GC) and epichlorohydrin carbonate (EC).

Keywords

Carbon dioxide Catalysis Cycloaddition Ionic liquid Cyclic carbonate 

Notes

Acknowledgements

This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nivel Superior – Brasil (CAPES) – Finance Code 001. SE thanks CNPq for research scholarship.

Supplementary material

11144_2019_1544_MOESM1_ESM.docx (196 kb)
Supplementary material 1 (DOCX 195 kb)

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Copyright information

© Akadémiai Kiadó, Budapest, Hungary 2019

Authors and Affiliations

  1. 1.Post-Graduation Program in Materials Engineering and TechnologyPontifical Catholic University of Rio Grande do Sul - PUCRSPorto AlegreBrazil
  2. 2.School of TechnologyPontifical Catholic University of Rio Grande do Sul - PUCRSPorto AlegreBrazil
  3. 3.P.E.SSaint PetersburgRussian Federation
  4. 4.School of SciencesPontifical Catholic University of Rio Grande do Sul - PUCRSPorto AlegreBrazil

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